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Development of wire-type molecular magnets by control of coordination in combination of ruthenium dimer cyanidometallate units

Research Project

Project/Area Number 16K05722
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionShimane University

Principal Investigator

Handa Makoto  島根大学, 学術研究院環境システム科学系, 教授 (70208700)

Co-Investigator(Kenkyū-buntansha) 片岡 祐介  島根大学, 学術研究院環境システム科学系, 助教 (20725543)
Project Period (FY) 2016-10-21 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsルテニウム二核錯体 / ランタン型二核錯体 / シアニド金属酸イオン / 集積型錯体 / ワイヤー型構造鎖状構造 / フェリ磁性体 / ヘキサシアニド金属酸塩 / ワイヤー型集積錯体 / 磁性体 / 3,4,5-エトキシ安息香酸イオン / ピバル酸イオン / N,N’-ジフェニルフォルムアミディネートイオン / ルテニウム / シアニド架橋ポリマー / 一次元ワイヤー構造 / ロジウム / 多核・クラスター錯体 / 分子磁石
Outline of Final Research Achievements

Introduction of bulky trialkoxyphenyl groups onto carboxlato bridging ligands of lanthanum-type ruthenium (II, III) dinuclear complexes gave rise to insufficient axial coordination of cyanido groups in combination with cyanido complexes. The bridging ligand was changed to amidato and formamidinato ions. The assembled complexes obtained using amidato ligands showed the ferrimagnetic ordering at low temperatures, though those with the formadinato ligand did not lead to the occurrence of the ferrimagnetic behavior because the dinuclear units became the low-spin state in the assembled complexes.

Academic Significance and Societal Importance of the Research Achievements

ランタン型ルテニウム(II,III)二核錯体は、第5周期元素の重い遷移金属(ルテニウム)から形成されているにも拘らず、低スピン状態に陥らず3個のスピンを有する稀有な磁性ユニットである。シアニド錯イオンとの組合せによる集積型磁性体の開発に於いて、二核内架橋配位子を、これまでのカルボン酸イオンからアミダートイオンあるいはホルムアミジナート配位子を用いても3次元集積構造が得られ、架橋配位子を変えることで集積化合物のスピン状態が制御できることが分かったことは意義深く、今後の二核ユニットを用いた磁気材料の開発に1つの指針を与えると考えられる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (83 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (24 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 24 results,  Open Access: 12 results,  Acknowledgement Compliant: 8 results) Presentation (56 results) (of which Int'l Joint Research: 16 results,  Invited: 2 results) Remarks (1 results)

  • [Int'l Joint Research] Univertsite Claude Bernard Lyon 1(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Jagiellonian University(ポーランド)

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Magnetic and liquid-crystalline properties of chlorido- and cyanato-bridged chain complexes of mixed-valent dinuclear ruthenium(II,III) 3,4,5-trialkoxybenzoates2019

    • Author(s)
      Hideaki Ishida, Makoto Handa, Ichiro Hiromitsu, Seiji Ujiie, Daisuke Yoshioka, Ryoji Mitsuhashi, and Masahiro Mikuriya
    • Journal Title

      New J. Chem.

      Volume: 43 Issue: 3 Pages: 1134-1145

    • DOI

      10.1039/c8nj03436b

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Characterization, Absorption Properties, and Electronic Structures of Paddlewheel-Type Dirhodium(II) Tetra-μ-(n-naphthoate) Complexes: An Experimental and Theoretical Study2019

    • Author(s)
      Yusuke Kataoka, Raiki Fukumoto, Natsumi Yano, Daiki Atarashi, Hidekazu Tanaka, Tatsuya Kawamoto, Makoto Handa
    • Journal Title

      Molecules

      Volume: 24 Issue: 3 Pages: 447-447

    • DOI

      10.3390/molecules24030447

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Magnetic and Electrochemical Properties of Lantern-Type Dinuclear Ru(II,III) Complexes with Axial Chloride Ions or Water Molecules2019

    • Author(s)
      Makoto Handa, Haruki Yairi, Natsumi Yano, Minoru Mitsumi, Hiroshi Sakiyama, Masaharu Kitashima, Kazuhito Inoue, Ryoji Mitsuhashi, Masahiro Mikuriya, Haruo Akashi, and Yusuke Kataoka
    • Journal Title

      Magnetochemistry

      Volume: 5 Issue: 1 Pages: 18-18

    • DOI

      10.3390/magnetochemistry5010018

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structure of a Supramolecular Complex Built up from Molybdenum(II) Trifluoroacetate and Copper(II) Schiff-Base Components, [{CuL<sup>t-Bu</sup>}<sub>2</sub>{Mo<sub>2</sub>(O<sub>2</sub>CCF<sub>3</sub>)<sub>4</sub>}<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>]<sub>n</sub>, H<sub>2</sub>L<sup>t-Bu</sup> = 2,3-bis((5-<i>tert</i>-butyl-2-hydroxybenzylidene)amino)-2,3-butenedinitrile2018

    • Author(s)
      Makoto HANDA, Hiroshi KAMADA, Daisuke YOSHIOKA, Ichiro HIROMITSU, Kuninobu KASUGA, and Masahiro MIKURIYA
    • Journal Title

      X-ray Structure Analysis Online

      Volume: 34 Issue: 0 Pages: 59-62

    • DOI

      10.2116/xraystruct.34.59

    • NAID

      130007528643

    • ISSN
      1883-3578
    • Year and Date
      2018-12-10
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Crystal Structure of Mixed-metal Complex of Paddle-wheel-type Dinuclear Ruthenium(II,III) Carboxylate and Tetracyanidopalladate(II)2018

    • Author(s)
      Masahiro MIKURIYA, Shun KAWAUCHI, Daisuke YOSHIOKA, Ryoji MITSUHASHI, and Makoto HANDA
    • Journal Title

      X-ray Structure Analysis Online

      Volume: 34 Issue: 0 Pages: 37-39

    • DOI

      10.2116/xraystruct.34.37

    • NAID

      130007474789

    • ISSN
      1883-3578
    • Year and Date
      2018-09-10
    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis, Structures, and Properties of a Lantern-type Dinuclear Rhodium(II) Complex cis-[Rh2(4-Me-pf)2(O2CCMe3)2], 4-Me-pf = N,N’-di-p-tolylformamidinate anion2018

    • Author(s)
      Makoto Handa, Satoshi Nishiura, Takafumi Masuda, Natsumi Yano, Masahiro Mikuriya, Yusuke Kataoka
    • Journal Title

      Chemical Papers

      Volume: 72 Issue: 4 Pages: 841-851

    • DOI

      10.1007/s11696-017-0244-2

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure and Magnetic and Electrochmical Properties of Tetrakis(benzamidato)diruthenium(II,III) Tetrafluoroborate2018

    • Author(s)
      Handa Makoto、Yano Natsumi、Okuno Airi、Nakai Hiroki、Mitsumi Minoru、Mikuriya Masahiro、Kataoka Yusuke
    • Journal Title

      Magnetochemistry

      Volume: 4 Issue: 2 Pages: 21-21

    • DOI

      10.3390/magnetochemistry4020021

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chain Compounds Based on Paddle-wheel Copper(II) Carboxylate Bearing Four Nitroxide Radicals2018

    • Author(s)
      Masahiro Mikuriya, Renny Indrawati, Rieko Hashido, Shizuka Matsubara, Chizu Nakamura, Daisuke Yoshioka, Kazuyuki Yokota, Masafumi Fukuzaki, and Makoto Handa
    • Journal Title

      Magnetochemistry

      Volume: 4 Issue: 2 Pages: 22-22

    • DOI

      10.3390/magnetochemistry4020022

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] One-Dimensional Chain-Type Dicopper Coordination Polymer Linked by 1,4-Di(4-pyridyl)benzene; Synthesis, Crystal Structure, Magnetic Property, and Gas-Adsorption Property2018

    • Author(s)
      Yano Natsumi、Handa Makoto、Mitsumi Minoru、Kataoka Yusuke
    • Journal Title

      Magnetochemistry

      Volume: 4 Issue: 2 Pages: 26-26

    • DOI

      10.3390/magnetochemistry4020026

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Experimental and Theoretical Study for Dimer-of-Dimers-type Tetrarhodium(II) Complexes Bridged by 1,4-Benzenedicarboxylate Linkers2018

    • Author(s)
      Yusuke Kataoka, Kazuki Arakawa, Hikaru Ueda, Natsumi Yano, Tatsuya Kawamoto, Makoto Handa
    • Journal Title

      Dalton Transactions

      Volume: 47 Issue: 48 Pages: 17233-17242

    • DOI

      10.1039/c8dt03293a

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New luminescent cyclometalated iridium complexes prepared by the post-synthetic modification2018

    • Author(s)
      Yusuke Kataoka, Kaede Okuno, Natsumi Yano, Hikaru Ueda, Tatsuya Kawamoto, Makoto Handa
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: 358 Pages: 345-355

    • DOI

      10.1016/j.jphotochem.2017.09.009

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and properties of a trinuclear copper(II) complex of a ligand with phthalocyanine and Schiff-base coordination sites2018

    • Author(s)
      Makoto Handa, Kenichi Kanagawa, Natsumi Yano, Haruki Yairi, Airi Okuno, Minoru Mitsumi, Yusuke Kataoka
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 22 Issue: 01n03 Pages: 95-101

    • DOI

      10.1142/s108842461850013x

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photo- and Electrocatalytic Hydrogen Production Using Valence Isomers of N2S2‐Type Nickel Complexes2017

    • Author(s)
      Satoshi Inoue, Manabu Mitsuhashi, Takeshi Ono, Yin-Nan Yan, Yusuke Kataoka, Makoto Handa, Tatsuya Kawamoto
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 20 Pages: 12129-12138

    • DOI

      10.1021/acs.inorgchem.7b01244

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Chain Complex Based on Diruthenium(II,III) Acetate and Tetracyanidoplatinate(II)2017

    • Author(s)
      Masahiro Mikuriya, Shun Kawauchi, Kenta Ono, Ryoji Mitsuhashi, Nobuto Yoshinari, Takumi Konno, Hidekazu Tanaka, and Makoto Handa
    • Journal Title

      J. Supercond. Nov. Magn.

      Volume: in press Issue: 7 Pages: 2007-2010

    • DOI

      10.1007/s10948-016-3643-7

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Analysis and Discrimination of Disperse Dyes Extracted from Black Polyester Fibers2017

    • Author(s)
      Takao Kato, Yasuhiro Suzuki, and Makoto Handa
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 66 Issue: 1 Pages: 39-48

    • DOI

      10.2116/bunsekikagaku.66.39

    • NAID

      130005313296

    • ISSN
      0525-1931
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic Material Based on Mixed-valent Dinuclear pivalate and Cyanidometalate2017

    • Author(s)
      M. Mikuriya, D. Yoshioka, R. Mitsuhashi, D. Luneau, D. Matoga, J. Szklarzewicz, and M. Handa
    • Journal Title

      Acta Physica Polonica, A

      Volume: 131 Issue: 1 Pages: 120-123

    • DOI

      10.12693/aphyspola.131.120

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] A neutral paddlewheel-type diruthenium(III) complex with benzamidinato: synthesis, crystal structure, magnetism, and electrochemical and absorption properties2016

    • Author(s)
      Yusuke Kataoka, Saki Mikami, Hiroshi Sakiyama, Minoru Mitsumi, Tatsuya Kawamoto, Makoto Handa
    • Journal Title

      Polyhedron

      Volume: 印刷中 Pages: 87-92

    • DOI

      10.1016/j.poly.2017.03.005

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Characterizations of a Paddlewheel-type Dirhodium-based Photoactive Porous Metal-Organic Framework2016

    • Author(s)
      Yusuke Kataoka, Konomi S. Kataoka, Hidenobu Murata, Makoto Handa, Wasuke Mori, Tatsuya Kawamoto
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 68 Pages: 37-41

    • DOI

      10.1016/j.inoche.2016.04.009

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Paddlewheel-Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self-Assembly and Disassembly Transformation Properties2016

    • Author(s)
      Yusuke Kataoka, Natsumi Yano, Takashi Shimodaira, Yin-Nan Yan, Mikio Yamasaki, Hidekazu Tanaka, Koji Omata, Tatsuya Kawamoto, and Makoto Handa
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: - Issue: 17 Pages: 2810-2815

    • DOI

      10.1002/ejic.201600197

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Crystal Structure of Another Tetranuclear Oxidovanadium(IV) Complex with 2,6-Bis(hydroxymethyl)-4-methylphenol Having an N<sub>2</sub>-Adsorption Property2016

    • Author(s)
      Masahiro MIKURIYA, Masami FUKUTANI, Masataka OMOTE, Daisuke YOSHIOKA, Ryoji MITSUHASHI, Hidekazu TANAKA, and Makoto HANDA
    • Journal Title

      X-ray Structure Analysis Online

      Volume: 32 Issue: 0 Pages: 29-32

    • DOI

      10.2116/xraystruct.32.29

    • NAID

      130005164237

    • ISSN
      1883-3578
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] (4,4'-Dimeth&#173;oxy-2,2'-bi&#173;pyridine-[kappa]2N,N')bis&#173;[2-(pyridin-2-yl)phenyl-[kappa]C1]iridium(III) hexa&#173;fluorido&#173;phosphate unknown solvate2016

    • Author(s)
      Natsumi Yano, Yusuke Kataoka, Tatsuya Kawamoto, and Makoto Handa
    • Journal Title

      IUCrData

      Volume: 1 Issue: 3 Pages: 1-3

    • DOI

      10.1107/s2414314616004879

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] A New Paddlewheel-type Dirhodium-based Metal-Organic Framework with deprotonated 2,6-Bis(2-benzimidazolyl)pyridine ligand2016

    • Author(s)
      Natsumi Yano, Yusuke Kataoka, Hidekazu Tanaka, Tatsuya Kawamoto, Makoto Handa
    • Journal Title

      ChemistrySelect

      Volume: 1 Issue: 11 Pages: 2571-2575

    • DOI

      10.1002/slct.201600617

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Extraction and Analysis of Disperse Dyes from Colored Polyester Single Fibers Using Liquid Chromatography/Linear Ion Trap Tandem Mass Spectrometry2016

    • Author(s)
      Takao Kato, Yasuhiro Suzuki, and Makoto Handa
    • Journal Title

      Analytical Sciences

      Volume: 32 Issue: 9 Pages: 1019-1022

    • DOI

      10.2116/analsci.32.1019

    • NAID

      130006777413

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Crystal Structures of Dinuclear Cobalt(III) Complexes with 1,3-Bis(5-nitrosalicylideneamino)-2-propanol and 1,3-Bis(3-nitrosalicylideneamino)-2-propanol2016

    • Author(s)
      Masahiro MIKURIYA, Yuko NAKA, Daisuke YOSHIOKA, Makoto Handa
    • Journal Title

      X-ray Structure Analysis Online

      Volume: 32 Issue: 0 Pages: 55-58

    • DOI

      10.2116/xraystruct.32.55

    • NAID

      130005433486

    • ISSN
      1883-3578
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 電子吸引性基を有する新規シクロメタレート型イリジウム錯体による水の光還元反応2018

    • Author(s)
      矢野なつみ, 半田真, 片岡祐介
    • Organizer
      錯体化学会第68回討論会,2018年7月28 - 30日, 仙台.
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノ基を有するPaddlewheel型ロジウム二核錯体の合成と集積制御2018

    • Author(s)
      荒川和樹, 片岡祐介, 川本達也, 半田真
    • Organizer
      錯体化学会第68回討論会,2018年7月28 - 30日, 仙台.
    • Related Report
      2018 Annual Research Report
  • [Presentation] ベンズアミジナート架橋を有するパドルホイール型ルテニウム二核錯体の電子状態と磁気的性質2018

    • Author(s)
      奥野愛里, 片岡祐介, 崎山博史, 満身稔, 川本達也, 半田真
    • Organizer
      錯体化学会第68回討論会,2018年7月28 - 30日, 仙台.
    • Related Report
      2018 Annual Research Report
  • [Presentation] Electronic Structures and Magnetic Properties of Paddlewheel-type Diruthenium (III,III) Complexes with Benzamidinate Ligands2018

    • Author(s)
      Airi Okuno, Yusuke Kataoka, Hiroshi Sakiyama, Minoru Mitsumi, Tatsuya Kawamoto, Makoto Handa
    • Organizer
      43th International Conference on Coordination Chemistry, Sendai, July 30 - August 4
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photophysical and Electrochemical Properties of Cyclometalated Iridium(III) Complexes coordinated with 5,5'-Bis(trifluoromethyl)-2,2'-bipyridine2018

    • Author(s)
      Natsumi Yano, Makoto Handa, Yusuke Kataoka
    • Organizer
      43th International Conference on Coordination Chemistry, Sendai, July 30 - August 4, 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Structure and Magnetic Property of Tatrakis(benzamidato)diruthenium(II,III) Tetrafluoroborate2018

    • Author(s)
      Makoto Handa
    • Organizer
      43th International Conference on Coordination Chemistry, Sendai, July 30 - August 4, 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 合成後修飾法による新規シクロメタレート型イリジウム錯体の開発と光水素発生反応2018

    • Author(s)
      矢野なつみ, 片岡祐介, 川本達也, 半田真
    • Organizer
      2018年日本化学会中国四国支部大会, 2018年11月17-18日, 松山.
    • Related Report
      2018 Annual Research Report
  • [Presentation] Twist-box型Rh4Cl4錯体の合成と反応性2018

    • Author(s)
      片岡祐介, 矢野なつみ, 富永哲也, 越猪昂幸, 半田真
    • Organizer
      2018年日本化学会中国四国支部大会, 2018年11月17-18日, 松山.
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノ基を有するPaddlewheel型ロジウム二核錯体の集積制御とメカノクロミズムの発現2018

    • Author(s)
      荒川和樹, 片岡祐介, 矢野なつみ, 川本達也, 半田真
    • Organizer
      2018年日本化学会中国四国支部大会, 2018年11/17-18日, 松山.
    • Related Report
      2018 Annual Research Report
  • [Presentation] アミノピリジンを配位子に用いたパドルホイール型ルテニウム二核錯体の合成と電子状態2018

    • Author(s)
      今崎那奈子, 片岡祐介, 奥野愛里, 崎山博史, 満身稔, 半田真
    • Organizer
      2018年日本化学会中国四国支部大会, 2018年11/17-18日, 松山.
    • Related Report
      2018 Annual Research Report
  • [Presentation] Synthesis and Properties of a Trinuclear Copper(II) Complex of a Ligand with Phthalocyanine and Schiff-base Coordination Sites2018

    • Author(s)
      Makoto Handa, Kenichi Kanagawa, Natsumi Yano, Haruki Yairi, Airi Okuno, Minoru Mitsumi, Yusuke Kataoka
    • Organizer
      日本化学会第98春季年会,2018年3月20~19日, 船橋(日本大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] Structures and properties of pyz and 4,4’-bpy adduct polymers of lantern-type dirhodium(II) units with formamidinato and pivalato intra-dimer bridges2017

    • Author(s)
      Makoto Handa, Satoshi Nishihara, Natsumi Yano, Takafumi Masuda, Masahiro Mikuriya, and Yusuke Kataoka
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学(横浜)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Copper(II) benzoate with trimethoxy groups2017

    • Author(s)
      Masahiro Mikuriya, Chihiro Yamakawa, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, and Makoto Handa
    • Organizer
      Fifth International Conference on Multifunctional, Hybrid and Nanomaterials
    • Place of Presentation
      Lisbon, Portugal
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Anchor-shaped dirhodium complex as a catalyst for water reduction2017

    • Author(s)
      Natusumi Yano, Yusuke Kataoka, Tatsuya Kawamoto, and Makoto Handa
    • Organizer
      2017 International Conference on Artificical Photosynthesis (ICARP2017)
    • Place of Presentation
      立命館大学朱雀キャンパス(京都)
    • Year and Date
      2017-03-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] New cyclometalated iridium complexes prepared by the post-synthetic modification2017

    • Author(s)
      Yusuke Kataoka, Kaede Okuno, Natsumi Yano, Tatsuya Kawamoto, and Makoto Handa
    • Organizer
      2017 International Conference on Artificical Photosynthesis (ICARP2017)
    • Place of Presentation
      立命館大学朱雀キャンパス(京都)
    • Year and Date
      2017-03-02
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Structures, and Properties of a Lantern-type Dinuclear Rhodium(II) Complex cis-[Rh2(4-Me-pf)2(O2CCMe3)2], 4-Me-pf = N,N’-di-p-tolylformamidinate anion2017

    • Author(s)
      Makoto Handa, Satoshi Nishiura, Takafumi Masuda, Natsumi Yano, Masahiro Mikuriya, Yusuke Kataoka
    • Organizer
      XXVI. Inthernational Conference on Coordination and Bioinorganic Chemistry, Smolenice, Slovakia, Jun. 4 -9, 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Dinuclear and Trtranuclear Vanadium Complexes with Multidentate Ligands2017

    • Author(s)
      Masahiro Mikuriya, Masataka Omote, Masami Fukutani, Taro Kuriyama, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, Makoto Handa
    • Organizer
      EuCheMS-2017-Inorganic Chemistry Conference, Copenhagen, Denmark, Jul. 2-5, 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Liquid crystalline properties of chain compexes basd on dinuclear ruthenium carboxylates2017

    • Author(s)
      Masahiro Mikuriya, Hideaki Ishida, Seiji Ujiie, Makoto Handa
    • Organizer
      10th Liquid Matter Conference, Ljubljana, Slovenia, ,Jul. 17-21, 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis, Crystal Structure, Magnetic Property, and N2-Gas-Adaorption Property of Dinuclear Copper(II) 3,4,5-Trimethoxybenzoate2017

    • Author(s)
      Masahiro Mikuriya, Chihiro Yamakawa, Kensuke Tanabe, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, Makoto Handa
    • Organizer
      3rd International Porous Powder Materials, Kusadasi, Izmir, Turkey, Sept. 12-15
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] テトラキス(ベンズアミジナート)ルテニウム二核錯体の合成2017

    • Author(s)
      奥野愛里, 片岡祐介, 矢野なつみ, 崎山博史, 満身 稔, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] 酢酸架橋パラジウム二核ユニットからなる一次元鎖状錯体2017

    • Author(s)
      北村匠磨, 片岡祐介, 半田 真, 川本達也
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] プロトン共役電子移動反応が可能なロジウム二核錯体の合成と光水素発生2017

    • Author(s)
      植田 光,片岡祐介, 矢野なつみ, 川本達也, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] 塩素架橋ロジウム四核錯体の合成とテトラフルオロホウ酸銀との反応2017

    • Author(s)
      富永哲也, 片岡祐介, 矢野なつみ, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] シクロメタレート結合を有する新規ジホスフィンロジウム二核錯体の合成2017

    • Author(s)
      越猪昂幸, 片岡祐介, 矢野なつみ, 北村匠磨, 川本達也, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] ホルムアミジナートイオンとカルボン酸イオンを分子内架橋配位子とするランタン型ロジウム二核を連結したポリマー錯体2017

    • Author(s)
      西浦聡志, 矢野なつみ, 御厨正博, 田中秀和, 川本達也, 片岡祐介, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] ランタン型ルテニウム二核とシアニド金属酸イオンからなる配位高分子錯体2017

    • Author(s)
      矢入永基, 矢野なつみ, 満身 稔, 三橋了爾, 御厨正博, 片岡祐介, 半田真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] 芳香環架橋配位子を有するHalf-Paddlewheel型ロジウム二核錯体の合成と光水素発生反応2017

    • Author(s)
      福本頼輝, 片岡祐介, 矢野なつみ, 川本達也, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] アンカー型ロジウム二核錯体の開発と水の光還元反応2017

    • Author(s)
      矢野なつみ, 片岡祐介, 川本達也, 半田 真
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] 2-フェニルベンゾチアゾール類を配位子とする白金錯体の合成と性質2017

    • Author(s)
      前川貴一, 大森武弥, 多田宣明, 北村匠磨, 片岡祐介, 半田 真, 川本達也
    • Organizer
      錯体化学会第67回討論会, 2017年9月16日~18日, 北海道 (北海道大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] Metal-Assembled Complexes of Copper-Acetate Type Building Blocks2017

    • Author(s)
      Masahiro Mikuriya, Makoto Handa
    • Organizer
      3rd International Conference on Functional Molecular Materials FUNMAT 2017, Krakow, Poland, Nov. 8-10,2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] ビピリジン配位子への合成後修飾による新規シクロメタレート型イリジウム錯体の 合成と光機能性2017

    • Author(s)
      奥野 楓, 片岡祐介, 矢野なつみ, 川本達也, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] テトラキス(ベンズアミジナート)ルテニウム二核錯体の軸配位子に依存する電子状態2017

    • Author(s)
      奥野愛里, 片岡祐介, 矢野なつみ, 崎山博史, 満身 稔, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] レドックス活性な配位子を有する新規ホスフィンロジウム二核錯体の合成2017

    • Author(s)
      越猪昂幸, 片岡祐介, 矢野なつみ, 北村匠磨, 川本達也, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] ホルムアミジナートイオンとカルボン酸イオンを分子内架橋配位子とするランタン型ロジウム二核錯体の電気化学的性質と磁気的性質2017

    • Author(s)
      西浦聡志, 矢野なつみ, 満身 稔, 御厨正博, 片岡祐介, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] π共役配位子を有するロジウム二核骨格から形成される一次元配位高分子錯体の合成と結晶構造2017

    • Author(s)
      福本頼輝, 片岡祐介, 矢野なつみ, 満身 稔, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] 芳香族カルボン酸配位子を有する塩素架橋ロジウム四核錯体の合成2017

    • Author(s)
      富永哲也, 片岡祐介, 矢野なつみ, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] ジカルボン酸架橋配位子を有するDimer-of-Dimer型ロジウム四核錯体の合成2017

    • Author(s)
      荒川和樹, 植田 光, 片岡祐介, 川本達也, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] アーチ型ジカルボン酸配位子を有するロジウム多核錯体の合成と水からの光水素発生2017

    • Author(s)
      植田 光, 片岡祐介, 矢野なつみ, 川本達也, 半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] カルボン酸架橋ランタン型ルテニウム(II,III)二核錯体の磁気的性質および電気化学的性質に及ぼす軸配位子の影響2017

    • Author(s)
      半田 真,矢入永基,矢野なつみ,満身 稔,崎山博史,三橋了爾,御厨正博,赤司治夫,片岡祐介
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] Half-Paddlewheel型ロジウム二核錯体による水の光還元反応と水素発生メカニズム2017

    • Author(s)
      矢野なつみ,片岡祐介,川本達也,半田 真
    • Organizer
      2017年日本化学会中国四国支部大会, 2017年11月11日~12日, 鳥取 (鳥取大学)
    • Related Report
      2017 Research-status Report
  • [Presentation] Dinuclear Ruthenum(II,III) Acetate: An Ionic Coordination Compound as Copper Acetate Analogue2017

    • Author(s)
      Masahiro Mikuriya, Makoto Handa
    • Organizer
      The 1st International Symposium on Coordination Ionic Compounds, Osaka University, Toyonaka, Japan, Dec. 15, 2017
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Metal Complexes with organic tridentate thiolic ligands2016

    • Author(s)
      Masahiro Mikuriyam Takanori, Kotera, and Makoto Handa
    • Organizer
      XXth International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz, Poland
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Polymorphism in tetranuclear vanadium complexes with 2,6-bis(hydroxymethyl)- 4-methylphenol2016

    • Author(s)
      Masahiro Mikuriya, Masataka Omote, Masami Fukutani, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, and Makoto Handa
    • Organizer
      XXth International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz, Poland
    • Year and Date
      2016-12-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photofunctional Properties of Cyclometalated Iridium Complexes Prepared via Postsynthetic Modification2016

    • Author(s)
      Yusuke Kataoka, Kaede Okuno, Natsumi Yano, Tatsuya Kawamoto, and Makoto Handa
    • Organizer
      10th Anniversary International Symposium on Nanomedicine
    • Place of Presentation
      産業技術総合研究所(筑波)
    • Year and Date
      2016-11-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Molecular Assembly in Tetranuclear Vanadium Complexes with 2,6-Bis(hydroymethyl)-4-methylphenol2016

    • Author(s)
      Masahiro Mikuriya, Masataka Omote, Masami Fukutani, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, and Makoto Handa
    • Organizer
      The 24th International SPACC Symposium
    • Place of Presentation
      岡山理科大学(岡山)
    • Year and Date
      2016-11-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 四核オキシドバナジウム錯体の結晶構造と窒素吸着特性2016

    • Author(s)
      御厨正博, 表 正高, 福谷 正美,吉岡大輔,三橋了爾,田中秀和,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 酢酸ルテニウム二核とテトラシアニドパラジウム(II)酸の混合金属錯体の合成と性質2016

    • Author(s)
      御厨正博, 河内 峻, 吉岡大輔,三橋了爾,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] パドルホイール型ベンズアミジナート 架橋ルテニウム二核錯体の結晶構造と電子状態2016

    • Author(s)
      三上沙紀,片岡祐介,川本達也, 御厨正博,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 合成後修飾法による新規燐光性シクロ メタレートイリジウム錯体の合成と光機能性2016

    • Author(s)
      奥野 楓,片岡祐介,矢野なつみ,川本達也,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Dimer-of-Dimer 型ロジウム四核錯体の合成と水からの光水素発生反応2016

    • Author(s)
      植田 光,片岡祐介,矢野なつみ,川本達也,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Anchor 型ロジウム二核錯体による高効率な水の光還元反応2016

    • Author(s)
      矢野なつみ,片岡祐介, 川本達也,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] 芳香環架橋配位子を有するPaddlewheel型ロジウム二核錯体の合成と水からの光水素発生反応2016

    • Author(s)
      福本頼輝,片岡祐介,矢野なつみ,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] カルボン酸架橋ランタン型ルテニウム (II,III)二核錯体の電気化学的性質に及ぼす軸配位子の影響2016

    • Author(s)
      矢入永基, 矢野なつみ, 河内 峻, 御厨正博,片岡祐介,半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] シクロメタレート型ロジウム二核錯体の合成と水からの光水素発生反応2016

    • Author(s)
      越猪昂幸,片岡祐介,矢野なつみ, 半田 真
    • Organizer
      2016年日本化学会中国四国支部大会
    • Place of Presentation
      香川大学(高松)
    • Year and Date
      2016-11-05
    • Related Report
      2016 Research-status Report
  • [Presentation] NNS型三座配位子のコバルト錯体の結晶構造とDFT計算2016

    • Author(s)
      小寺孝範,藤田篤史,御厨正博,半田 真
    • Organizer
      日本コンピュータ化学会2016秋季年会
    • Place of Presentation
      島根大学(松江)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Research-status Report
  • [Presentation] 多孔性配位高分子における二核金属骨格の構造安定性に関する理論的研究2016

    • Author(s)
      矢野なつみ,片岡祐介,半田 真
    • Organizer
      日本コンピュータ化学会2016秋季年会
    • Place of Presentation
      島根大学(松江)
    • Year and Date
      2016-10-22
    • Related Report
      2016 Research-status Report
  • [Remarks] 無機化学1研究室(半田研究室)

    • URL

      http://www.ipc.shimane-u.ac.jp/inorganic_chem_lab/Home.html

    • Related Report
      2017 Research-status Report

URL: 

Published: 2016-10-24   Modified: 2020-03-30  

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