| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
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| Outline of Final Research Achievements |
In this study, Pheox- and Phebox-Al complexes stabilized by intramolecular coordination were synthesized and their Lewis acidic properties were controlled by hydrocarbyl ligands. The exchange of counter anions also succeeded in the expression of higher Lewis acidity. It is noteworthy that when the synthesized aluminum complex was applied to catalysis, it showed high activity in the hydroboration reaction of aldehydes and functioned as a more efficient catalyst than typical aluminum chloride and the like.
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