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Development of Asymmetric Reactions Based on the Chirality Transfer from Chiral Solvents to Helical Polymers

Research Project

Project/Area Number 16K05796
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionKyoto University

Principal Investigator

Nagata Yuuya  京都大学, 工学研究科, 助教 (60512762)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsらせん高分子 / 不斉合成 / キラル溶媒 / 不斉触媒 / 不斉転写 / 高分子不斉触媒 / ポリ(キノキサリン-2,3-ジイル) / 高分子合成 / 合成化学 / 高分子構造・物性 / 有機化学 / 構造・機能材料
Outline of Final Research Achievements

Although some attempts to obtain optically active products have already been made using chiral compounds as solvents, examples exhibiting high enantioselectivities are still limited. In this study, we have tried to develop asymmetric reactions based on the chirality transfer from chiral solvents to the macromolecular backbones. Firstly, we have demonstrated that the induction of the single-handed conformation of polymer-based catalysts. Consequently, high enantioselectivities were observed in various catalytic reactions using the single-handed polymer-based catalysts.

Academic Significance and Societal Importance of the Research Achievements

本研究において開発した方法は、多段階を必要とする従来の触媒的不斉合成法と比較して、キラル化合物を溶媒として用いるだけで高い純度でキラリティの制御された生成物を得られる点において、極めて革新的な方法である。本成果は、キラリティの制御された医薬品や農薬の工業的合成のほか、キラル液晶を用いたコピー防止印刷やバイオ研究用試薬等の効率的な開発に応用されることが期待されるとともに、安価なキラルバイオマス資源を有効に活用する、新たな指針を示すものとして期待される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (103 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (11 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 4 results,  Open Access: 2 results) Presentation (88 results) (of which Int'l Joint Research: 31 results,  Invited: 25 results) Remarks (3 results)

  • [Int'l Joint Research] Institut Laue-Langevin(フランス)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Telechelic Helical Poly(quinoxaline-2,3-diyl)s Containing a Structurally Defined, Circularly Polarized Luminescent Terquinoxaline Core: Synthesis by Core-Initiated Bidirectional Living Polymerization2019

    • Author(s)
      Shogo Kuriyama, Yuuya Nagata, and Michinori Suginome
    • Journal Title

      ACS Macro Lett.

      Volume: 8 Issue: 4 Pages: 479-485

    • DOI

      10.1021/acsmacrolett.9b00165

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A bidirectional screw-sense induction of poly(quinoxaline-2,3-diyl)s that depends on the degree of polymerization2018

    • Author(s)
      Nagata Yuuya、Nishikawa Tsuyoshi、Terao Ken、Hasegawa Hirokazu、Suginome Michinori
    • Journal Title

      Journal of Polymer Science Part A: Polymer Chemistry

      Volume: 57 Issue: 3 Pages: 260-263

    • DOI

      10.1002/pola.29224

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Planar-Chiral Pillar[5]arene-Based Monophosphine Ligand with Induced Chirality at the Biaryl Axis2018

    • Author(s)
      Yuuya Nagata, Yasuo Shimada, Tsuyoshi Nishikawa, Ryohei Takeda, Makoto Uno, Tomoki Ogoshi, and Michinori Suginome
    • Journal Title

      Synlett

      Volume: 29 Issue: 16 Pages: 2167-2170

    • DOI

      10.1055/s-0037-1610635

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elucidating the Solvent Effect on the Switch of the Helicity of Poly(quinoxaline-2,3-diyl)s: A Conformational Analysis by Small-Angle Neutron Scattering2018

    • Author(s)
      Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome, Sota Sato, Masaaki Sugiyama, Lionel Porcar, Anne Martel, Rintaro Inoue, and Nobuhiro Sato
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 140 Issue: 8 Pages: 2722-2726

    • DOI

      10.1021/jacs.7b11626

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Poly(quinoxaline-2,3-diyl) as a Multifunctional Chiral Scaffold for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of the CPL Handedness2017

    • Author(s)
      Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
    • Journal Title

      ACS Macro Lett.

      Volume: 6 Issue: 4 Pages: 431-431

    • DOI

      10.1021/acsmacrolett.7b00131

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Solution Properties of a Rigid Helical Star Polymer: Three-Arm Star Poly(quinoxaline-2,3-diyl)2017

    • Author(s)
      Hirokazu Hasegawa, Yuuya Nagata, Ken Terao, and Michinori Suginome
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 19 Pages: 7491-7497

    • DOI

      10.1021/acs.macromol.7b01797

    • NAID

      120007053184

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Catalytic Applications of a Triptycene-Based Monophosphine Ligand for Palladium-Mediated Organic Transformations2017

    • Author(s)
      Franco King-Chi Leung, Fumitaka Ishiwari, Yoshiaki Shoji, Tsuyoshi Nishikawa, Ryohei Takeda, Yuuya Nagata, Michinori Suginome, Yasuhiro Uozumi, Yoichi M. A. Yamada, and Takanori Fukushima
    • Journal Title

      ACS Omega

      Volume: 2 Issue: 5 Pages: 1930-1937

    • DOI

      10.1021/acsomega.7b00200

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Synthesis of Enantiopure C3-Symmetric Triangular Molecules2017

    • Author(s)
      Tomoya Miura, Takayuki Nakamuro, Scott G. Stewart, Yuuya Nagata, and Masahiro Murakami
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 12 Pages: 3334-3338

    • DOI

      10.1002/anie.201612585

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Solvent Effect on the Sergeants-and-Soldiers Effect Leading to Bidirectional Induction of Single-Handed Helical Sense of Poly(quinoxaline-2,3-diyl)s Copolymers in Aromatic Solvents2016

    • Author(s)
      Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome
    • Journal Title

      ACS Macro Lett.

      Volume: 5 Issue: 4 Pages: 519-522

    • DOI

      10.1021/acsmacrolett.6b00191

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Three-Way-Switchable (Right/Left/OFF) Selective Reflection of Circularly Polarized Light on Solid Thin Films of Helical Polymer Blends2016

    • Author(s)
      Yuuya Nagata, Makoto Uno, and Michinori Suginome
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 55 Issue: 25 Pages: 7126-7130

    • DOI

      10.1002/anie.201602035

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] High-Pressure Circular Dichroism Spectroscopy up to 400 MPa Using Polycrystalline Yttrium Aluminum Garnet (YAG) as Pressure-Resistant Optical Windows2016

    • Author(s)
      Yuuya Nagata, Ryohei Takeda, and Michinori Suginome
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 111 Pages: 109726-109729

    • DOI

      10.1039/c6ra23736c

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] キラリティスイッチング型機能性材料開発における超臨界流体クロマトグラフィーの活用2019

    • Author(s)
      ◯長田裕也
    • Organizer
      第18回SFC研究会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 非共有結合型相互作用に基づいたアキラルらせん高分子への高効率不斉誘起2019

    • Author(s)
      ◯長田裕也
    • Organizer
      分子研研究会「錯体化学を基盤とした階層構造制御と機能発現」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 中性子小角散乱/中性子準弾性散乱測定を用いた高分子主鎖の溶媒依存性らせん反転の原理解明2019

    • Author(s)
      ◯長田裕也
    • Organizer
      2018量子ビームサイエンスフェスタ
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 中性子科学が照らし出す新規キラル材料創出の最前線2019

    • Author(s)
      ◯長田裕也
    • Organizer
      日本物理学会 第74回年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アキラルカルボン酸側鎖を有するポリ(キノキサリン-2,3-ジイル)のキラルアミン類とのイオン性相互作用による高効率主鎖らせん不斉誘起2019

    • Author(s)
      長田 裕也・◯山脇 大昇・黒田 拓馬・杉野目 道紀
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 水溶性らせん高分子配位子を用いた水中不斉鈴木-宮浦クロスカップリング反応による軸不斉ビアリール化合物の高エナンチオ選択的触媒的不斉合成2019

    • Author(s)
      長田裕也、○神谷尚明、杉野目道紀
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] キラル溶媒蒸気によるアキラルポリ(キノキサリン-2,3-ジイル)主鎖不斉らせん誘起に基づいたコレステリック型超構造の形成2019

    • Author(s)
      長田 裕也・◯足利 駿輔・杉野目 道紀
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然アミノ酸誘導体とアキラルポリ(キノキサリン-2,3-ジイル)間の非結合性相互作用による主鎖らせん不斉誘起とその触媒的不斉合成への応用2019

    • Author(s)
      長田裕也、○池田翔真、杉野目道紀
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Elucidation of the mechanism of the solvent-dependent helix inversion of poly(quinoxaline-2,3-diyl)s2019

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      日本化学会 第99春季年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] らせん高分子ポリ(キノキサリン-2,3-ジイル)の主鎖不斉構造の自在制御と新機能の創出2019

    • Author(s)
      ◯長田裕也
    • Organizer
      日本薬学会 第139年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of New Chiral Materials Based on the Control of Macromolecular Helix Sense2018

    • Author(s)
      ◯長田裕也
    • Organizer
      微生物化学研究所 柴崎コロキウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子の主鎖らせん反転に基づいた新規キラルマテリアルの創出2018

    • Author(s)
      ◯長田裕也
    • Organizer
      高分子同友会勉強会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子主鎖の自在らせん不斉制御に基づいたキラル機能性材料の創出2018

    • Author(s)
      ◯長田裕也
    • Organizer
      第6回慶應有機化学若手シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] コレステリック構造を有するポリキノキサリン薄膜の円偏光選択反射特性:溶媒蒸気及び側鎖末端置換基の影響2018

    • Author(s)
      長田 裕也・◯足利 駿輔・近藤 弘紀・杉野目 道紀
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子主鎖らせん不斉の自在制御に基づいたキラリティスイッチング型機能性材料の創出2018

    • Author(s)
      ◯長田裕也
    • Organizer
      錯体化学若手の会・近畿支部勉強会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] らせん高分子主鎖のキラリティスイッチングに基づいた不斉機能性材料の創出2018

    • Author(s)
      ◯長田裕也
    • Organizer
      第90回高分子若手研究会【関西】
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光学活性アミノ酸誘導体からの非結合性相互作用を用いたアキラルポリ(キノキサリン-2,3-ジイル)の高効率主鎖らせん不斉誘起2018

    • Author(s)
      長田裕也、○池田翔真、杉野目道紀
    • Organizer
      第38回有機合成若手セミナー「明日の有機合成を担う人のために」
    • Related Report
      2018 Annual Research Report
  • [Presentation] 面性不斉四置換[2.2]パラシクロファンを用いるV 字型光学活性化合物の合成2018

    • Author(s)
      ○菊池克彰・中村純・土田啓・角田貴洋・生越友樹・長田裕也・森崎泰弘
    • Organizer
      第29回基礎有機化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 光学活性二次構造を制御したπ 電子系の積層2018

    • Author(s)
      ◯森崎泰弘・菊池克彰・中村純・土田啓・角田貴洋・ 生越友樹・長田裕也
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 非結合性相互作用によるキラリティ転写に基づいたアキラルポリ(キノキサリン-2,3-ジイル)の主鎖らせん不斉誘起2018

    • Author(s)
      ◯長田裕也・池田翔真・杉野目道紀
    • Organizer
      第67回高分子討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] キラル溶媒からアキラルらせん高分子配位子への不斉転写に基づいた高選択的不斉触媒反応2018

    • Author(s)
      ◯長田裕也・竹田 龍平・杉野目 道紀
    • Organizer
      第65回有機金属化学討論会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 中性子準弾性散乱測定を用いた溶媒依存性らせん反転を示すらせん高分子の分子ダイナミクスの解明2018

    • Author(s)
      ◯長田裕也
    • Organizer
      DIRECTION2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ポリ(キノキサリン-2,3-ジイル)の主鎖らせん不斉制御に基づいた新規キラルマテリアルの創出2018

    • Author(s)
      ◯長田裕也
    • Organizer
      中国四国支部 高分子材料研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 天然アミノ酸誘導体からの不斉転写に基づいたアキラルポリ(キノキサリン-2,3-ジイル)の高効率主鎖らせん不斉誘起2018

    • Author(s)
      長田裕也、○池田翔真、杉野目道紀
    • Organizer
      第8回 CSJ化学フェスタ
    • Related Report
      2018 Annual Research Report
  • [Presentation] 乳酸由来キラル側鎖を持つ水溶性らせん高分子を用いた水中不斉鈴木-宮浦クロスカップリング反応2018

    • Author(s)
      長田裕也、○神谷尚明、杉野目道紀
    • Organizer
      第8回CSJ化学フェスタ2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 溶媒依存性主鎖らせん反転に基づいた新規キラルマテリアルの創出(どうやってらせんをひっくり返すか、ひっくりかえしてどうするか)2018

    • Author(s)
      ◯長田裕也
    • Organizer
      錯体化学若手の会北陸支部勉強会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 中性子準弾性散乱を用いた高分子主鎖溶媒依存性らせん反転現象の機構解明2018

    • Author(s)
      ◯長田裕也・杉野目道紀・富永大輝・井上倫太郎・杉山正明
    • Organizer
      日本中性子科学会 第18回年会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 主鎖らせん反転に基づいた新規キラルマテリアルの創出:小さな偶然の種を育てる話2018

    • Author(s)
      ◯長田裕也
    • Organizer
      ITbM/IGER Chemistry Workshop 2018
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] 高分子主鎖らせん不斉の自在制御に基づいた新規キラルマテリアルの創出2018

    • Author(s)
      ○長田裕也
    • Organizer
      2018KIPS若手シンポジウム
    • Related Report
      2018 Annual Research Report
  • [Presentation] L-乳酸由来キラル側鎖を有する水溶性らせんポリマー触媒を用いた水中不斉鈴木-宮浦クロスカップリング反応2018

    • Author(s)
      長田裕也・○神谷尚明・杉野目道紀
    • Organizer
      2018KIPS若手シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Circularly Polarized Selective Reflection Properties of Poly(quinoxaline-2,3-diyl)s Forming Cholesteric Superstructure: Effect of the Solvent Vapors and the Substituents on the Side Chains2018

    • Author(s)
      Yuuya Nagata, ◯Shunsuke Ashikaga, Hiroki Kondo, Michinori Suginome
    • Organizer
      Chirality 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Poly(quinoxaline-2,3-diyl)s with a Sequence-controlled Terquinoxaline Core and Their Circularly Polarized Luminescent Properties2018

    • Author(s)
      ○Shogo Kuriyama, Yuuya Nagata, Michinori Suginome
    • Organizer
      Chirality 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New Chiral Amplification System Using Helical Macromolecular Catalysts Based on the Feedback of the Reaction Product2018

    • Author(s)
      Yuuya Nagata, ◯Takuya Nakagawa, Fumiko Miyata,and Michinori Suginome
    • Organizer
      4th International Conference on Organometallic and Catalysis 2018 (OM&Cat 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] New Chiral Amplification System Using Helical Polymer Catalyst Based on the Feedback of the Reaction Products2018

    • Author(s)
      ◯Yuuya Nagata, Fumiko Miyata,and Michinori Suginome
    • Organizer
      4th Molecular Chirality Asia (MCAsia 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] An Efficient Chirality Transfer from Chiral Amino Acid Derivatives to Achiral Poly(quinoxaline-2,3-diyl)s2018

    • Author(s)
      Yuuya Nagata, ○Shoma Ikeda,and Michinori Suginome
    • Organizer
      4th Molecular Chirality Asia (MCAsia 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Asymmetric Suzuki-Miyaura Cross-coupling Reaction in Water with a Water-soluble Chiral Helical Polymer LigandBearing Chiral Side Chains Derived from L-Lactic Acid2018

    • Author(s)
      Yuuya Nagata, ○Naoaki Kamiya, Michinori Suginome
    • Organizer
      4th Molecular Chirality Asia (MCAsia 2018)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Elucidation of Molecular Dynamics of Poly(quinoxaline-2,3-diyl)s Exhibiting Solvent-dependent Helix Inversion Through Quasielastic Neutron Scattering Measurements2018

    • Author(s)
      ◯Yuuya Nagata, Michinori Suginome, Taiki Tominaga, Rintaro Inoue, Sugiyama Masaaki
    • Organizer
      QENS/WINS 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of new chirality-switchable polymeric materials based on the solvent-dependent helix inversion of the macromolecular helicity2018

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      ACS meeting 256
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Chirality-switchable Functional Materials Based on the Solvent-dependent Inversion of the Main-Chain Helical Chirality2018

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      9th Joint CSJ RSC Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of New Chirality-switchable Functional Materials Based on the Solvent-dependent Inversion of Poly(quinoxaline-2,3-diyl)s2018

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      Universitat Hamburg - Kyoto University Symposium 2018
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Circularly Polarized Selective Reflection Properties of Thin Films of Poly(quinoxaline-2,3-diyl)s Forming Cholesteric Superstructure: Effect of the Solvent Vapors and the Substituents on the Side Chains2018

    • Author(s)
      Yuuya Nagata, ◯Shunsuke Ashikaga, Hiroki Kondo, Michinori Suginome
    • Organizer
      The 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] An Efficient Chirality Transfer from Chiral Amino Acid Derivatives to Achiral Poly(quinoxaline-2,3-diyl)s2018

    • Author(s)
      Yuuya Nagata, 〇Shoma Ikeda, Michinori Suginome
    • Organizer
      The 8th Spanish-Portuguese-Japanese Organic Chemistry Symposium
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 小角中性子散乱を用いた高分子主鎖の溶媒依存性反転の機構解明2018

    • Author(s)
      ◯長田裕也・西川剛・杉野目道紀・杉山正明・井上倫太郎・佐藤信浩・佐藤宗太・Lionel Porcar・Anne Martel
    • Organizer
      京都大学原子炉実験所 第52回学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 高分子主鎖らせんキラリティの自在制御を可能とする分子技術とその新材料開発への応用2018

    • Author(s)
      ◯長田裕也
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Synthesis of Asymmetric Catalysts with an Efficient Chiral Amplification Based on the Feedback of the Reaction Products2018

    • Author(s)
      Yuuya Nagata, ◯Fumiko Miyata, Michinori Suginome
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Research-status Report
  • [Presentation] 保護天然アミノ酸からの非結合性相互作用によるキラリティ転写に基づいたアキラルポリ(キノキサリン-2,3-ジイル)の高効率主鎖らせん不斉誘起2018

    • Author(s)
      長田 裕也・〇池田 翔真・杉野目 道紀
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Research-status Report
  • [Presentation] Synthesis of Poly(quinoxaline-2,3-diyl)s with a Sequence-controlled Terquinoxaline Core through Bidirectional Living Polymerization and Their CPL Properties2018

    • Author(s)
      ◯栗山翔吾・長田裕也・杉野目道紀
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Research-status Report
  • [Presentation] 乳酸由来のキラル側鎖を有する水溶性キラルらせん高分子触媒を用いた水中不斉鈴木-宮浦クロスカップリング反応2018

    • Author(s)
      長田 裕也・○神谷 尚明・杉野目 道紀
    • Organizer
      日本化学会第98春季年会(2018)
    • Related Report
      2017 Research-status Report
  • [Presentation] Enhancing Sensitivity toward Solvent Effect in Switching Helical Sense of Poly(quinoxaline-2,3-diyl)s by Modulation of Chiral Side Chains2018

    • Author(s)
      Yuuya Nagata, Yusuke Kakihara, Tsuyoshi Nishikawa, Michinori Suginome
    • Organizer
      IUPAC-FAPS 2017 Polymer Congress
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] A New Chiral Amplification System Using Helical Polymer Catalysts Based on the Introduction of Asymmetric Reaction Products to the Side Chains2018

    • Author(s)
      Yuuya Nagata, ◯Fumiko Miyata, Michinori Suginome
    • Organizer
      JGP-Chem Kyoto-Bordeaux Faculty & Student Research Workshop on Chiral Nanostructures for Photonic Application
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Solvent Vapor Dependence on the Formation of Superstructures of Poly(quinoxaline-2,3-diyl)s Exhibiting Circularly Polarized Selective Reflection2018

    • Author(s)
      Yuuya Nagata, ◯Shunsuke Ashikaga, Hiroki Kondo, Michinori Suginome
    • Organizer
      JGP-Chem Kyoto-Bordeaux Faculty & Student Research Workshop on Chiral Nanostructures for Photonic Application
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] NEW CHIRAL AMPLIFICATION SYSTEM WITH HELICAL POLYMER CATALYSTS BASED ON THE INTRODUCTION OF ASYMMETRIC REACTION PRODUCTS TO THE SIDE CHAINS2018

    • Author(s)
      Yuuya Nagata, ◯Fumiko Miyata, and Michinori Suginome
    • Organizer
      Toyota Riken International Workshop on Chirality in Soft Matter
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] SOLVENT VAPOR DEPENDENCE ON THE FORMATION OF CHOLESTERIC STRUCTURES EXHIBITING CIRCULARLY POLARIZED SELECTIVE REFLECTION OF A POLY(QUINOXALINE-2,3-DIYL)2018

    • Author(s)
      Yuuya Nagata, ◯Shunsuke Ashikaga, Hiroki Kondo, Michinori Suginome
    • Organizer
      Toyota Riken International Workshop on Chirality in Soft Matter
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Poly(quinoxaline,2-3-diyl) as a Modular Chiral Platform for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Solvent-dependent Switch of CPL Handedness2018

    • Author(s)
      ◯Tsuyoshi Nishikawa, Yuuya Nagata, and Michinori Suginome
    • Organizer
      Toyota Riken International Workshop on Chirality in Soft Matter
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Poly(quinoxaline-2,3diyl)s as a Modular Platform for Circularly Polarized Luminescent Materials: Color Tuning, Energy Transfer, and Switching of CPL Handedness2017

    • Author(s)
      ◯NISHIKAWA Tsuyoshi, NAGATA Yuuya, SUGINOME Michinori
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] Development of Innovative Chiral Materials Based on Solvent-Dependent Helix Inversion of Macromolecular Backbone2017

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Asymmetric Catalysis through Chirality Transfer from Chiral Solvent Using Achiral Helical Macromolecule as a Catalyst2017

    • Author(s)
      NAGATA, Yuuya; ○TAKEDA, Ryohei; SUGINOME, Michinori
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] らせん高分子配位子を用いた不斉増幅:反応生成物の側鎖への導入に基づいた不斉増幅システム2017

    • Author(s)
      長田 裕也・○宮田 文子・杉野目 道紀
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] (S)-4-オクチルオキシメチル側鎖を有するポリキノキサリンの不斉らせん誘起における鋭敏な溶媒依存性を利用したらせん高分子配位子のキラリティスイッチング2017

    • Author(s)
      長田裕也◯柿原佑亮・西川剛・杉野目道紀
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] らせんポリキノキサリン薄膜の円偏光選択反射構造の形成における溶媒蒸気依存性2017

    • Author(s)
      長田 裕也・○近藤 弘紀・杉野目 道紀
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶応義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] ポリ(キノキサリン-2,3-ジイル)を基本骨格とするキラリティスイッチング型円偏光蛍光材料の発光波長制御2017

    • Author(s)
      ◯長田裕也・西川剛・杉野目道紀
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Research-status Report
  • [Presentation] ”円偏光蛍光キラリティをスイッチング”できるフルカラー発光材料2017

    • Author(s)
      ◯長田裕也
    • Organizer
      第 12 回ナノカーボン先端技術交流会
    • Related Report
      2017 Research-status Report
  • [Presentation] 高分子主鎖のキラリティスイッチングに基づいた新規機能性材料の創出2017

    • Author(s)
      ◯長田裕也
    • Organizer
      2017年液晶交流会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 混合溶媒中におけるキラル溶媒の優先溶媒和に基づいた ポリ(キノキサリン-2,3-ジイル)の不斉らせん誘起2017

    • Author(s)
      ◯長田裕也・竹田龍平・杉野目道紀
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 3 本腕星型ポリ(キノキサリン-2,3-ジイル)の溶液物性2017

    • Author(s)
      ◯長谷川 博一・寺尾 憲・長田 裕也・杉野目 道紀
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] らせん高分子配位子を用いた不斉増幅システムの構築:反応生成物の側鎖への導入に基づいた高効率不斉増幅2017

    • Author(s)
      長田 裕也・〇宮田 文子・杉野目 道紀
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] Development of New Chirality-switchable Materials Based on the Solvent-dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s2017

    • Author(s)
      ◯Yuuya Nagata
    • Organizer
      10th China-Japan Joint Symposium on Functional Supramolecular Architectures
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Helical Poly(quinoxaline-2,3-diyl)s with a Precisely Made Terquinoxaline ABA Core through Bidirectional Living Polymerization2017

    • Author(s)
      ○Shogo Kuriyama, Yuuya Nagata, Michinori Suginome
    • Organizer
      29th International Symposium on Chirality (Chirality 2017; ISCD-29)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Solvent Vapor Dependence on the Formation of Superstructures Exhibiting Circularly Polarized Selective Reflection of Poly(quinoxaline-2,3-diyl)s2017

    • Author(s)
      ◯Shunsuke Ashikaga, Hiroki Kondo, Yuuya Nagata, Michinori Suginome
    • Organizer
      29th International Symposium on Chirality (Chirality 2017; ISCD-29)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Poly(quinoxaline-2,3-diyl) as a Chirality-switchable Scaffold for Circularly Polarized Luminescent Materials2017

    • Author(s)
      ◯Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome
    • Organizer
      29th International Symposium on Chirality (Chirality 2017; ISCD-29)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Chiral Amplification Based on the Majority-rules Effect of Helical Macromloecular Catalyst PQXphos2017

    • Author(s)
      Yuuya Nagata, ◯Fumiko Miyata, Michinori Suginome
    • Organizer
      18th Tetrahedron Symposium Asia Edition
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of a New Chiral Amplification System Using Helical Polymer Catalysts Based on the Introduction of Asymmetric Reaction Products to Side Chains2017

    • Author(s)
      ◯Fumiko Miyata, Yuuya Nagata, Michinori Suginome
    • Organizer
      2017 KIPS International Symposium
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高分子主鎖らせんキラリティの自在制御に基づく新材料創出2016

    • Author(s)
      ◯長田裕也
    • Organizer
      分子研研究会 「若い世代が創る次世代型分子触媒の開発とその展望」
    • Place of Presentation
      分子科学研究所
    • Year and Date
      2016-11-10
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Chiral Amplification in Asymmeetric Synthesis Based on Majority-Rules-Type Poly(quinoxaline-2,3-diyl)s2016

    • Author(s)
      ◯Fumiko Miyata, Yuan-Zhen Ke, Tetsuya Yamada, Yuuya Nagata, Michinori Suginome
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2016
    • Place of Presentation
      Taipei, Taiwan
    • Year and Date
      2016-11-10
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] キラル側鎖構造のチューニングに基づいたポリ(キノキサリン-2,3-ジイル)の不斉らせん誘起における溶媒依存性の鋭敏化2016

    • Author(s)
      長田裕也・◯柿原佑亮・西川剛・杉野目道紀
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] 天然物由来キラル溶媒からポリキノキサリン主鎖への高効率不斉転写2016

    • Author(s)
      ○長田裕也・竹田龍平・杉野目道紀
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] Enhanced Solvent-Dependent Helix Inversion of Poly(quinoxaline-2,3-diyl)s Bearing (S)-4-Octyloxymethyl Side Chains2016

    • Author(s)
      Yuuya Nagata, ◯Yusuke Kakihara, Tsuyoshi Nishikawa, Michinori Suginome
    • Organizer
      The 3rd International Conference on Organometallics and Catalysis (OM&Cat 2016)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2016-08-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Solvent-dependent Abnormal Sergeants-and-Soldiers Effect on Poly(quinoxaline-2,3-diyl) Copolymers Enabling Bidirectional Induction of Single-Handed Helical Sense2016

    • Author(s)
      ◯Yuuya Nagata, Tsuyoshi Nishikawa, Michinori Suginome
    • Organizer
      The 28th International Symposium on Chiral Discrmination (Chirality 2016)
    • Place of Presentation
      Heidelberg, Germany
    • Year and Date
      2016-07-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Screw-sense Induction of Achiral Poly(quinoxaline-2,3-diyl)s through Chirality Transfer from Chiral Solvent2016

    • Author(s)
      Yuuya Nagata, ○Ryohei Takeda, and Michinori Suginome
    • Organizer
      The 28th International Symposium on Chiral Discrmination (Chirality 2016)
    • Place of Presentation
      Heidelberg, Germany
    • Year and Date
      2016-07-24
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 天然由来キラル溶媒中におけるアキラルポリ(キノキサリン-2,3-ジイル)への高効率キラル転写2016

    • Author(s)
      ◯竹田龍平・長田裕也・杉野目道紀
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      ANAクラウンプラザホテル神戸
    • Year and Date
      2016-06-02
    • Related Report
      2016 Research-status Report
  • [Presentation] 高分子主鎖のキラリティスイッチングに基づく新機能性材料の開拓2016

    • Author(s)
      ◯長田裕也
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場・展示場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Switch of Main-Chain Helical Chirality of Poly(quinoxaline-2,3-diyl)s Based on the Molecular Shape of Alkane Solvents2016

    • Author(s)
      Yuuya Nagata, 〇Tsuyoshi Nishikawa, Michinori Suginome
    • Organizer
      The 12th International Symposium on Organic Reaction (ISOR-12)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-04-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Pressure-Induced Helix Inversion of Poly(quinoxaline-2,3-diyl)s Bearing Chiral Side Chains2016

    • Author(s)
      ◯Yuuya Nagata, Ryohei Takeda, Michinori Suginome
    • Organizer
      Molecular Chirality Asia 2016 (MCAsia 2016)
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2016-04-20
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポリ(キノキサリン-2,3-ジイル)の主鎖らせん反転:キラル側鎖構造のチューングによる溶媒依存性の鋭敏化2016

    • Author(s)
      ◯柿原佑亮・西川 剛・長田裕也・杉野目道紀
    • Organizer
      第62回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館
    • Related Report
      2016 Research-status Report
  • [Presentation] 高分子主鎖の溶媒依存性キラリティ反転に基づいた新機能性材料開発2016

    • Author(s)
      ◯長田裕也
    • Organizer
      化学反応経路探索のニューフロンティア2016
    • Place of Presentation
      京都教育文化センター
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] らせん高分子主鎖のキラリティスイッチングに基づく新機能性材料の創出2016

    • Author(s)
      ◯長田裕也
    • Organizer
      日本化学会東北支部山形地区講演会
    • Place of Presentation
      山形大学小白川キャンパス
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] キラル側鎖の合理的設計に基づくポリ(キノキサリン-2,3-ジイル)の不斉らせん誘起における溶媒依存性の鋭敏化2016

    • Author(s)
      長田裕也・◯柿原佑亮・西川剛・杉野目道紀
    • Organizer
      2016KIPS高分子若手シンポジウム
    • Place of Presentation
      京都大学 ローム記念館
    • Related Report
      2016 Research-status Report
  • [Presentation] 光学活性溶媒から アキラルポリ(キノキサリン-2,3-ジイル)主鎖への高効率キラル転写2016

    • Author(s)
      長田 裕也, ○竹田 龍平, 杉野目 道紀
    • Organizer
      2016KIPS高分子若手シンポジウム
    • Place of Presentation
      京都大学 ローム記念館
    • Related Report
      2016 Research-status Report
  • [Remarks] 杉野目研究室

    • URL

      http://www.sbchem.kyoto-u.ac.jp/suginome-lab/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 杉野目研究室webサイト

    • URL

      http://www.sbchem.kyoto-u.ac.jp/suginome-lab/

    • Related Report
      2017 Research-status Report
  • [Remarks] 杉野目研究室

    • URL

      http://www.sbchem.kyoto-u.ac.jp/suginome-lab/jp/

    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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