Time domain photoelectron spectroscopy of gas-phase molecules
| Project/Area Number |
16K05496
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Atomic/Molecular/Quantum electronics
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Research Collaborator |
Shimada Hiroyuki
Yagishita Akira
Mizuno Tomoya
Majima Takuya
Tsuru Shota
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| Project Period (FY) |
2016-04-01 – 2019-03-31
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| Project Status |
Completed (Fiscal Year 2018)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | 光電子分光 / 自由電子レーザー / 高次高調波発生 / 配列分子 / 時間分解分光 / 時間分解光電子分光 / 光電子回折 / X線自由電子レーザー / 超高速光化学反応 / 原子・分子物理 |
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| Outline of Final Research Achievements |
The present study aims to observe the structural dynamics during ultrafast photochemical reactions by the photoelectron diffraction using the free electron laser (FEL), in the extreme ultraviolet (EUV) regions. I focused on developing the time-resolved photoelectron spectroscopy by synchronizing the optical laser and EUV-FEL pulses.
One example is the sideband spectra of Ar 3p photoelectrons by the optical laser and EUV-FEL pulses, which appear only when the two pulses are temporally overlapped. The observed intensities and the angular distributions of sidebands are reasonably reproduced by theoretical simulations by considering the timing jitter between the two pulses.
Another examples are the photoelectron angular distributions of CO2 molecules nonadiabatically aligned by optical laser pulses. The observed alignment dependence of the angular distributions is well reproduced by theoretical simulations, which ensures the validity of our time-resolved measurement methodology.
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| Academic Significance and Societal Importance of the Research Achievements |
超短パルスレーザーを用いた超高速に進行する現象のダイナミクス研究によって、化学反応の本質を理解できるため、多くの研究者が興味を持って研究を続けている。特に、化学反応とは、分子の中で原子の位置が変化することを表わす現象であり、構造の変化を観測することが、化学反応の本質に迫る直接的な手段である。光電子回折法はその有力な手段の一つであり、本研究によって光電子回折の実現直前まで迫ることが可能になった。
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Report
(4 results)
Research Products
(33 results)
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[Presentation] Two-color above threshold ionization of atoms by using femtosecond XUV free electron laser and NIR laser pulses2018
Author(s)
Shinichirou Minemoto, Hiroyuki Shimada, Kazma Komatsu, Wataru Komatsubara, Takuya Majima, Tomoya Mizuno, Shigeki Owada, Hirofumi Sakai, Tadashi Togashi, Shintaro Yoshida, Makina Yabashi, and Akira Yagishita,
Organizer
XXI International Conference on Ultrafast Phenomena
Related Report
Int'l Joint Research
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[Presentation] Two-color above threshold ionization of atoms by using femtosecond XUV free electron laser and NIR laser pulses2018
Author(s)
Shinichirou Minemoto, Hiroyuki Shimada, Kazma Komatsu, Wataru Komatsubara, Takuya Majima, Tomoya, Mizuno, Shigeki Owada, Hirofumi Sakai, Tadashi Togashi, Shintaro Yoshida, Makina Yabashi, and Akira Yagishita
Organizer
the 21st International Conference on Ultrafast Phenomena
Related Report
Int'l Joint Research
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[Presentation] Electron spectra in short-pulse two-color (EUV+NIR) photoionization of atoms and molecules2017
Author(s)
Shinichirou Minemoto, Hiroyuki Shimada, Kazuma Komatsu, Wataru Komatsubara, Takuya Majima, Soichiro Miyake, Tomoya Mizuno, Satoru Takano, Hirofumi Sakai, Shintaro Yoshida, and Akira Yagishita
Organizer
33rd Symposium on Chemical Kinetics and Dynamics
Related Report
Int'l Joint Research
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[Presentation] Femtosecond structure determination of molecules in an alignment laser by photoelectron diffraction with an XFEL2016
Author(s)
S. Minemoto, T. Teramoto, H. Akagi, T. Fujikawa, T. Majima, K. Nakajima, K. Ogawa, H. Sakai, T. Togashi, K. Tono, S. Tsuru, S. Yoshida, K. Wada, M. Yabashi, and A. Yagishita,
Organizer
The 16th International Conference on X-Ray Lasers
Place of Presentation
奈良春日野国際フォーラム(奈良県奈良市)
Related Report
Int'l Joint Research
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[Presentation] Femtosecond structure determination of aligned molecules in an intense laser field studied by X-ray photoelectron diffraction with an XFEL2016
Author(s)
S. Minemoto, T. Teramoto, H. Akagi, T. Fujikawa, T. Majima, K. Nakajima, K. Ogawa, H. Sakai, T. Togashi, K. Tono, S. Tsuru, S. Yoshida, K. Wada, M. Yabashi, and A. Yagishita,
Organizer
39th International Conference on Vacuum Ultraviolet and X-ray Physics
Place of Presentation
Zuerich, Switzerland
Related Report
Int'l Joint Research
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