| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Outline of Final Research Achievements |
To develop catalysts for transformations of inert bonds such as carbon-hydrogen (C-H) bonds under mild conditions, we investigated synthesis and catalysis of newly-designed metal complexes bearing chelate ligands involving silyl coordinating moieties bound to metals via silicon. As representative results, silyl chelate complexes of late transition metals (iridium and ruthenium) were found to catalyze the following reactions: (1) Si-H deuteration of trialkylsilanes with benzene-d6 via activation of its carbon-deuterium (C-D) bonds, (2) C-H borylation of aromatic compounds, (3) hydrosilylation of carbon dioxide, and (4) C-H deuteration of trialkylphosphine via H/D exchange with benzene-d6.
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