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Disappearance of the quantum spin liquid state in dimer-Mott insulators by disorder

Research Project

Project/Area Number 16K05747
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionUniversity of Yamanashi

Principal Investigator

YONEYAMA Naoki  山梨大学, 大学院総合研究部, 教授 (80312643)

Research Collaborator ENOMOTO Masaya  
ASHIZAWA Norihiro  
NISHIMURA Yuma  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2017: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords量子スピン液体 / ダイマーモット絶縁体 / 真性モット絶縁体 / 化学圧力 / 部分分子置換 / 有機導体 / 強相関電子系
Outline of Final Research Achievements

Quantum spin liquid (QSL) is a fluid-like state of magnetic spins fluctuating down to low temperatures, which is remarkable for the application to micro storage medium. It has been known that the QSL state is realized in an organic crystal. By means of the resistivity measurement under pressure, we have clarified the mechanism of the destruction of the QSL state by introducing impurity.

Academic Significance and Societal Importance of the Research Achievements

本研究では,不純物分子による量子スピン液体状態の壊れ方が不純物分子の大きさによって異なることを検証した.母体結晶中の有機分子よりも小さい分子を不純物としたときは結晶中の“乱れ”によって,逆に大きい分子の場合は結晶内部に“実効的な圧力”が加わった状態になることで,量子スピン液体状態が壊れてしまう.このことは量子スピン液体状態を制御・応用するための将来的指針となると思われる.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (7 results)

All 2019 2018 2017 Other

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Dimer-Mott and charge-ordered insulating states in the quasi-one-dimensional organic conductors delta(P)'- and delta(C)'-(BPDT-TTF)(2)ICl22017

    • Author(s)
      Kobayashi, R. and Hashimoto, K. and Yoneyama, N. and Yoshimi, K. and Motoyama, Y. and Iguchi, S. and Ikemoto, Y. and Moriwaki, T. and Taniguchi, H. and Sasaki, T.
    • Journal Title

      Physical Review B

      Volume: 96 Issue: 11 Pages: 1151121-8

    • DOI

      10.1103/physrevb.96.115112

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Presentation] X-ray irradiation effect on a genuine organic Mott insulator (BEDT-TTF)Cu[N(CN)2]2: II2019

    • Author(s)
      M. K. Nuryadin, S. Iguchi, K. Hashimoto, K. Itoh, N. Yoneyama, T. Moriwaki, Y. Ikemoto, T. Sasaki
    • Organizer
      日本物理学会 第74回年次大会(2019年)
    • Related Report
      2018 Annual Research Report
  • [Presentation] 部分分子置換したk-(ET)2Cu2(CN)3における高圧下電気抵抗率2018

    • Author(s)
      芦沢方大,米山直樹,長尾雅則,田中功,佐々木孝彦
    • Organizer
      日本物理学会2018年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] X-ray irradiation effect on a genuine organic Mott insulator (BEDT-TTF)Cu[N(CN)2]22018

    • Author(s)
      M. K. Nuryadin, S. Iguchi, K. Hashimoto, N. Yoneyama, T. Moriwaki, Y. Ikemoto, T. Sasaki
    • Organizer
      日本物理学会2019年秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 擬一次元有機伝導体beta-(BPDT-TTF)2X(X=IBr2, AuBr2)の電気抵抗と静磁化率2017

    • Author(s)
      岡根由紘,米山直樹,武井貴弘,熊田伸弘,小林亮太,橋本顕一郎,佐々木孝彦
    • Organizer
      第11回分子科学討論会2017仙台
    • Related Report
      2017 Research-status Report
  • [Presentation] S=1/2一次元反強磁性鎖を有する(BEDT-TTF)Cu[N(CN)2]2の静磁化率2017

    • Author(s)
      米山直樹,赤池佳亮,手塚健太,武井貴弘,熊田伸弘,佐々木孝彦
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Research-status Report
  • [Remarks] 米山研究室:研究内容

    • URL

      http://www.ccn.yamanashi.ac.jp/~nyoneyama/research.html

    • Related Report
      2018 Annual Research Report 2017 Research-status Report 2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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