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Relation between Structural Heterogeneity of Cellular Structures and Mechanical Properties of Polymer Foams

Research Project

Project/Area Number 16K05513
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biological physics/Chemical physics/Soft matter physics
Research InstitutionNagoya University (2018-2019)
Kanazawa University (2016-2017)

Principal Investigator

Uneyama Takashi  名古屋大学, 工学研究科, 准教授 (10524720)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Discontinued (Fiscal Year 2019)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords高分子発泡体 / セル構造 / 圧縮 / 力学試験 / 不均一構造 / 画像解析 / 発泡体 / 高分子構造・物性 / 粗視化
Outline of Final Research Achievements

Polymer foams have cellular structures which consist of solid polymer matrices and dispersed gas pores. Polymer foams exhibit good energy absorption property while they are light. The properties of polymer foams are known to strongly depend on the degree of foaming. But in addition to the degree of foaming, the properties can depend on the heterogeneity of the cellular structures. In this work, we prepared series of polymer foams with different heterogeneous cellular structures. We measured both the mechanical properties of these foams by the compression tests, and the cellular structures by microscope observations and image analyses. We introduced the cell strength parameter to characterize the strength of a cell against the compression. We showed that the heterogeneity of the cell strength parameter can be semi-quantitatively related to the stress-strain curve obtained by a direct compression test.

Academic Significance and Societal Importance of the Research Achievements

高分子発泡体は種々の用途に利用されている材料であるが、あまり発泡をしていない高分子発泡体の物性が何に支配されているかはこれまで十分には理解されていなかった。本研究により、発泡の程度に加えてセル構造の不均一性が高分子発泡体の力学物性に影響を与えることが明らかになった。さらに、顕微鏡でセル構造を測定することで力学挙動をある程度予測することもできるようになった。このような知見は特定の用途に最適化した高分子発泡体を作成したり、作成した高分子発泡体がどれだけのエネルギーを吸収できるかを知りたい場合に有用であると期待される。

Report

(4 results)
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Research-status Report
  • 2016 Research-status Report

Research Products

(30 results)

All 2019 2018 2017 2016

All Journal Article (10 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 10 results) Presentation (20 results) (of which Int'l Joint Research: 6 results,  Invited: 2 results)

  • [Journal Article] A transient bond model for dynamic constraints in meso-scale coarse-grained systems2019

    • Author(s)
      Uneyama Takashi
    • Journal Title

      The Journal of Chemical Physics

      Volume: 150

    • DOI

      10.1063/1.5062495

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relaxation functions of the Ornstein-Uhlenbeck process with fluctuating diffusivity2019

    • Author(s)
      Takashi Uneyama; Tomoshige Miyaguchi; Takuma Akimoto
    • Journal Title

      Phys. Rev. E

      Volume: 99 Pages: 032127-032127

    • DOI

      10.1103/physreve.99.032127

    • NAID

      120006650171

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of critical gel state of polyamides by viscoelastic, thermal, and IR measurements2019

    • Author(s)
      Hirayama Takaya、Uneyama Takashi、Masubuchi Yuichi
    • Journal Title

      Rheologica Acta

      Volume: 58 Pages: 281-290

    • DOI

      10.1007/s00397-019-01136-0

    • NAID

      120006711425

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Self-Consistent Field Theory Based on a Soft-Dumbbell Model for Symmetric Diblock Copolymers2019

    • Author(s)
      UNEYAMA Takashi
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 76 Issue: 1 Pages: 44-51

    • DOI

      10.1295/koron.2018-0035

    • NAID

      130007556886

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Comparison among multi-chain models for entangled polymer dynamics2018

    • Author(s)
      Masubuchi Yuichi、Uneyama Takashi
    • Journal Title

      Soft Matter

      Volume: 14 Pages: 5986-5994

    • DOI

      10.1039/c8sm00948a

    • NAID

      120006577115

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of pore size distribution on compressive behavior of moderately expanded low-density polyethylene foams2018

    • Author(s)
      Uneyama Takashi、Yamazaki Tatsuya、Igarashi Toshio、Nitta Koh-hei
    • Journal Title

      Polymer Engineering & Science

      Volume: 59 Pages: 510-518

    • DOI

      10.1002/pen.24958

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transparent Woody Film Made by Dissolution of Finely Divided Japanese Beech in Formic Acid at Room Temperature2017

    • Author(s)
      Yuri Nishiwaki-Akine, Sui Kanazawa, Takashi Uneyama, Koh-hei Nitta, Ryoko Yamamoto-Ikemoto, and Takashi Watanabe
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 5 Pages: 11536-11542

    • DOI

      10.1021/acssuschemeng.7b02839

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Orientational cross correlations between entangled branch polymers in primitive chain network simulations2017

    • Author(s)
      Yuichi Masubuchi, Ankita Pandey, Yoshifumi Amamoto, and Takashi Uneyama
    • Journal Title

      J Chem Phys

      Volume: 147 Pages: 184903-184903

    • DOI

      10.1063/1.5001960

    • NAID

      120006380357

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] コンピュータを使った高分子の見方:何ができるか、どうするか2017

    • Author(s)
      畝山多加志
    • Journal Title

      高分子

      Volume: 66 Pages: 547-548

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Constrution of Coarse-Grained Models of Meso-Scale Structures for Dynamics in Polymeric Systems2017

    • Author(s)
      畝山多加志
    • Journal Title

      J. Soc. Rheol., Jpn

      Volume: 45 Issue: 5 Pages: 217-223

    • DOI

      10.1678/rheology.45.217

    • NAID

      130006513845

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] 高分子の粗視化シミュレーション2019

    • Author(s)
      畝山多加志
    • Organizer
      高分子学会東海支部 2018東海シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Mesoscopic coarse-grained simulation models for entangled polymers with transient objects2019

    • Author(s)
      Takashi Uneyama
    • Organizer
      Computational Sciences Workshop 2019 (CSW2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 過渡的結合を持つ多粒子系の拡散の不均一性2019

    • Author(s)
      畝山多加志
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Rheological Behavior of Partially Melted High-Density Polyethylene near Melting Point2018

    • Author(s)
      Takashi Uneyama and Koh-hei Nitta
    • Organizer
      The 7th Pacific Rim Conference on Rheology (PRCR 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 会合性テレケリック高分子水溶液のレオロジーとダイナミクス2018

    • Author(s)
      畝山多加志
    • Organizer
      第165回東海高分子研究会講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Takashi Uneyama and Yuichi Masubuchi2018

    • Author(s)
      Modeling Viscoelasticity by Mesoscopic Coarse-Grained Models with Transient Bonds
    • Organizer
      First International Conference on 4D Materials and Systems (4DMS)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 過渡的結合の導入による多粒子系のダイナミクスとレオロジーのシミュレーション2018

    • Author(s)
      畝山多加志
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 過渡的結合を取り入れた高レベル粗視化シミュレーションモデルの性質2018

    • Author(s)
      畝山多加志
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 運動性のゆらぐ系における緩和関数の解析2018

    • Author(s)
      畝山多加志
    • Organizer
      第66回レオロジー討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] からみあい高分子系の高レベル粗視化シミュレーションモデルの比較2018

    • Author(s)
      畝山多加志, 増渕雄一
    • Organizer
      第30回高分子加工技術討論会記念大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高分子鎖の運動性のゆらぎの緩和への影響2018

    • Author(s)
      畝山多加志
    • Organizer
      高分子基礎研究会2018
    • Related Report
      2018 Annual Research Report
  • [Presentation] Fluctuation of Diffusion Coefficient in Coarse-Grained Models of Entangled Polymers2018

    • Author(s)
      Takashi Uneyama
    • Organizer
      Soft Matter Physics: from the perspective of the essential heterogeneity
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 過渡的結合のある高分子系における拡散挙動の解析2018

    • Author(s)
      畝山多加志
    • Organizer
      2018年度高分子基礎物性研究会・高分子計算機科学研究会・高分子ナノテクノロジー研究会合同討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Coarse-grained modeling and statistical mechanical analysis of entangled polymers2018

    • Author(s)
      Takashi Uneyama
    • Organizer
      Bridging the Scales in Soft Matter Simulations
    • Related Report
      2017 Research-status Report
  • [Presentation] 分子系ダイナミクスのメソスケール構造粗視化モデルの構築2017

    • Author(s)
      畝山多加志
    • Organizer
      日本レオロジー学会第 44 年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 突き刺し変形下における高分子フィルムの形状と力学挙動の解析2017

    • Author(s)
      畝山多加志, 菊岡智諭, 新田晃平
    • Organizer
      第65回レオロジー討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 融点近傍の高密度ポリエチレンのネットワーク構造とレオロジーの温度依存性2017

    • Author(s)
      畝山多加志, 新田晃平
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] イソタクチックポリプロピレンの熱収縮挙動のモデル化2016

    • Author(s)
      畝山 多加志, 室谷 佳奈, 新田 晃平
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 (横浜)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of Cellular Structure on Compressive Behavior of Moderately Expanded Low Density Polyethylene (LDPE) Foams2016

    • Author(s)
      T. Uneyama, T. Yamazaki, T. Igarashi and K. Nitta
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Year and Date
      2016-08-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Bending Behavior of Moderately Expanded Linear Low Density Polyethylene (LLDPE) Foams with Different Relative Densities2016

    • Author(s)
      T. Uneyama, S. Tatsuta, T. Igarashi and K. Nitta
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2021-02-19  

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