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Elucidation of degradation mechanism of polymers in thermal oxidation and gamma-ray irradiation by luminescence spectroscopy

Research Project

Project/Area Number 16K05644
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

NAKATA MUNETAKA  東京農工大学, (連合)農学研究科(研究院), 教授 (40143367)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsルミネッセンス分光法 / 熱酸化劣化 / 放射線劣化 / 放射線履歴検知 / 熱化学発光 / 高分子 / 分子分光
Outline of Final Research Achievements

Ultraweak chemiluminescence from organic and inorganic polymers during heating was measured as spectrum with a multichannel Fourier-transform chemiluminescence spectrometer. By joint use of matrix-isolation infrared spectroscopy, UV-visible spectroscopy, and thermal analysis, the following research projects were performed: (1) Elucidation of gamma-ray irradiation degradation mechanism of polytetrafluoroethylene to produce peroxy radical; (2) elucidation of thermal oxidative degradation mechanism of cross-linking agents to be used in production of elastomers; (3) consideration of possibility of a detection method of gamma-ray irradiation history by thermoluminescence spectroscopy.

Academic Significance and Societal Importance of the Research Achievements

新しく開発された発光分光分析装置で,物質から放射される極微弱な光を検出した.この装置の特色は発光の強度だけではなく,発光の種類も区別できることである.とくに,放射線を照射した有機高分子(ポリエチレンなど)や,無機高分子(カキやホタテなどの貝殻)からの発光を丁寧に分析して,どのくらいの放射線が照射されたかを調べた.前処理することのない簡易な放射線量の測定法を提案した.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (18 results)

All 2019 2018 2017 2016 Other

All Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (1 results)

  • [Journal Article] Hydrogen-bonded complexes of ethynethiol and hydrogen cyanide trapped in low-temperature argon matrices2019

    • Author(s)
      J. Miyazaki, T. Hatayama, N. Akai, M. Nakata
    • Journal Title

      J. Mol. Struct.

      Volume: 1175 Pages: 900-905

    • DOI

      10.1016/j.molstruc.2018.08.028

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoinduced reversible isomerization of 9H-f;uorene into 1H-Fuorene by means of hydrogen-atom migration and the lowest electronically excited triplet state studied by matrix-isolation FTIR spectroscopy2019

    • Author(s)
      T. Kumakura, N. Akai, M. Nakata
    • Journal Title

      Chemical Physics Letters

      Volume: 714 Pages: 160-165

    • DOI

      10.1016/j.cplett.2018.11.011

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Matrix-isolation infrared spectrum of acenaphthene in the lowest electronically excited triplet (T1) state2018

    • Author(s)
      T. Kumakura, N. Akai, M. Nakata
    • Journal Title

      J. Mol. Struct.

      Volume: 1172 Pages: 89-93

    • DOI

      10.1016/j.molstruc.2017.11.036

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Red-light induced photoreaction of ozone-dimethylamine complex; matrix-isolation infrared spectra of dimethylamine-N-oxide and N,N-dimethylhydroxylamine2018

    • Author(s)
      K. Kamata, N. Akai, M. Nakata
    • Journal Title

      Chemical Physics Letters

      Volume: 707 Pages: 49-53

    • DOI

      10.1016/j.cplett.2018.07.041

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between Crystal Structures and Thermoluminescence Spectra of Gamma-Irradiated Shells of Shellfish Measured with a Multichannel Fourier-Transform Luminescence Spectrometer2017

    • Author(s)
      庄中萌,石井浩,廣庭隆行,赤井伸行,中田宗隆
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 90 Issue: 8 Pages: 905-909

    • DOI

      10.1246/bcsj.20170097

    • NAID

      130005973698

    • ISSN
      0009-2673, 1348-0634
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Detection Method of Gamma-Ray Irradiation History of Shellfish by Thermoluminescence Spectra2017

    • Author(s)
      M. Shonaka, H. Ishii, T. Hironiwa, M. Nakata
    • Journal Title

      RADIOISOTOPES

      Volume: 66 Issue: 2 Pages: 55-60

    • DOI

      10.3769/radioisotopes.66.55

    • NAID

      130005332377

    • ISSN
      0033-8303, 1884-4111
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Degradation mechanism of gamma-irradiated polytetrafluoroethylenen (PTFE) powder by low-temperature matrix-isolation infrared spectroscopy and chemiluminescence spectroscopy2016

    • Author(s)
      M. Minatoyama, N. Akai, E. Yamada, T. Noguchi, H. Ishii, C. Satoh, T. Hironiwa, K.R. Millington, M. Nakata
    • Journal Title

      Polymer J.

      Volume: 48(6) Issue: 6 Pages: 697-702

    • DOI

      10.1038/pj.2015.139

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 可視光で誘起されるオゾン-ジメチルアミン錯体の反応機構2018

    • Author(s)
      鎌田賢太郎,赤井伸行,中田宗隆
    • Organizer
      分子科学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 9H-フルオレンの分子内水素移動と最低励起三重項状態2018

    • Author(s)
      熊倉健太,赤井伸行,中田宗隆
    • Organizer
      分子科学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] フッ素エラストマーのための架橋剤の熱反応機構2018

    • Author(s)
      中村壮吾,上谷文宏,野口剛,赤井伸行,中田宗隆
    • Organizer
      高分子分析討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] エラストマー用のフッ素系ポリマーの熱分解機構の解明2018

    • Author(s)
      松永拓海,赤井伸行,上谷文宏,野口剛,中田宗隆
    • Organizer
      高分子分析討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of a multichannel Fourier-transform luminescence spectrometer and its application to oxidative degradation of polymers2017

    • Author(s)
      C. Satoh, M. Nakata
    • Organizer
      BIT’s Annual Congress of AnalytiX-2017
    • Place of Presentation
      ヒルトン福岡シーホーク(福岡県福岡市)
    • Year and Date
      2017-03-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ガンマ線照射した貝殻の熱発光スペクトルと結晶構造との関係2017

    • Author(s)
      庄中萌,石井浩,廣庭隆行,赤井伸行,中田宗隆
    • Organizer
      分子科学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] マルチチャンネルフーリエ変換型微弱発光分光分析装置の開発と応用2016

    • Author(s)
      佐藤親弘,石井浩,中田宗隆
    • Organizer
      応用物理学会
    • Place of Presentation
      東京理科大学(森戸記念館)(東京都新宿区)
    • Year and Date
      2016-12-08
    • Related Report
      2016 Research-status Report
  • [Presentation] Thermal degradation mechanism of perfluoroelastomers2016

    • Author(s)
      T. Noguchi, F. Kamiya, M. Minatoyama, K. Hombo, N. Akai, M. Nakata
    • Organizer
      The International Rubber Conference 2016
    • Place of Presentation
      北九州市国際会議場(福岡県北九州市)
    • Year and Date
      2016-10-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 含フッ素ポリマーの分子レベルでの熱分解機構の解明2016

    • Author(s)
      湊山美咲,本坊恭一郎,野口剛,赤井伸明,中田宗隆
    • Organizer
      分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Presentation] 発光分光法による貝類の放射線照射履歴の検知法2016

    • Author(s)
      庄中萌,中田宗隆,石井浩,木村久枝
    • Organizer
      アイソトープ・放射線研究発表会
    • Place of Presentation
      東京大学(弥生キャンパス)(東京都文京区)
    • Year and Date
      2016-07-06
    • Related Report
      2016 Research-status Report
  • [Remarks] 東京農工大学中田研究室ホームページ

    • URL

      http://web.tuat.ac.jp/~nakata/index-js.html

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2020-03-30  

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