| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
In order to develop a novel method for synthesis of pi-conjugated molecules, regioselective and direct functionalization of C-H bonds was studied by using dinuclear palladium complexes as catalysts. Several novel regioselective arylation reactions of various heteroaromatics were found. Based on the results, the alkynylation and alkenylation reactions were also developed. By using dinuclear palladium complexes as catalysts, beta-selectivity, for which there have been few reports, was achieved.
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