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Peripheral plasma diagnostics by electron spectroscopy of vibrationally-excited hydrogen molecules

Research Project

Project/Area Number 16K05636
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Plasma science
Research InstitutionSophia University

Principal Investigator

Hoshino Masamitsu  上智大学, 理工学部, 教授 (40392112)

Project Period (FY) 2016-04-01 – 2020-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywords電子分光 / 衝突断面積 / プラズマ素過程 / 加熱分子 / 衝突断面積データ / プラズマ関連分子 / 原子分子物理学 / 振動励起分子
Outline of Final Research Achievements

In order to understand atomic and molecular fundamental processes in the low-temperature plasmas around nuclear fusion including the interactions among electrons, metal surfaces, and neutral hydrogen molecules, electron collision cross sections for vibrationally-excited molecules generated by interacting between metal surfaces and hydrogen molecules were measured quantitatively. First, the collision cross sections of pure gas phase hydrogen molecules and its isotope deuterium molecules at room temperature were more precisely measured than previous works as the reference values. Then, when the electron collision cross sections of hydrogens penetrated though the high temperature metal cylinder were also measured and compared with the reference values, the different trend of the cross sections have been clearly observed between the present results and that for the pure gaseous hydrogen predicted from the Boltzmann distribution at high temperature.

Academic Significance and Societal Importance of the Research Achievements

これまで核融合周辺プラズマや半導体プロセスにおけるプラズマモデリングの基礎データとして様々な原子分子衝突過程の衝突断面積が用いられてきた。特に電子衝突断面積については,純粋な気相原子分子標的,類似標的に対する理論値や予測値が主に使用され,定量的な実験データの少なさが問題であった。そこで今回,金属表面と水素分子の相互作用で生成された励起水素分子の電子衝突断面積の定量データ,および室温で測定された基準となる純粋気相分子の精密データを測定し,高精度なプラズマモデリングを実行する上で必要不可欠なデータを得ることで,今後より現実に近いシミュレーションに基づいたプラズマの詳細な理解が期待される。

Report

(5 results)
  • 2019 Annual Research Report   Final Research Report ( PDF )
  • 2018 Research-status Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (28 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (7 results) Journal Article (4 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 4 results) Presentation (17 results) (of which Int'l Joint Research: 4 results,  Invited: 3 results)

  • [Int'l Joint Research] Universidade Nova de Lisoba(ポルトガル)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Instituto de Fisica Fundamental(スペイン)

    • Related Report
      2018 Research-status Report
  • [Int'l Joint Research] Universidad Complutense de Madrid/Instituto de Fisica Fundamental(スペイン)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Universidade NOVA de Lisboa(ポルトガル)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Universidade NOVA de Lisboa(ポルトガル)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Universit´e de Lille(フランス)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Universidad Complutense de Madrid/Investigaciones Cientificas(スペイン)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Absolute cross section measurements for the scattering of low- and intermediate-energy electrons from PF3. II. Inelastic scattering of vibrational and electronic excitations2018

    • Author(s)
      N. Hishiyama, M. Hoshino, F. Blanco, G. Garcia, and H. Tanaka
    • Journal Title

      The Journal of Chemical Physics

      Volume: 148 Issue: 8

    • DOI

      10.1063/1.5012844

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Absolute cross section measurements for the scattering of low- and intermediate-energy electrons from PF3. I. Elastic scattering2017

    • Author(s)
      N. Hishiyama, M. Hoshino, F. Blanco, G. Garcia, and H. Tanaka
    • Journal Title

      The Journal of Chemical Physics

      Volume: 147 Issue: 22

    • DOI

      10.1063/1.5009482

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Experimental scaling of plane-Born cross sections and ab initio assignments for electron-impact excitation and dissociation of XF4 (X = C, Si, and Ge) molecules2017

    • Author(s)
      M. Hoshino, D. Duflot, P. Limao-Vieira, S. Ohtomi, and H. Tanaka
    • Journal Title

      The Journal of Chemical Physics

      Volume: 146 Issue: 14

    • DOI

      10.1063/1.4979299

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Studies on GeF4 Valence and Rydberg States by Electron Impact Spectroscopy and Ab Initio Calculations2016

    • Author(s)
      S. Ohtomi, M. Hoshino, A. Suga, H. Kato, D. Duflot, P. Limao-Vieira, and H. Tanaka
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 120 Issue: 46 Pages: 9170-9177

    • DOI

      10.1021/acs.jpca.6b09138

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 低エネルギー電子衝撃によるH_2_とD_2_分子の部分断面積に現れる同位体効果2019

    • Author(s)
      要藤明洋、北島昌史、星野正光
    • Organizer
      原子衝突学会 第44回年会
    • Related Report
      2019 Annual Research Report
  • [Presentation] 低エネルギー電子分光法を用いたH_2_とD_2_分子の電子衝突断面積における同位体効果の検証2019

    • Author(s)
      要藤明洋, 北島昌史, 星野正光
    • Organizer
      日本物理学会 2019年秋季大会
    • Related Report
      2019 Annual Research Report
  • [Presentation] Absolute cross section measurements in collisions of low- and intermediate-energy electrons with polyatomic molecules2019

    • Author(s)
      星野正光
    • Organizer
      International workshop on atomic and molecular data for plasma applications
    • Related Report
      2019 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low energy electron spectroscopy of fluorine containing molecules2018

    • Author(s)
      星野正光
    • Organizer
      Research frontier on atomic elementary processes in peripheral plasmas
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] HDの超低エネルギー電子衝突全断面積2018

    • Author(s)
      奥村拓馬, 赤坂博史, 江尻智一, 穂坂綱一, 北島昌史, 小田切丈, 星野正光
    • Organizer
      日本物理学会 第73回年次大会(2018年)
    • Related Report
      2017 Research-status Report
  • [Presentation] PF3分子の電子分光II:非弾性散乱過程2017

    • Author(s)
      菱山直樹,大富翔平,田中敦也,星野正光,田中大
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学(石川県・金沢市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] PF3分子の電子分光II:非弾性散乱過程2017

    • Author(s)
      菱山直樹、大富翔平、田中敦也、星野正光、田中大
    • Organizer
      日本物理学会第72回年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] Experimental scaling of plane-Born cross sections for the electron-impact excitation to the b1Πu state of N2 molecule2017

    • Author(s)
      A. Tanaka, H. Kato, M. Hoshino, and H. Tanaka
    • Organizer
      30th International Conference on Photonic, Electronic, Atomic Collisions
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Absolute elastic differential cross sections for PF_3_ molecule by electron impact: A comparative study with XF3 ( X =B, C, N and CH) molecules2017

    • Author(s)
      N. Hishiyama, M. Hoshino, F. Blanco, G. Garcia, and H. Tanaka
    • Organizer
      30th International Conference on Photonic, Electronic, Atomic Collisions
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] e- + PF_3_衝突における励起断面積の絶対値測定2017

    • Author(s)
      菱山直樹、星野正光、田中大
    • Organizer
      原子衝突学会 第42回年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 電子衝突によるN2分子のb1Πu状態に関する励起断面積2017

    • Author(s)
      田中敦也、加藤英俊、星野正光、田中大
    • Organizer
      原子衝突学会 第42回年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 電子衝撃によるN2分子のb1Πu状態の電子励起断面積測定2017

    • Author(s)
      田中敦也、加藤英俊、星野正光、田中大
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Presentation] 低エネルギー電子とフッ素化合物の衝突における励起素過程と衝突断面積データセット2017

    • Author(s)
      星野正光、菱山直樹、田中大
    • Organizer
      「原子分子過程研究と受動・能動分光計測の高度化のシナ効果によるプラズマ科学の展開」,「原子分子データ応用フォーラムセミナー」ジー 合同研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] NH3分子の低エネルギー電子分光:弾性散乱過程2016

    • Author(s)
      菱山直樹,山崎義基,尾形昌洋,石塚雅典,大富翔平,田中敦也,星野正光,田中大
    • Organizer
      原子衝突学会 第41回年会
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Research-status Report
  • [Presentation] 電子衝撃によるPF3分子の弾性散乱微分断面積の絶対値測定2016

    • Author(s)
      菱山直樹,大富翔平,田中敦也,星野正光,田中大
    • Organizer
      原子衝突学会 第41回年会
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Research-status Report
  • [Presentation] EELSによるXF4分子(X = C, Si, Ge)の電子励起状態とab inito計算2016

    • Author(s)
      大富翔平, 菅惇史, 加藤英俊, 星野正光, D. Duflot, P. Lim o-Vieira, 田中大
    • Organizer
      原子衝突学会 第41回年会
    • Place of Presentation
      富山大学(富山県・富山市)
    • Year and Date
      2016-12-10
    • Related Report
      2016 Research-status Report
  • [Presentation] PF3分子の電子分光I:弾性散乱過程2016

    • Author(s)
      菱山直樹,大富翔平,田中敦也,星野正光,田中大
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学(石川県・金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2021-02-19  

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