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Origin of ferroelectric-like metal state in superconducting parent phase

Research Project

Project/Area Number 16K05434
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Condensed matter physics II
Research InstitutionTokyo Institute of Technology

Principal Investigator

Yamaura Junichi  東京工業大学, 元素戦略研究センター, 特任准教授 (80292762)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords鉄系超伝導 / 強誘電金属 / ネマチック状態 / ネマチック揺らぎ / 構造ゆらぎ / 超伝導 / 構造秩序 / 磁気秩序
Outline of Final Research Achievements

A hydrogen-substituted iron-based superconductor has a unique parent phase that loses spatial inversion symmetry and a superconducting phase adjacent to it. Since the superconducting phase is regarded as the fluctuations of superconductivity are ordered, the relationship between fluctuations in the ferroelectric metallic state and superconductivity is interesting. From the X-ray diffraction in LaFeAsO1-xHx, we found that the lattice symmetry lowering -nematic state- from a much higher temperature of the parent phase. From EXAFS measurement, we discovered that there is a local inversion symmetry breaking -ferroelectric fluctuation- from a much higher temperature region. This result suggests that the fluctuation of polar metal may be related to superconductivity.

Academic Significance and Societal Importance of the Research Achievements

本研究成果は、最近多くの超伝導体で観測されているネマチック状態が、水素置換系鉄系超伝導体でも存在していることを新たに証明し、さらに、超伝導体全体でも未知といえる、強誘電的金属状態の揺らぎと超伝導の関連を見出した重要な意義がある。また、反転対称を破った構造における超伝導は、上部臨界磁場の理論的限界値を上げる可能性があり、超伝導体の応用という面でも重要な情報を提供できると考えている。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (34 results)

All 2020 2019 2018 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (17 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 17 results,  Open Access: 6 results,  Acknowledgement Compliant: 3 results) Presentation (11 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (2 results)

  • [Int'l Joint Research] LNCMI-CNRS(France)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Institute for Basic Science/Seoul National University/Ewha Womans University(韓国)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] U.S. Department of Energy(米国)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Institute for Basic Science(韓国)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Polar nano-region structure in the oxynitride perovskite LaTiO2N2020

    • Author(s)
      Yamaura Jun-ichi、Maki Sachiko、Honda Takashi、Matsui Yoshio、Noviyanto Alfian、Otomo Toshiya、Abe Hitoshi、Murakami Youichi、Ohashi Naoki
    • Journal Title

      Chemical Communications

      Volume: 56 Issue: 9 Pages: 1385-1388

    • DOI

      10.1039/c9cc07029j

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystal structure and magnetic properties of the 5d transition metal oxides AOsO4(A=K,Rb,Cs)2019

    • Author(s)
      Yamaura Jun-ichi、Hiroi Zenji
    • Journal Title

      Physical Review B

      Volume: 99 Issue: 15

    • DOI

      10.1103/physrevb.99.155113

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantum dynamics of hydrogen in the iron-based superconductor LaFeAsO0.9D0.1 measured with inelastic neutron spectroscopy2019

    • Author(s)
      Jun-ichi Yamaura, Haruhiro Hiraka, Soshi Iimura, Yoshinori Muraba, Joonho Bang, Kazuhiko Ikeuchi, Mitsutaka Nakamura, Yasuhiro Inamura, Takashi Honda, Masatoshi Hiraishi, Kenji M. Kojima, Ryosuke Kadono, Yoshio Kuramoto, Youichi Murakami, Satoru Matsuishi, and Hideo Hosono
    • Journal Title

      Phys. Rev. B

      Volume: 99 Issue: 22

    • DOI

      10.1103/physrevb.99.220505

    • NAID

      120007168972

    • Related Report
      2019 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] High-pressure Raman study on the superconducting pyrochlore oxide Cd2Re2O72018

    • Author(s)
      Y. Matsubayashi, T. Hasegawa, N. Ogita, J. Yamaura, Z. Hiroi,
    • Journal Title

      Physica B

      Volume: 536 Pages: 600-603

    • DOI

      10.1016/j.physb.2017.10.030

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] High-pressure crystal and electronic structures in iron-based ladder superconductor BaFe2S32018

    • Author(s)
      K. Kobayashi, S. Maki, Y. Murakami, Y. Hirata, K. Ohgushi, and J. Yamaura
    • Journal Title

      Superconduct. Sci. Technol

      Volume: 31 Issue: 10 Pages: 105002-105002

    • DOI

      10.1088/1361-6668/aad790

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Gapless magnetic excitation in a heavily electron-doped antiferromagnetic phase of LaFeAsO0.5D0.52018

    • Author(s)
      H. Tamatsukuri, H. Hiraka, K. Ikeuchi, S. Iimura, Y. Muraba, M. Nakamura, H. Sagayama, J. Yamaura, Y. Murakami, Y. Kuramoto, and H. Hosono
    • Journal Title

      Phys. Rev. B.

      Volume: 98 Issue: 17 Pages: 1744151-1744156

    • DOI

      10.1103/physrevb.98.174415

    • NAID

      120006731602

    • Related Report
      2018 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structural Insight into Charge Transfer Phase Transition for Unique Iron Mixed-Valence Complex (n-C3H7)4N[FeIIFeIII(dto)3] with 2D Honeycomb Network2018

    • Author(s)
      M. Itoi, A. Okazawa, J. Yamaura, S. Maki, T. Komatsu, N. Kojima, I. Maurien, E. Codjovi, K. Boukheddaden. and F. Varret
    • Journal Title

      Inorg. Chem.

      Volume: 57 Issue: 21 Pages: 13728-13738

    • DOI

      10.1021/acs.inorgchem.8b02211

    • Related Report
      2018 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural variations and dielectric properties of (Bi1-xLax)2SiO5 (0<x<0.1): Polycrystallines synthesized by crystallization of Bi-Si-O and Bi-La-Si-O glasses2018

    • Author(s)
      Hiroki Taniguchi、Shingo Tatewaki、Shintaro Yasui、Yasuhiro Fujii、Jun-ichi Yamaura、Ichiro Terasaki
    • Journal Title

      Physical Review Materials

      Volume: 2 Issue: 4

    • DOI

      10.1103/physrevmaterials.2.045603

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Pyrochlore Oxide Superconductor Cd2Re2O7 Revisited2018

    • Author(s)
      Zenji Hiroi、Jun-ichi Yamaura、Tatsuo C. Kobayashi、 Yasuhito Matsubayashi、Daigorou Hirai
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 2 Pages: 024702-024702

    • DOI

      10.7566/jpsj.87.024702

    • NAID

      210000134700

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Spin dynamics in the high-field phases of volborthite2017

    • Author(s)
      M. Yoshida、K. Nawa、H. Ishikawa、M. Takigawa、M. Jeong、S. Kramer、M. Horvatic、C. Berthier、K. Matsui、T. Goto、S. Kimura、T. Sasaki、J. Yamaura、H. Yoshida、Y. Okamoto、Z. Hiroi
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 18

    • DOI

      10.1103/physrevb.96.180413

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure determination in thin film Ba1-xLaxFe2As2: Relation between the FeAs4 geometry and superconductivity2017

    • Author(s)
      Kensuke Kobayashi、Akiko Nakao、Sachiko Maki、Jun-ichi Yamaura、Takayoshi Katase、Hikaru Sato、Hajime Sagayama、Reiji Kumai、Yoshio Kuramoto、Youichi Murakami、Hidenori Hiramatsu、Hideo Hosono
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 12

    • DOI

      10.1103/physrevb.96.125116

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Two-magnon scattering in the 5d all-in-all-out pyrochlore magnet Cd2Os2O72017

    • Author(s)
      Thi Minh Hien Nguyen、Luke J. Sandilands、C. H. Sohn、C. H. Kim、Aleksander L. Wysocki、In-Sang Yang、S. J. Moon、Jae-Hyeon Ko、J. Yamaura、Z. Hiroi、Tae Won Noh
    • Journal Title

      Nature Communications

      Volume: 8 Issue: 1

    • DOI

      10.1038/s41467-017-00228-w

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Semimetallic bands derived from interlayer electrons in the quasi-two-dimensional electride Y2C2017

    • Author(s)
      Horiba Koji、Yukawa Ryu、Mitsuhashi Taichi、Kitamura Miho、Inoshita Takeshi、Hamada Noriaki、Otani Shigeki、Ohashi Naoki、Maki Sachiko、Yamaura Jun-ichi、Hosono Hideo、Murakami Youichi、Kumigashira Hiroshi
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 4 Pages: 045101-045101

    • DOI

      10.1103/physrevb.96.045101

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] 4.Strong Spin-Phonon Coupling Mediated by Single Ion Anisotropy in the All-In--All-Out Pyrochlore Magnet Cd2Os2O72017

    • Author(s)
      C. H. Sohn, C. H. Kim, L. J. Sandilands, N. M. Hien, S. Y. Kim, H. J. Park, K. W. Kim, S. J. Moon, J. Yamaura, Z. Hiroi, and T. W. Noh
    • Journal Title

      Phys. Rev. Lett.

      Volume: 118 Issue: 11 Pages: 117201-117201

    • DOI

      10.1103/physrevlett.118.117201

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Robust ferromagnetism carried by antiferromagnetic domain walls2017

    • Author(s)
      Hishiro T. Hirose, Jun-ichi Yamaura, Zenji Hiroi
    • Journal Title

      Scientific Reports

      Volume: 7 Issue: 1 Pages: 42440-42440

    • DOI

      10.1038/srep42440

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 1.Successive spatial symmetry breaking under high pressure in the spin-orbit-coupled metal Cd2Re2O72017

    • Author(s)
      J. Yamaura, K. Takeda, Y. Ikeda, N. Hirao, Y. Ohishi, T. C. Kobayashi, Z. Hiroi
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 2 Pages: 020102-020102

    • DOI

      10.1103/physrevb.95.020102

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 2.Pressure effect on iron-based superconductor LaFeAsO1-xHx: Peculiar response of 1111-type structure2016

    • Author(s)
      K. Kobayashi, J. Yamaura, S. Iimura, S. Maki, H. Sagayama, R. Kumai, Y. Murakami, H. Takahashi, S. Matsuishi, H. Hosono
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 39646-39646

    • DOI

      10.1038/srep39646

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Quantum Dynamics of Hydrogen in Iron-based Superconductor2019

    • Author(s)
      J. Yamaura
    • Organizer
      Materials Research Meeting
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ヒドリド誘起の超伝導をプロトンのトンネリングで観測する2018

    • Author(s)
      山浦淳一
    • Organizer
      第3回 固体化学フォーラム研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] BiFeO3における傾角反強磁性相の新奇電気分極2018

    • Author(s)
      河智史朗, 木下雄斗, 三宅厚志, 伊藤利充, 宮原慎, 山浦淳一, 徳永将史
    • Organizer
      日本物理学会 年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 結晶構造解析とDFT計算による鉄混合原子価錯体(n-C3H7)4N[FeIIFeIII(dto)3]の光誘起電荷移動相転移の可能性の検討2018

    • Author(s)
      糸井充穂, 岡澤厚, 山浦淳一, 真木祥千子, 小松徳太郎, Isabelle Maurin, Epiphane Codjovi, Kamel Boukheddaden, 小島憲道
    • Organizer
      日本物理学会 年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] 超強磁場高周波透過法によるCd2Os2O7の磁場誘起絶縁体金属転移の探索III2018

    • Author(s)
      三田航平, 山浦淳一, 廣瀬陽代, 廣井善二, 松田康弘
    • Organizer
      日本物理学会 年次大会
    • Related Report
      2018 Research-status Report
  • [Presentation] Ba1-xLaxFe2As2薄膜の結晶構造2017

    • Author(s)
      小林賢介, 中尾朗子, 真木祥千子, 山浦淳一, 片瀬貴義, 佐藤光, 佐賀山基, 熊井玲児, 村上洋一, 平松秀典, 細野秀雄
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Cd2Re2O7の圧力-温度相図と超伝導2017

    • Author(s)
      小林達生, 安部大貴, 荒木新吾, 町田洋, 井澤公一, 山浦淳一, 松林康仁, 廣井善二
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] All-In-All-Outパイロクロア磁性体Cd2Os2O7における新奇な電荷スピン交差ダイナミクス2017

    • Author(s)
      幸田章宏, 門野良典, 岡部博孝, 平石雅俊, 竹下聡史, 小嶋健児, 廣瀬陽代, 広井善二, 山浦淳一
    • Organizer
      日本物理学会
    • Place of Presentation
      大阪大学
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Noncentrosymmetric parent phase in iron-based superconductor2017

    • Author(s)
      Jun-ichi Yamaura
    • Organizer
      J-Physics 2017: International Workshop on Multipole Physics and Related Phenomena
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素置換型鉄系超伝導体REFeAsO1-xHxの圧力下結晶構造2016

    • Author(s)
      小林賢介, 山浦淳一, 真木祥千子, 岡西洋志, 飯村壮史, 佐賀山基, 熊井玲児, 村上洋一, 松石聡, 細野秀雄
    • Organizer
      日本物理学会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] Cd2Re2O7の圧力 温度相図2016

    • Author(s)
      小林達生, 安部大貴, 荒木新吾, 山浦淳一, 松林康仁, 広井善二
    • Organizer
      日本物理学会
    • Place of Presentation
      金沢大学
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Remarks] 水素誘起の超伝導を水素運動で観る

    • URL

      https://www.mces.titech.ac.jp/authors/yamaura/quantumhydrogen.html

    • Related Report
      2019 Annual Research Report
  • [Remarks] 鉄系超伝導体における結晶構造との特異な関係を発見

    • URL

      http://www.kek.jp/ja/NewsRoom/Release/2016/12/22/pressrelease20161222_2.pdf

    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2022-02-22  

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