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Development of Non-noble Metal Complex-based Electrode of Fuel Cell

Research Project

Project/Area Number 16K05727
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKyushu University

Principal Investigator

Matsumoto Takahiro  九州大学, 工学研究院, 准教授 (90570987)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2018: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords分子触媒 / 酵素モデル / 燃料電池 / 水素 / 酸素 / 合成化学 / 生物無機化学 / バイオミメティクス
Outline of Final Research Achievements

Resources, environment, and energy issues should be urgently needed to solve. A fuel cells are clean devices whose emission is only water, and can be expected to replace thermal power generation and nuclear power generation. There are several fuel cells, in particular, a polymer electrolyte fuel cell, which has a large power density and can be miniaturized, is useful as a mobile power source, and has recently been mounted in automobiles for practical use. However, platinum is still used for the electrode catalyst. Platinum should not be practically used because it is scarce and expensive. In this study, we succeeded in the development of a non-platinum-based molecular fuel cell by learning natural enzymes that can active hydrogen, oxygen, carbon monoxide, and hydrogen peroxide.

Academic Significance and Societal Importance of the Research Achievements

固体高分子形燃料電池は、自動車や家庭用電源のような小型移動用電源として実用化されつつあるが、現状ではいくつか問題点がある:(1)電極触媒に枯渇性資源の白金を使用していること、(2)水素に極微量含まれる一酸化炭素でアノード触媒が被毒されてしまうこと、(3)酸素の不完全還元から生成される過酸化水素が高酸化力を持つオキシラジカルに変換し、電極や固体高分子膜を分解することである。本研究の成果は、これらの問題に対し、自然界に存在する酵素から学び、その解決の糸口を見つけるものであり、今後の燃料電池開発事業の糧になるものと思われる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (19 results)

All 2018 2017 2016 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 5 results,  Invited: 5 results) Remarks (1 results)

  • [Journal Article] Multifunctional Catalysts for H2O2-resistant Hydrogen Fuel Cells2018

    • Author(s)
      Mori, Yuki; Ando, Tatsuya; Matsumoto, Takahiro; Yatabe, Takeshi; Kikkawa, Mitsuhiro; Yoon, Ki-Seok; Ogo, Seiji
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 57 Issue: 48 Pages: 34-36

    • DOI

      10.1002/anie.201810270

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Oxidation of Guanosine Monophosphate with O2 via a Ru-peroxo Complex in Water2018

    • Author(s)
      Takenaka, Makoto; Kikkawa, Mitsuhiro; Matsumoto, Takahiro; Yatabe, Takeshi; Ando, Tatsuya; Yoon, Ki-Seok; Ogo, Seiji
    • Journal Title

      Chem. Asian J.

      Volume: 13 Issue: 21 Pages: 3180-3184

    • DOI

      10.1002/asia.201801267

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A MnI Model for the Photoinhibited Species of Oxygen-Evolving Complex.2018

    • Author(s)
      Yatabe, Takeshi; Tokunaga, Taisuke; Matsumoto, Kikkawa, Mitsuhiro; Tatsuya; Yoon, Ki-Seok; Ogo, Seiji.
    • Journal Title

      Chem. Lett.

      Volume: 47 Issue: 1 Pages: 34-36

    • DOI

      10.1246/cl.170869

    • NAID

      130006302110

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Luminescent Tb(III) and Sm(III) Complexes with a 1,4,7-Triazacyclononane-based Tris-aryloxide Ligand for High-performance Oxygen Sensors.2017

    • Author(s)
      Nakai, Hidetaka;* Kuyama, Masafumi; Seo, Juncheol; Goto, Takahiro; Matsumoto, Takahiro; Ogo, Seiji.
    • Journal Title

      Dalton Trans.

      Volume: 46 Issue: 28 Pages: 9126-9130

    • DOI

      10.1039/c7dt01388d

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] One Model, Two Enzymes: Activation of Hydrogen and Carbon Monoxide.2017

    • Author(s)
      Ogo, Seiji; Mori, Yuki; Ando, Tatsuya; Matsumoto, Takahiro; Yatabe, Takeshi; Yoon, Ki-Seok; Hayashi, Hideki; Asano, Masashi.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 33 Pages: 9723-9726

    • DOI

      10.1002/anie.201704864

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Fusion of Biomimetic Fuel and Solar Cells Based on Hydrogenase, Photosystem II, and Cytochrome c Oxidase.2017

    • Author(s)
      Kikkawa, Mitsuhiro; Yatabe, Takeshi; Matsumoto, Takahiro; Yoon, Ki-Seok; Suzuki, Kazuhau; Enomoto, Takao; Kaneko, Kenji; Ogo, Seiji.
    • Journal Title

      ChemCatChem

      Volume: 9 Issue: 21 Pages: 4024-4028

    • DOI

      10.1002/cctc.201700995

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Insight into Switching between H2- or O2-Activation by Simple Ligand Effects of [NiFe]hydrogenase Models.2017

    • Author(s)
      Matsumoto, Takahiro; Kishima, Takahiro; Yatabe, Takeshi; Yoon, Ki-Seok; Ogo, Seiji.
    • Journal Title

      Organometallics

      Volume: 36 Issue: 20 Pages: 3883-3890

    • DOI

      10.1021/acs.organomet.7b00471

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Investigation of the Formation of H2 from HCOOH with a Dinuclear Ru Model Complex for Formate Hydrogen Lyase.2017

    • Author(s)
      Tokunaga, Taisuke; Yatabe, Takeshi; Matsumoto, Takahiro; Ando, Tatsuya; Yoon, Ki-Seok; Ogo, Seiji.
    • Journal Title

      Sci. Tech. Adv. Mater.

      Volume: 18 Issue: 1 Pages: 870-876

    • DOI

      10.1080/14686996.2017.1379857

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structure and Reactivity of a Ru-based Peroxide Complex as a Reactive Intermediate of O2-Promoted Activation of a C-H Bond in a Cp* Ligand.2017

    • Author(s)
      Yatabe, Takeshi; Kishima, Takahiro; Nagano, Hideaki; Matsumoto, Takahiro; Yamasaki, Mikio; Yoon, Ki-Seok; Ogo, Seiji
    • Journal Title

      Chemistry Letters

      Volume: 46 Issue: 1 Pages: 74-76

    • DOI

      10.1246/cl.160909

    • NAID

      130005308316

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Inorganic Clusters with a [Fe2MoOS3] Core―A Functional Model for Acetylene Reduction by Nitrogenases2016

    • Author(s)
      Yoshimoto, Koji; Yatabe, Takeshi; Matsumoto, Takahiro; Tran, Viet-Ha; Robertson, Andrew; Nakai, Hidetaka; Asazawa, Koichiro; Tanaka, Hirohisa; Ogo, Seiji
    • Journal Title

      Dalton Trans.

      Volume: 45(37) Issue: 37 Pages: 14620-14627

    • DOI

      10.1039/c6dt01655c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Mechanistic Investigation of Switching between H2- or O2-Activation by [NiFe]hydrogenase Models2018

    • Author(s)
      松本崇弘
    • Organizer
      43rd International Conference on Coordination Chemistry (ICCC2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] H2 and O2 Activation by [NiFe]hydrogenase Models2018

    • Author(s)
      松本崇弘
    • Organizer
      The 13th International Symposium on Organic Reactions (ISOR-13)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 自然に学ぶ分子燃料電池の開発2017

    • Author(s)
      松本 崇弘
    • Organizer
      nano tech 2017-第16回国際ナノテクノロジー総合展・技術会議-
    • Place of Presentation
      東京ビッグサイト(東京都江東区)
    • Year and Date
      2017-02-15
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Mechanistic Insight into Switching between H2- or O2-Activation by Simple Ligand Effects of [NiFe]hydrogenase Models2017

    • Author(s)
      松本崇弘
    • Organizer
      第67回錯体化学会討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] H2 and O2 Activation by a Hydrogenase Model2017

    • Author(s)
      松本 崇弘
    • Organizer
      I2CNER International Workshop 2016 Natural and Chemical Catalysts for Technology
    • Place of Presentation
      九州大学(福岡県福岡市)
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Hydrogenase and its Mimics for Fuel Cell Electrodes2016

    • Author(s)
      松本 崇弘
    • Organizer
      8th Asian Biological Inorganic Chemistry Conference (AsBIC8)
    • Place of Presentation
      The University of Auckland(ニュージーランド、オークランド)
    • Year and Date
      2016-12-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 分子燃料電池-ヒドロゲナーゼを範とする水素と酸素の活性化-2016

    • Author(s)
      松本 崇弘
    • Organizer
      第66回錯体化学会討論会
    • Place of Presentation
      福岡大学(福岡県福岡市)
    • Year and Date
      2016-09-10
    • Related Report
      2016 Research-status Report
  • [Presentation] Hydrogenase and its Mimics for Fuel Cell Electrodes2016

    • Author(s)
      松本 崇弘
    • Organizer
      42nd International Conference on Coordination Chemistry (ICCC-42) Activation of Small Molecules
    • Place of Presentation
      Le Quartz Convention Center(フランス、ブレスト)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] 九州大学大学院工学研究院小江研究室ホームページ

    • URL

      http://web.cstm.kyushu-u.ac.jp/ogo/

    • Related Report
      2018 Annual Research Report 2017 Research-status Report 2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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