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Synthesis and physical properties of new anion-substituted melilites

Research Project

Project/Area Number 16K05712
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionHokkaido University

Principal Investigator

DOI YOSHIHIRO  北海道大学, 理学研究院, 助教 (20359483)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Keywordsメリライト / 複合アニオン化合物 / 低次元磁性 / 磁気秩序 / 磁気的相互作用 / 第一原理バンド計算 / 希土類元素 / 磁気フラストレーション / 構造相転移 / トポタクティック反応 / マルチフェロイック / 無機固体化学 / 結晶構造 / 磁性
Outline of Final Research Achievements

The synthesis and physical properties of melilite-type compounds have been investigated. By the cation and anion substitution, new compounds were successfully obtained. As results of various measurements, their crystal structures and physical properties were revealed. It was found that the magnetic properties and interactions were strongly affected by the anion substitution.

Academic Significance and Societal Importance of the Research Achievements

新物質の探索は新たな有用な材料の発見だけでなく、新たな知識を得るという観点からも重要である。本研究では特徴的な結晶構造と物性を持つが、研究の立ち後れていたメリライト型化合物に注目し、カチオン/アニオンの置換による合成方法や、結晶構造、磁性を中心とした物性に関する多くの知見を得ることに成功した。特に磁気的性質に関して、アニオン置換により相互作用の強さを大きく変化させることを実験・計算の両面から明らかにし、新たな材料設計の指針にも繋がると期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (43 results)

All 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (14 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 14 results,  Acknowledgement Compliant: 2 results) Presentation (27 results) (of which Int'l Joint Research: 8 results,  Invited: 1 results)

  • [Int'l Joint Research] Universidad Complutense de Madrid/Universidad Politecnica de Madrid/Universidad de Zaragoza(スペイン)

    • Related Report
      2017 Research-status Report
  • [Int'l Joint Research] Universidad Complutense de Madrid/Universidad Politecnica de Madrid/Universidad de Zaragoza(スペイン)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Magnetic properties of rare earth rhenium oxides <i>Ln</i><sub>3</sub>ReO<sub>7</sub> (<i>Ln</i> = Y, Er–Lu) with fluorite-related structure2018

    • Author(s)
      M. Inabayashi, Y. Doi, M. Wakeshima and Y. Hinatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 11 Pages: 920-924

    • DOI

      10.2109/jcersj2.18127

    • NAID

      120006585784

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-11-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase transitions of Sm<sub>3</sub>NbO<sub>7</sub>, (Sm<sub>1−</sub><i><sub>x</sub>Ln<sub>x</sub></i>)<sub>3</sub>NbO<sub>7</sub> (<i>Ln</i> = Nd, Eu) and Sm<sub>3</sub>TaO<sub>7</sub> with fluorite-related structure2018

    • Author(s)
      M. Inabayashi, Y. Doi, M. Wakeshima, and Y. Hinatsu
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 126 Issue: 10 Pages: 743-749

    • DOI

      10.2109/jcersj2.18054

    • NAID

      130007493507

    • ISSN
      1348-6535, 1882-0743
    • Year and Date
      2018-10-01
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of Praseodymium-containing Double Perovskites (Ba1-xSrx)2PrRuO62018

    • Author(s)
      Y. Endo, Y. Doi, and Y. Hinatsu
    • Journal Title

      J. Solid State Chem.

      Volume: 267 Pages: 1-5

    • DOI

      10.1016/j.jssc.2018.08.001

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multistep Development of the Hyperfine Fields in λ-(BEDT-STF)2FeCl4 Studied by Messbauer Spectroscopy2018

    • Author(s)
      Fukuoka Shuhei、Sawada Masashi、Minamidate Takaaki、Matsunaga Noriaki、Nomura Kazushige、Ihara Yoshihiko、Kawamoto Atsushi、Doi Yoshihiro、Wakeshima Makoto、Hinatsu Yukio
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 87 Issue: 9 Pages: 093705-093705

    • DOI

      10.7566/jpsj.87.093705

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Studies on Eu3MO7 (M = Nb, Ta, Ir) with Fluorite-related Structure by 151Eu Mossbauer Spectroscopy and Magnetic Susceptibility Measurements2018

    • Author(s)
      Yukio Hinatsu, Yoshihiro Doi, and Makoto Wakeshima
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 262 Pages: 224-228

    • DOI

      10.1016/j.jssc.2018.03.024

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Crystal Structures and Magnetic Properties of Fluorite-related Compounds Ce3MO7 (M = Nb, Ta).2017

    • Author(s)
      Masaki Inabayashi, Yoshihiro Doi, Makoto Wakeshima, and Yukio Hinatsu
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 254 Pages: 150-154

    • DOI

      10.1016/j.jssc.2017.07.022

    • NAID

      120006727583

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal structures, magnetic properties, and DFT calculation of B-site defected 12L-perovskites Ba2La2MW2O12 (M = Mn, Co, Ni, Zn)2017

    • Author(s)
      Yoshihiro Doi, Makoto Wakeshima, Keitaro Tezuka, Yue Jin Shan, Kenji Ohoyama, Sanghyun Lee, Shuki Torii, Takashi Kamiyama, and Yukio Hinatsu
    • Journal Title

      Journal of Physics: Condensed Matter

      Volume: 29 Issue: 36 Pages: 3658021-11

    • DOI

      10.1088/1361-648x/aa7c9b

    • NAID

      120006517683

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Studies on phase transition temperature of rare earth niobates Ln3NbO7 (Ln = Pr, Sm, Eu) with orthorhombic fluorite-related structure.2017

    • Author(s)
      Yukio Hinatsu and Yoshihiro Doi
    • Journal Title

      Solid State Sciences

      Volume: 68 Pages: 19-24

    • DOI

      10.1016/j.solidstatesciences.2017.04.004

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Interactions in Praseodymium Ruthenate Pr3RuO7 with Fluorite-related Structure2017

    • Author(s)
      M. Inabayashi, Y. Doi, M. Wakeshima and Y. Hinatsu
    • Journal Title

      J. Solid State Chem.

      Volume: 250 Pages: 100-106

    • DOI

      10.1016/j.jssc.2017.03.025

    • NAID

      120006636184

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Interactions in Rhenium-containing Rare Earth Double Perovskites Sr2LnReO6 (Ln = Rare Earths)2017

    • Author(s)
      A. Nishiyama, Y. Doi and Y. Hinatsu
    • Journal Title

      J. Solid State Chem.

      Volume: 248 Pages: 134-141

    • DOI

      10.1016/j.jssc.2017.02.006

    • NAID

      120006552860

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of the Melilite-type Oxysulfide Sr2MGe2S6O: Magnetic Interactions Enhanced by Anion Substitution2017

    • Author(s)
      T. Endo, Y. Doi, M. Wakeshima, K. Suzuki, Y. Matsuo, K. Tezuka, T. Otsuki, Y. J. Shan and Y. Hinatsu
    • Journal Title

      Inorg. Chem.

      Volume: 56 Issue: 5 Pages: 2459-2466

    • DOI

      10.1021/acs.inorgchem.6b02505

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of new fluorite-related rare earth oxides LnLn'2MO7 (Ln, Ln' = rare earths; M = Nb, Sb, Ta), their structures and magnetic properties by calorimetry measurements.2017

    • Author(s)
      Yukio Hinatsu and Yoshihiro Doi
    • Journal Title

      Journal of Thermal Analysis and Calorimetry

      Volume: 127 Issue: 1 Pages: 749-754

    • DOI

      10.1007/s10973-016-5491-x

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Interactions in New Fluorite-related Rare Earth Oxides LnLn’2RuO7 (Ln, Ln’ = rare earths)2016

    • Author(s)
      Y. Hinatsu and Y. Doi
    • Journal Title

      J. Solid State Chem.

      Volume: 239 Pages: 214-219

    • DOI

      10.1016/j.jssc.2016.04.033

    • NAID

      120006484233

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Crystal Structures and Magnetic Properties of Iron Borates Containing Lanthanides Sr6LnFe(BO3)6 (Ln = La, Pr, Nd, Sm-Lu)2016

    • Author(s)
      H. Inoue, Y. Doi and Y. Hinatsu
    • Journal Title

      J. Alloys and Compounds

      Volume: 681 Pages: 115-119

    • DOI

      10.1016/j.jallcom.2016.03.227

    • NAID

      120006415986

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 三元系希土類アンチモナイドLn6MSb15 (M = Mn, Zn, In)の電子物性2018

    • Author(s)
      分島 亮、三塚 里穂、土井 貴弘、日夏 幸雄
    • Organizer
      第34回 希土類討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Diverse structures of perovskite-type oxides containing rare earths, and their thermal and magnetic properties2018

    • Author(s)
      Yukio Hinatsu, Yoshihiro Doi, Makoto Wakeshima
    • Organizer
      The 12th European Symposium on Thermal Analysis and Calorimetry (ESTAC12)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 層状鉄オキシセレナイドの磁性2018

    • Author(s)
      杉本 陽慈、分島 亮、土井 貴弘、日夏 幸雄
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] フレスノイト型化合物Ba2MnSi2O7Clの結晶構造と磁気的性質2018

    • Author(s)
      呉羽 美紀、土井 貴弘、遠堂 敬史、分島 亮、日夏 幸雄
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] 新規メリライト型複合金属酸化物の優れた酸素発生反応触媒活2018

    • Author(s)
      小川 哲志、鈴木 健太、齋藤 美和、土井 貴弘、本橋 輝樹
    • Organizer
      日本セラミックス協会 第31回秋季シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] フレスノイト型化合物Ba2MnSi2O7Clの結晶構造と磁気的性質2018

    • Author(s)
      呉羽 美紀、土井 貴弘、遠堂 敬史、分島 亮、日夏 幸雄
    • Organizer
      平成30年度 日本セラミックス協会 東北北海道支部研究発表会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 新規メリライト型複合酸化物の合成と酸素還元/発生反応触媒活性2018

    • Author(s)
      小川 哲志、齋藤 美和、鈴木 健太、土井 貴弘、本橋 輝樹
    • Organizer
      電気化学会第85回大会(2018年3月9-11日 東京)
    • Related Report
      2017 Research-status Report
  • [Presentation] ペロブスカイト関連化合物Ba2La2MW2O12(M: 遷移金属)の結晶構造と磁気的性質2017

    • Author(s)
      土井 貴弘、日夏 幸雄
    • Organizer
      日本セラミックス協会2016年年会
    • Place of Presentation
      日本大学駿河台キャンパス( 東京都千代田区)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] ダブルペロブスカイトBa2PrRuO6のBaサイトのSr置換による構造と磁性への影響2017

    • Author(s)
      遠藤 雄人、分島 亮、土井 貴弘、日夏 幸雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター(岡山県岡山市)
    • Year and Date
      2017-01-12
    • Related Report
      2016 Research-status Report
  • [Presentation] フルオライト派生化合物Pr3RuO7へのイオン置換による結晶構造、磁気的性質の変化2017

    • Author(s)
      稲林将来、分島 亮、土井 貴弘、日夏 幸雄
    • Organizer
      第55回セラミックス基礎科学討論会
    • Place of Presentation
      岡山コンベンションセンター(岡山県岡山市)
    • Year and Date
      2017-01-12
    • Related Report
      2016 Research-status Report
  • [Presentation] 低次元構造を持つPbMn2Ni6Te3O18型化合物の新規合成と物性評価2017

    • Author(s)
      溝口 誠祥、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      第56回セラミックス基礎科学討論会(2017年1月11-12日 つくば)
    • Related Report
      2017 Research-status Report
  • [Presentation] 新規6L-ペロブスカイトBa3LnMn2O9-δ(Ln =ランタノイド)の結晶構造と磁気的性質2017

    • Author(s)
      渡邊 悠香、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      平成29年度 日本セラミックス協会 東北北海道支部研究発表会(2017年11月1-2日 仙台)
    • Related Report
      2017 Research-status Report
  • [Presentation] 遷移金属ホウ酸塩SnM(BO3)2(M = 遷移金属)の合成と構造および磁気的性質2017

    • Author(s)
      峯田 和弥、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      平成29年度 日本セラミックス協会 東北北海道支部研究発表会(2017年11月1-2日 仙台)
    • Related Report
      2017 Research-status Report
  • [Presentation] 12LペロブスカイトBa4LnMn3O12-δ (Ln = Y, ランタノイド)中のMn3O12トライマーの磁気的性質2017

    • Author(s)
      西山 篤秀、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム (2017年9月19-21日 神戸)
    • Related Report
      2017 Research-status Report
  • [Presentation] Specific heat and Mossbauer spectra of double perovskites containing both rare earth and osmium.2017

    • Author(s)
      Yukio Hinatsu, Yoshihiro Doi, and Makoto Wakeshima
    • Organizer
      The International Conference on the Applications of the Mossbauer Effect (ICAME 2017) (2017年9月3-8日 Saint Petersburg, Russia)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetism and magnetocaloric Effect of Gd0.5R0.5CrO4 and EuR2O4 (R = rare earth)2017

    • Author(s)
      Regino Saez-Puche, Julio Romero, Jose Manuel Gallardo, Antonio Dos santos-Garcia, Elias Palacios, Miguel Castro, Ramon Burriel, Yoshihiro Doi, and Yukio Hinatsu,
    • Organizer
      XXVI International Materials Research Congress 2017 (IMRC 2017)(2017年8月20-25日 Cancun, Mexico)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Studies on phase transitions of rare earth niobates with orthorhombic fluorite-related structure.2017

    • Author(s)
      Yukio Hinatsu and Yoshihiro Doi
    • Organizer
      1st Journal of Thermal Analysis and Calorimetry Conference and 6th V4 (Joint Czech-Hungarian-Polish-Slovakian) Thermoanalytical Conference(2017年6月6-9日 Budapest, Hungary)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 12Lペロブスカイト型酸化物Ba4RMn3O12-d(R = Rare earths)の合成と結晶構造、磁気的性質2017

    • Author(s)
      西山 篤秀、土井 貴弘、日夏 幸雄
    • Organizer
      第33回希土類討論会 (2017年5月15-16日 鳥取)
    • Related Report
      2017 Research-status Report
  • [Presentation] Magnetocaloric Effect in EuR2O4 and RCrO4 (R = rare earth) Oxides.2016

    • Author(s)
      Regino Saez-Puche, Julio Romero, Antonio J. Dos santos-Garcia, Elias Palacios, Miguel Castro, Ramon Burriel, Yoshihiro Doi, Yukio Hinatsu
    • Organizer
      1st Caribbean Conference on Functional Materials (CARIBMAT 2016)
    • Place of Presentation
      サントドミンゴ(ドミニカ共和国)
    • Year and Date
      2016-11-08
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ダブルペロブスカイト(Ba1-xSrx)2PrRuO6の結晶構造および磁気的性質2016

    • Author(s)
      遠藤 雄人、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      平成28年度 日本セラミックス協会 東北北海道支部研究発表会
    • Place of Presentation
      北海道大学フロンティア応用科学研究棟(北海道札幌市)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Research-status Report
  • [Presentation] 蛍石関連化合物Pr3Ru1-xTaxO7および (Pr1-xYx)3RuO7の結晶構造と磁気的性質2016

    • Author(s)
      稲林 将来、土井 貴弘、分島 亮、日夏 幸雄
    • Organizer
      平成28年度 日本セラミックス協会 東北北海道支部研究発表会
    • Place of Presentation
      北海道大学フロンティア応用科学研究棟(北海道札幌市)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Research-status Report
  • [Presentation] 新規PbMn2Ni6Te3O18型化合物の合成と結晶構造、磁気的性質2016

    • Author(s)
      溝口 誠祥、土井 貴弘、日夏 幸雄
    • Organizer
      平成28年度 日本セラミックス協会 東北北海道支部研究発表会
    • Place of Presentation
      北海道大学フロンティア応用科学研究棟(北海道札幌市)
    • Year and Date
      2016-10-27
    • Related Report
      2016 Research-status Report
  • [Presentation] Structures and Magnetic Properties of 12-Layered Perovskites Ba4LnM3O12 (Ln = rare Earths; M = Ru, Ir)2016

    • Author(s)
      Yukio Hinatsu, Yoshihiro Doi, and Makoto Wakeshima
    • Organizer
      Challenges and Prospects for Solid State Chemistry (CPSSC 16)
    • Place of Presentation
      セビリア(スペイン)
    • Year and Date
      2016-09-09
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 新規ゴーデフロイアイト型ホウ酸塩の結晶構造と磁気的性質2016

    • Author(s)
      井上 博貴、土井 貴弘、日夏 幸雄
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] 12R-ペロブスカイトBa4LnMn3O12-δの結晶構造と磁気的性質2016

    • Author(s)
      西山 篤秀、土井 貴弘、日夏 幸雄
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Magnetic ordering of divalent europium in double perovskites Eu2LnTaO6 (Ln = rare earths).2016

    • Author(s)
      Yukio Hinatsu, Yoshitaka Misawa, and Yoshihiro Doi
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      北海道大学学術交流会館(北海道札幌市)
    • Year and Date
      2016-06-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Crystal Structures and Magnetic Properties of Perovskite-Related Oxides Containing Rare Earths.2016

    • Author(s)
      Yoshihiro Doi
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      北海道大学学術交流会館(北海道札幌市)
    • Year and Date
      2016-06-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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