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Development of analytical system for 2-dimensional chemical state of super light elements by using scanning transmission X-ray microscopy

Research Project

Project/Area Number 16K05022
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionInstitute for Molecular Science

Principal Investigator

Ohigashi Takuji  分子科学研究所, 極端紫外光研究施設, 助教 (50375169)

Research Collaborator Kosugi Nobuhiro  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords走査型透過X線顕微鏡 / 高分解能2次元化学状態分析 / リチウムK吸収端分析 / リチウム検出 / 全反射型Zone Plate / 2次電子検出 / 軽元素分析 / 全反射型ゾーンプレート / 放射光 / 検出手法開発
Outline of Final Research Achievements

Analytical system for chemical states of light elements below carbon, especially lithium, with high spatial resolution was developed by using a synchrotron-based scanning transmission X-ray microscope (STXM). STXM could access around 50 eVby fabricating a special focusing element, a Fresnel zone plate (FZP), which has high diffraction efficiency and longer focal length in low energy region and its supporting membrane of silicon works as a filter to cut off higher order lights above 100 eV. By using this FZP, low X-ray energy region from 50 to 100 eV with spatial resolution around 80 nm could be available to measure microscopic X-ray absorption spectrum around lithium K absorption edge. By using the technique, 2-dimensional chemical state of an electrode of a lithium-ion secondary battery was analyzed.

Academic Significance and Societal Importance of the Research Achievements

エネルギー確保が社会的課題になる中、リチウムイオン2次電池はもはや切り離し難いほど、我々の生活に浸透している。しかし一方で、安全性や電池容量など、解決すべき課題は未だ多く残っている。その原因の一つは、リチウムの化学的・形態的挙動を検出、そしてその分析を行うための適切な手法が、これまで存在しなかったことである。本研究の成果は、その解明をもたらすものである。よって今後のリチウムイオン電池研究において、ブレイクスルーをもたらすものと期待される上に、海洋鉱物類に含有される資源探索や、隕石中にビッグバン由来のリチウムの痕跡を認めるなどと言った、新たなサイエンス分野の開拓も期待できる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (3 results) Journal Article (10 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 10 results,  Open Access: 6 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Int'l Joint Research: 9 results,  Invited: 3 results)

  • [Int'l Joint Research] Berlin Freie Universitat(ドイツ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] NSRRC/淡江大学/中央研究院網站(その他の国・地域)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Oulu Univerisity(フィンランド)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Quantitative Distribution of DNA, RNA, Histone and Proteins Other than Histone in Mammalian Cells, Nuclei and a Chromosome at High Resolution Observed by Scanning Transmission Soft X-Ray Microscopy (STXM)2019

    • Author(s)
      K. Shinohara, S. Tone, T. Ejima, T. Ohigashi, A. Ito
    • Journal Title

      Cells

      Volume: 8 Issue: 2 Pages: 164-164

    • DOI

      10.3390/cells8020164

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 3-Dimensional Chemical Structures of an Isolated Cell Nucleus by a Scanning Transmission X-ray Microscope2018

    • Author(s)
      Ohigashi Takuji、Ito Atsushi、Shinohara Kunio、Tone Shigenobu、Inagaki Yuichi、Yuzawa Hayato、Kosugi Nobuhiro
    • Journal Title

      Microscopy and Microanalysis

      Volume: 24 Issue: S2 Pages: 400-401

    • DOI

      10.1017/s1431927618014289

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Origin of Magnetic properties in carbon Implanted ZnO nanowires2018

    • Author(s)
      Y.F. Wang, Y.C. Shao, S.H. Hsieh, Y.K. Chang, P.H. Yeh, H.C. Hsueh, J.W. Chiou, H.T. Wang, S.C. Ray, H.M. Tsai, C.W. Pao, C.H. Chen, H.J. Lin, J.F. Lee, C.T. Wu, J.J. Wu, Y.M. Chang, K. Asokan, K.H. Chae, T. Ohigashi, Y. Takagi, T. Yokoyama, N. Kosugi and W.F. Pong
    • Journal Title

      Scientific Report

      Volume: 8 Pages: 7758-7758

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Highly Efficient 2D/3D Hybrid Perovskite Solar Cells via Low-Pressure Vapor-Assisted Solution Process2018

    • Author(s)
      M-H. Li, H-H Yeh, U-S. Jeng, C-J. Su, H-W. Shiu, Y-J. Hsu, N. Kosugi, T. Ohigashi, Y-A. Chen, P-S. Shen, P. Chen, T-F. Guo
    • Journal Title

      Advanced Materials

      Volume: 30 Issue: 30 Pages: 1801401-1801401

    • DOI

      10.1002/adma.201801401

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Discrimination of DNA and RNA distribution in a mammalian cell by scanning transmission soft X-ray microscopy2018

    • Author(s)
      Shinohara Kunio、Ito Atsushi、Ohigashi Takuji、Kado Masataka、Tone Shigenobu
    • Journal Title

      Journal of X-Ray Science and Technology

      Volume: 26 Issue: 6 Pages: 877-884

    • DOI

      10.3233/xst-180392

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] orphology control in polymerized high internal phase emulsion templated via macro-RAFT agent composition: Visualizing surface chemistry2018

    • Author(s)
      A. Khodabandeh, R.D. Arrua, B.R. Coad, T. Rodemann, T. Ohigashi, N. Kosugi, S.C. Thickett and E. Hilder
    • Journal Title

      Polymer Chemistry

      Volume: 9 Issue: 2 Pages: 213-220

    • DOI

      10.1039/c7py01770g

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Spatially Resolved Distribution of Fe Species around Microbes at the Submicron Scale in Natural Bacteriogenic Iron Oxides2017

    • Author(s)
      H. Suga, S. Kikuchi, Y. Takeichi, C. Miyamoto, M. Miyahara, S. Mitsunobu, T. Ohigashi, K. Mase, K. Ono and Y. Takahashi
    • Journal Title

      Microbes and Environments

      Volume: 32 Issue: 3 Pages: 283-287

    • DOI

      10.1264/jsme2.ME17009

    • NAID

      130006105328

    • ISSN
      1342-6311, 1347-4405
    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Investigation of Measurement Condition for 3-Dimensional Spectroscopy by Scanning Transmission X-ray Microscopy2017

    • Author(s)
      T. Ohigashi, Y. Inagaki, A. Ito, K. Shinohara and N. Kosugi
    • Journal Title

      Journal of Physics Conference Series

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of In-Situ/Operando Sample Cells for Soft X-ray Transmission Spectromicroscopy at UVSOR-III Synchrotron2017

    • Author(s)
      M. Nagasaka, T. Ohigashi, N. Kosugi
    • Journal Title

      Synchrotron Radiation News

      Volume: 30(2) Issue: 2 Pages: 3-7

    • DOI

      10.1080/08940886.2017.1289798

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] UVSOR-IIIの走査型透過X線顕微鏡における化学状態分析法の開発2016

    • Author(s)
      大東 琢治, 小杉 信博
    • Journal Title

      放射光

      Volume: 29 Pages: 287-293

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] BL4U spectromicroscopy beamline and its application from skin to steel2018

    • Author(s)
      T. Ohigashi
    • Organizer
      I4FUTURE
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Application of soft x-ray spectro-microscopy beamline in UVSOR2018

    • Author(s)
      T. Ohigashi and H. Yuzawa
    • Organizer
      ACSIN14 & ICSPM26
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 3-Dimentional Chemical Structures of an Isolated Cell Nucleus by a Scanning X-ray Transmission Microscope2018

    • Author(s)
      T. Ohigashi, A. Ito, K. Shinohara, S. Tone, Y. Inagaki, H. Yuzawa and N. Kosugi
    • Organizer
      XRM 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] UVSORにおける走査型透過X線顕微鏡の現状と将来展望2018

    • Author(s)
      大東 琢治、湯沢 勇人
    • Organizer
      東京大学物性研短期研究会 軟X線放射光科学のアップシフト
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Progress of STXM beamline in UVSOR-III and its application2018

    • Author(s)
      T. Ohigashi and H. Yuzawa
    • Organizer
      Spectronanoscopy 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 走査型透過X線顕微鏡を用いた3次元化学状態マッピング法の開発2018

    • Author(s)
      大東 琢治、稲垣 裕一、伊藤 敦、篠原 邦夫、刀祢 重信、小杉 信博
    • Organizer
      日本放射光学会年会
    • Related Report
      2017 Research-status Report
  • [Presentation] STXM-CTによる3次元化学状態分析法の開発2017

    • Author(s)
      大東 琢治、稲垣 裕一、伊藤 敦、篠原 邦夫、小杉 信博
    • Organizer
      第30回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      神戸芸術センター、兵庫県神戸市
    • Year and Date
      2017-01-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Advances in Scanning Transmission X-ray Microscopy at UVSOR-III Synchrotron2017

    • Author(s)
      T. Ohigashi, Y. Inagaki and N. Kosugi
    • Organizer
      24th Congress of the International Commission for Optics
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Recent status of biological imaging at scanning transmission X-ray microscopy beamline2017

    • Author(s)
      T. Ohigashi
    • Organizer
      第26回バイオイメージング学会学術集会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Advanced Analyses in Scanning Transmission X-ray Microscopy at UVSOR-III Synchrotron2017

    • Author(s)
      T. Ohigashi, Y. Inagaki and N. Kosugi
    • Organizer
      24th International Congress on X-ray Optics and Microanalysis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] UVSORの走査型透過X線顕微鏡の現状2017

    • Author(s)
      大東 琢治、稲垣 裕一、小杉 信博
    • Organizer
      X線結像光学シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] Development of Scanning Transmission X-ray Microscopy for in situ/operando Chemical Analysis at UVSOR-III2016

    • Author(s)
      T. Ohigashi, Y. Inagaki and N. Kosugi
    • Organizer
      Advanced Spectroscopy of Organic Materials for Electronic Applications
    • Place of Presentation
      岡崎コンファレンスセンター、愛知県岡崎市(日本)
    • Year and Date
      2016-11-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of Scanning Transmission X-ray Microscopy for in situ/operando Chemical Analysis at UVSOR-III2016

    • Author(s)
      T. Ohigashi, Y. Inagaki and N. Kosugi
    • Organizer
      Mechanical Engineering Design of Synchrotron Radiation Equipment and Instrumentation
    • Place of Presentation
      Cosmocaixa, the science museum of Barcelona(スペイン)
    • Year and Date
      2016-09-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] UVSOR-STXMを用いた応用顕微XAFS手法の開発2016

    • Author(s)
      大東 琢治、小杉 信博
    • Organizer
      第19回XAFS討論会
    • Place of Presentation
      名古屋大学野依記念学術交流館、愛知県名古屋市
    • Year and Date
      2016-09-03
    • Related Report
      2016 Research-status Report
  • [Presentation] A QUANTITATIVE 3-DIMENSIONAL OBSERVATION METHOD FOR SCANNING TRANSMISSION X-RAY MICROSCOPY2016

    • Author(s)
      T. Ohigashi, Y. Inagaki, A. Ito, K. Shinohara and N. Kosugi
    • Organizer
      International Conference X-ray Microscopy
    • Place of Presentation
      University of Oxford (イギリス)
    • Year and Date
      2016-08-15
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chemical Applications of a Scanning Transmission X-ray Microscope Developed at UVSOR-III Synchrotron2016

    • Author(s)
      T. Ohigashi, Y. Inagaki and N. Kosugi
    • Organizer
      39th International Conference on Vacuum Ultraviolet and X-ray Physics
    • Place of Presentation
      ETH Zurich (スイス)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2020-03-30  

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