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development of control technique for behavior of ionic liquid molecules at graphene/SiC surface and interface

Research Project

Project/Area Number 16K04939
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Applied materials
Research InstitutionUbe National College of Technology

Principal Investigator

IKARI Tomonori  宇部工業高等専門学校, 電気工学科, 教授 (40419619)

Co-Investigator(Kenkyū-buntansha) 内藤 正路  九州工業大学, 大学院工学研究院, 教授 (60264131)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords表面・界面物性 / グラフェン / SiC / 準安定原子誘起電子分光法 / イオン液体 / 超薄膜
Outline of Final Research Achievements

We have carried out the preparation of experimental setup for organic molecules (ionic liquids: IL) and the experiments for controlling behavior of organic molecules. In the preparation of experimental setup, we performed the development of metastable atom source with time of flight system and construction of sample preparation chamber with evaporators for organic molecules. Graphene or some reconstructed surface were formed on SiC substrate with annealing temperature. The electric charges at substrate surface were controlled by introducing different kind of atoms to these surface. We observed the influence of the surface structure and electric charge to behavior of organic molecules. In this research, mainly experimental techniques were low energy electron diffraction (LEED) for the observation of surface structure and metastable atom induced electron spectroscopy (MIES) for measurement of electronic structure.

Academic Significance and Societal Importance of the Research Achievements

グラフェン及びSiC再構成表面への異種原子導入による局所的な電荷の制御や最表面構造による有機分子(イオン液体(IL)等)の配向等の振舞を制御できれば、エネルギー貯蔵デバイスの高効率化や微細化へ貢献できる。表面の水素化や酸化に関する知見は、表面の特徴を利用したデバイス開発において、非常に重要である。特に酸化については、アルカリ金属触媒を用いることで、従来のプロセスよりも低温で高効率に良質な膜を形成することが出来る。また、飛行時間差型準安定原子源の開発により、表面上の原子や有機分子による構造を傷つけることなく、最表面から真空側に浸み出した局所的な電子状態の観測を実現した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (7 results)

All 2019 2018 2017

All Presentation (7 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Presentation] 準安定原子誘起電子分光法によるO/Cs/SiC(3×3)表面の電子状態測定2019

    • Author(s)
      田中晶貴,飯田涼,柏谷拓実,渡邉拓斗,平山楓,田中悟,内藤正路,碇智徳
    • Organizer
      2019年 第66回応用物理学会春季学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] MIESによる異種原子吸着したSiC再構成表面上の電子状態観測2019

    • Author(s)
      碇智徳
    • Organizer
      第11回九大2D物質研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Initial oxidation process of the alkali metals adsorbed 4H-SiC surface studied by metastable atom induced electron spectroscopy2018

    • Author(s)
      R. Iida, M. Tanaka, K. Hirayama, K. Muraoka, S. Kuroki, S. Tanaka, M. Naitoh, T. Ikari
    • Organizer
      14th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures (ACSIN-14) & 26st International Colloquium on Scanning Probe Microscopy (ICSPM26)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] SiC(3×3)表面における酸素とCs吸着に関する研究2018

    • Author(s)
      田中晶貴,飯田涼,平山楓,Visikovskiy Anton,田中悟,内藤正路,碇智徳
    • Organizer
      平成30年度日本表面真空学会 九州支部学術講演(九州表面・真空研究会2018)
    • Related Report
      2018 Annual Research Report
  • [Presentation] MIESによる酸素吸着したCs/6H-SiC(0001)表面の電子状態観測2017

    • Author(s)
      中村拓人,平山楓,村岡幸輔,石井純子,黒木伸一郎,田中悟,内藤正路,碇智徳
    • Organizer
      日本物理学会 第72回年次大会(2017年)
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Electronic structure of Oxygen and Cesium co-adsorption on 6H-SiC(0001)_(6√3×6√3)R30° surface studied by MIES2017

    • Author(s)
      K. Hirayama, R. Iida, T. Nakamura, T. Kajiwara, S. Tanaka, M. Naitoh and T. Ikari
    • Organizer
      The 8th International Symposium on Surface Science (ISSS-8)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] アルカリ金属及び酸素吸着したSiC(0001)‐(6√3×6√3)R30°表面の電子状態2017

    • Author(s)
      碇智徳,平山楓,中村拓人,村岡幸輔,田中悟,黒木伸一郎,内藤正路
    • Organizer
      平成29年度九州表面・真空研究会2017(兼第22回九州薄膜表面研究会)
    • Related Report
      2017 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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