| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
The synthesis and characterization of novel pyrrole-containing nanographenes were performed, which was synthesized by using aromatic nucleophilic substitution of pyrrole toward electron-deficient aromatics and successive oxidative cyclodehydrogenation. Through a series of study, the synthesis of curved π-electron compounds and anti aromatic compounds was succeeded. The compounds showed stable redox properties compared to previously known nanographene, resulted in the isolation of not only neutral species but also radical cations and diction. The structure-property relationships of the newly obtained compounds were conducted.
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