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Minute area XAFS development for orientational evaluations of structure controlled functional organic polymer materials

Research Project

Project/Area Number 16K05020
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionUniversity of Hyogo

Principal Investigator

HARUYAMA YUICHI  兵庫県立大学, 高度産業科学技術研究所, 准教授 (10316036)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
KeywordsXAFS / 機能性分子材料 / 微小領域 / 分子配向 / 配向 / 量子ビーム / 放射光
Outline of Final Research Achievements

Molecular orientation in the structure controlled photoreactive liquid crystalline polymer films was investigated by using near-edge X-ray absorption fine structure (NEXAFS) spectra at the C K-edge region. The line and space patterns were fabricated by imprint technology on the photoreactive liquid crystalline polymer films. NEXAFS spectra were simultaneously measured by three types of detection methods with the different probing depth. From the incident angle dependence of the NEXAFS spectra, the molecular orientations in the films were evaluated. It was found that the orientation of the liquid crystalline molecules near the surface tended to be parallel to the surface. In addition, minute area XAFS apparatus was developed for orientational evaluations of structure controlled functional organic polymer materials.

Academic Significance and Societal Importance of the Research Achievements

これまでのナノインプリント研究では、主に応用的な観点から研究が行われてきているが、本研究では、インプリントにより機能性分子材料を構造制御することで、分子配向がどのように影響するかについて基本的な性質を調べた点で、学術的に意義がある。機能性分子材料における分子配向の様子を明らかにすることにより、機能性分子材料の3次元配向や制御などの応用に結びつくので、今後の産業への応用を考える上で意義のある研究である。また、微小領域のXAFS測定は、今後数多くの微小な材料に適用でき、材料分析に関して非常に重要である。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (13 results)

All 2019 2018 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 3 results) Book (1 results)

  • [Journal Article] Depth analysis of molecular orientation induced by nanoimprint graphoepitaxy2017

    • Author(s)
      Makoto Okada, Ryosuke Fujii, Yuichi Haruyama, Hiroshi Ono, Nobuhiro Kawatsuki, and Shinji Matsui
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 56 Issue: 4 Pages: 1-4

    • DOI

      10.7567/jjap.56.040302

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of complex molecular orientation patterns in nanostructures via double nanoimprint graphoepitaxy2017

    • Author(s)
      M. Okada, R. Fujii, Y. Haruyama, H. Ono, and N. Kawatsuki
    • Journal Title

      Appl. Phys. Express

      Volume: 10 Issue: 10 Pages: 105201-4

    • DOI

      10.7567/apex.10.105201

    • NAID

      210000136001

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] マイクロフォーカス放射光を用いた2次元マッピング装置の開発2019

    • Author(s)
      春山雄一, 西原克浩
    • Organizer
      第32回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 分子配向性光配向膜に対する深さ方向に依存した分子配向性評価2018

    • Author(s)
      春山雄一, 岡田真, 近藤瑞穂, 川月喜弘
    • Organizer
      2018年日本表面真空学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Evaluation on the molecular orientation in photoreactive liquid crystalline polymer films by NEXAFS spectroscopy2018

    • Author(s)
      Y. Haruyama, M. Okada, M. Kondo, and N. Kawatsuki
    • Organizer
      The Fourteenth International Conference on Electron Spectroscopy and Structure
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] インプリントされた光反応性高分子液晶に対する配向性評価2017

    • Author(s)
      春山雄一, 岡田真, 西岡江美, 近藤瑞穂, 川月喜弘, 松井真二
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大(大阪府豊中市)
    • Year and Date
      2017-03-20
    • Related Report
      2016 Research-status Report
  • [Presentation] NEXAFS測定を用いた光反応性高分子液晶膜に対する分子配向の深さ方向依存性評価2017

    • Author(s)
      春山雄一, 谷口雄亮, 近藤瑞穂, 川月喜弘, 岡田真, 松井真二
    • Organizer
      第30回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      神戸芸術センター(兵庫県神戸市)
    • Year and Date
      2017-01-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Molecular orientation of photoreactive liquid crystalline polymer films observed by NEXAFS2017

    • Author(s)
      Y. Haruyama, M. Okada, E. Nishioka, M. Kondo, N. Kawatsuki, and S. Matsui
    • Organizer
      European Congress and Exhibition on Advanced Materials and Processes
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] NEXAFSによる深さ方向に依存した高分子液晶膜中の分子配向評価2017

    • Author(s)
      春山雄一, 岡田真, 稲田陽之助, 近藤瑞穂, 川月喜弘
    • Organizer
      第31回日本放射光学会年会・放射光科学合同シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] 軟X線吸収分光による高分子液晶薄膜の分子配向性評価2017

    • Author(s)
      春山雄一, 岡田真,近藤瑞穂, 川月喜弘
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 光反応性高分子液晶膜に対する深さ方向に依存した分子配向性評価2016

    • Author(s)
      春山雄一, 谷口雄亮, 近藤瑞穂, 川月喜弘, 岡田真, 松井真二
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大(石川県金沢市)
    • Year and Date
      2016-09-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Molecular orientation in photoreactive liquid crystalline polymer films observed by NEXAFS2016

    • Author(s)
      Y. Haruyama, Y. Taniguchi, M. Kondo, N. Kawatsuki, M. Okada, and S. Matsui
    • Organizer
      39th International conference on Vacuum Ultraviolet and X-ray Physics
    • Place of Presentation
      チューリッヒ(Switzerland)
    • Year and Date
      2016-07-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Book] ナノインプリント技術ハンドブック2019

    • Author(s)
      春山 雄一
    • Total Pages
      4
    • Publisher
      株式会社オーム社
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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