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Three-dimensional structures of solvated ions with high molecular weight observed by cryogenic ion mobility mass spectrometry

Research Project

Project/Area Number 16K05641
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionTohoku University

Principal Investigator

Ohshimo Keijiro  東北大学, 理学研究科, 助教 (40373279)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsイオン移動度質量分析 / 構造異性体分離 / 配位構造 / 異性体分離 / 溶媒和 / イオントラップ / 質量分析 / エレクトロスプレーイオン化 / 物理化学
Outline of Final Research Achievements

To study the formation mechanism of three-dimensional structures of solvated ions with high molecular weight, we made the ion mobility mass spectrometer with low-temperature ion drift cell. We performed ion mobility mass spectrometry of a 1:1 complex between a sodium ion and a diol to study structural flexibility of hydrocarbon chain. We measured the collision cross section of the complex between Na+ and 1,7-heptanediol (HD) with a He buffer gas atom. We concluded that the HD has a folded structure in Na+(HD).

Academic Significance and Societal Importance of the Research Achievements

分子の反応性や物性は分子の構造や電子状態により決まるが、溶液中では反応速度や生成物が溶媒の種類により影響を受ける溶媒効果が存在する。その際、溶媒は単に溶質を溶かすためだけにあるのではなく、分子としての個性をもって溶質分子と相互作用する。よって、溶媒効果の本質を理解するためには、溶質分子と溶媒分子との間の分子間の相互作用を考える必要がある。本研究では溶質溶媒分子間ならびに溶媒分子間相互作用に伴う高分子の立体構造の柔軟な変化を研究するために、イオンと高分子からなる錯体イオンの立体構造を観測可能な低温イオン移動度質量分析装置を製作した。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (22 results)

All 2019 2018 2017 2016

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (8 results)

  • [Journal Article] Visible Photodissociation of the CO2 Dimer Cation: Fast and Slow Dissociation Dynamics in the Excited State2019

    • Author(s)
      Y. Nakashima, K. Okutsu, K. Fujimoto, Y. Ito, M. Kanno, M. Nakano, K. Ohshimo, H. Kono, F. Misaizu
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 21 Issue: 6 Pages: 3083-3091

    • DOI

      10.1039/c8cp07068g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Geometrical structures and molecular adsorption reactions of alkali-halide cluster ions investigated by ion mobility-mass spectrometry2019

    • Author(s)
      Keijiro Ohshimo, Tohru Takahashi, Motoyoshi Nakano, Fuminori Misaizu
    • Journal Title

      Bull. Soc. Sea Water Sci. Jpn.

      Volume: 73 Pages: 59-64

    • NAID

      130007920123

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ion Imaging of MgI+ Photofragment in Ultraviolet Photodissociation Mass-selected Mg+ICH3 Complex2018

    • Author(s)
      K. Okutsu, K. Yamazaki, M. Nakano, K. Ohshimo, F. Misaizu
    • Journal Title

      J. Phys. Chem. A

      Volume: 122 Issue: 22 Pages: 4948-4953

    • DOI

      10.1021/acs.jpca.8b01944

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stable Compositions and Structures of Copper Oxide Cluster Cations CunOm+ (n = 2-8) Studied by Ion Mobility Mass Spectrometry2018

    • Author(s)
      M. A. Latif, J. W. J. Wu, R. Moriyama, M. Nakano, K. Ohshimo, F. Misaizu
    • Journal Title

      ACS Omega

      Volume: 3 Issue: 12 Pages: 18705-18713

    • DOI

      10.1021/acsomega.8b02466

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Small Carbon Nano-Onions: An Ion Mobility Mass Spectrometric Study2018

    • Author(s)
      Moriyama Ryoichi、Wu Jenna W. J.、Nakano Motoyoshi、Ohshimo Keijiro、Misaizu Fuminori
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 122 Issue: 9 Pages: 5195-5200

    • DOI

      10.1021/acs.jpcc.8b00597

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Correlation between Electronic Shell Structure and Inertness of Cun+ toward O2 Adsorption at n = 15, 21, 41, and 492018

    • Author(s)
      Ohshimo Keijiro、Akimoto Kengo、Ogawa Masato、Iwasaki Wataru、Yamamoto Hiroaki、Tona Masahide、Tsukamoto Keizo、Nakano Motoyoshi、Misaizu Fuminori
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 122 Issue: 11 Pages: 2927-2932

    • DOI

      10.1021/acs.jpca.8b00246

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of a linear-type double reflectron for focused imaging of photofragment ions from mass-selected complex ions2017

    • Author(s)
      Okutsu Kenichi、Nakashima Yuji、Yamazaki Kenichiro、Fujimoto Keita、Nakano Motoyoshi、Ohshimo Keijiro、Misaizu Fuminori
    • Journal Title

      Review of Scientific Instruments

      Volume: 88 Issue: 5 Pages: 053105-053105

    • DOI

      10.1063/1.4982706

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mass spectrometric study of N 2 -adsorption on copper cluster cations formed by modulated pulsed power magnetron sputtering in aggregation cell2017

    • Author(s)
      Ohshimo Keijiro、Mizuuchi Isamu、Akimoto Kengo、Tsukamoto Keizo、Tona Masahide、Yamamoto Hiroaki、Nakano Motoyoshi、Misaizu Fuminori
    • Journal Title

      Chemical Physics Letters

      Volume: 682 Pages: 60-63

    • DOI

      10.1016/j.cplett.2017.06.012

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Geometrical Structures of Gas Phase Chromium Oxide Cluster Anions Studied by Ion Mobility Mass Spectrometry2017

    • Author(s)
      Moriyama Ryoichi、Sato Ryuki、Nakano Motoyoshi、Ohshimo Keijiro、Misaizu Fuminori
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 121 Issue: 30 Pages: 5605-5613

    • DOI

      10.1021/acs.jpca.7b02431

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Compositions and structures of niobium oxide cluster ions, NbmOn±, (m = 2-12), revealed by ion mobility mass spectrometry2017

    • Author(s)
      Wu Jenna W. J.、Moriyama Ryoichi、Nakano Motoyoshi、Ohshimo Keijiro、Misaizu Fuminori
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 36 Pages: 24903-24914

    • DOI

      10.1039/c7cp04017b

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photofragment ion imaging from mass-selected Mg+BrCH3 complex: Dissociation mechanism following photoinduced charge transfer2017

    • Author(s)
      Kenichi Okutsu, Kenichiro Yamazaki, Keijiro Ohshimo, Fuminori Misaizu
    • Journal Title

      Journal of Chemical Physics

      Volume: 146 Issue: 2 Pages: 024301-024301

    • DOI

      10.1063/1.4973386

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Stable compositions and geometrical structures of titanium oxide cluster cations and anions studied by ion mobility mass spectrometry2016

    • Author(s)
      Keijiro Ohshimo, Naoya Norimasa, Ryoichi Moriyama, Fuminori Misaizu
    • Journal Title

      Journal of Chemical Physics

      Volume: 144 Issue: 19 Pages: 194305-194305

    • DOI

      10.1063/1.4949269

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Compositions and Structures of Vanadium Oxide Cluster Ions VmOn+/- (m = 2-20) Investigated by Ion Mobility Mass Spectrometry2016

    • Author(s)
      Jenna W. J. Wu, Ryoichi Moriyama, Hiroshi Tahara, Keijiro Ohshimo, Fuminori Misiazu
    • Journal Title

      Journal of Physical Chemistry A

      Volume: 120 Issue: 21 Pages: 3788-3796

    • DOI

      10.1021/acs.jpca.6b03403

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structures of Vanadium Oxide Cluster Ions up to Nanometer Diameter Investigated by Ion Mobility Mass Spectrometry2016

    • Author(s)
      Ryoichi Moriyama, Jenna W. J. Wu, Keijiro Ohshimo, Fuminori Misaizu
    • Journal Title

      Bulletin of Chemical Society of Japan

      Volume: 89 Issue: 10 Pages: 1225-1229

    • DOI

      10.1246/bcsj.20160211

    • NAID

      130005332392

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] イオン移動度質量分析を用いたアルカリ金属イオンと直鎖アルカンジオールからなる錯体の配位構造2019

    • Author(s)
      大下慶次郎, 矢部謙太, 宮﨑舜, 田井中創太, 長谷川皓平, 美齊津文典
    • Organizer
      日本化学会第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] エレクトロスプレーイオン化法により生成した有機分子イオンの低温イオン移動度質量分析2018

    • Author(s)
      大下 慶次郎,西 結人,矢部 謙太,宮崎 舜,田井中 創太,美齊津 文典
    • Organizer
      第7回イオン移動度研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] エレクトロスプレーイオン化法により生成した有機分子イオンの低温イオン移動度質量分析2018

    • Author(s)
      矢部 謙太、西 結人、宮崎 舜、田井中 創太、大下 慶次郎、美齊津 文典
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Research-status Report
  • [Presentation] 水和された高分子イオンの構造解析を目的とした低温イオン移動度質量分析装置の製作2017

    • Author(s)
      大下 慶次郎、西 結人、矢部 謙太、美齊津 文典
    • Organizer
      第6回イオン移動度研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] 水和高分子イオンの構造解析を目的とした低温イオン移動度質量分析計の制作2017

    • Author(s)
      西 結人、矢部 謙太、大下 慶次郎、美齊津 文典
    • Organizer
      第65回質量分析総合討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] エレクトロスプレーイオン化法を用いて生成した水和高分子イオンの低温イオン移動度質量分析装置の開発2017

    • Author(s)
      矢部 謙太、西 結人、田井中 創太、宮崎 舜、大下 慶次郎、美齊津 文典
    • Organizer
      第11回分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] エレクトロスプレーイオン化法で生成したアルカリハライドクラスターイオンの構造研究2017

    • Author(s)
      宮﨑 舜、田井中 創太、矢部 謙太、西 結人、大下 慶次郎、美齊津 文典
    • Organizer
      平成29年度化学系学協会東北大会
    • Related Report
      2017 Research-status Report
  • [Presentation] エレクトロスプレーイオン源と四重極イオントラップを用いた低温イオン移動度質量分析装置の製作2017

    • Author(s)
      大下 慶次郎、西 結人、矢部 謙太、中野 元善、美齊津 文典
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学(神奈川県横浜市)
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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