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Preparation of transparent activated carbon fibers for carbon dioxide recycling

Research Project

Project/Area Number 16K05909
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionShinshu University

Principal Investigator

Hattori Yoshiyuki  信州大学, 学術研究院繊維学系, 准教授 (20456495)

Research Collaborator TANAKA Hideki  
KIMURA Mutsumi  
IIYAMA Taku  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords活性炭素繊維 / フッ素化学 / 吸着 / 二酸化炭素 / 光触媒 / 炭素繊維 / 吸着剤 / 人工光合成 / メタンハイドレート / 二酸化炭素変換 / 繊維材料
Outline of Final Research Achievements

Hollow nanoporous carbon fibers were prepared by the thermal decomposition of cotton fibers impregnated with zinc and nitrate ions. Activated carbon fibers and single walled carbon nanotubes were fluorinated by using fluorine gas. The adsorption/desorption hysteresis was observed for carbon dioxide isotherms of fluorinated ACF and SWCNT. Furthermore, the preparation of photo-catalyst nickel nanoparticles in carbon matrix was reported. The photo-catalyst showed the high photo-catalytic activity for methane production from mixed gas of carbon dioxide and hydrogen.

Academic Significance and Societal Importance of the Research Achievements

本研究で開発した中空状活性炭素繊維は、高い比表面積と細孔容量を有するため、種々の分子およびイオンを高密度に貯蔵することが可能である。また、フッ素化ナノカーボンは不可逆的な二酸化炭素吸着能を有していることも明らかにした。さらにカーボンナノ空間中に高分散されたニッケルナノ粒子は、自発性圧縮作用を利用した光触媒反応が進行したことにより、高効率にメタンへの光化学変換が可能となった。これらの学術展開は、世界の環境問題への取り組みに必要とされている、二酸化炭素のエネルギー高度利用の構築へとつながる研究開発の一助となる。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (15 results)

All 2018 2017 2016

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] Hollow structured porous carbon fibers with the inherent texture of the cotton fibers2018

    • Author(s)
      Kento Sagisaka, Atsushi Kondo, Taku Iiyama, Mutsumi Kimura, Hiroyuki Fujimoto, Hidekazu Touhara, and Yoshiyuki Hattori
    • Journal Title

      Chemical Physics Letters

      Volume: 710 Pages: 118-122

    • DOI

      10.1016/j.cplett.2018.08.081

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Restricted adsorption of carbon dioxide gas in fluorinated single-walled carbon nanotubes2018

    • Author(s)
      Yuta Sekiya, Hironori Sugiyama, Kento Sagisaka, Atsushi Kondo, and Yoshiyuki Hattori
    • Journal Title

      Fullerenes, Nanotubes and Carbon Nanostructures

      Volume: 26 Issue: 11 Pages: 746-750

    • DOI

      10.1080/1536383x.2018.1493460

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and formation mechanism of porous carbon nanosheets by thermal decomposition of polyvinyl alcohol films impregnated with zinc (II) and nitrate ions2017

    • Author(s)
      Y. Hattori, R. Kojima, K. Sagisaka, M. Umeda, T. Tanaka, A. Kondo, T. Iiyama, M. Kimura, H. Fujimoto, H. Touhara
    • Journal Title

      Solid State Science

      Volume: 65 Pages: 33-40

    • DOI

      10.1016/j.solidstatesciences.2017.01.002

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Porous Carbon Nanosheets Prepared from Cellulose Nanofibers2018

    • Author(s)
      K. Ito, K. Sagisaka, M. Kimura and Y. Hattori
    • Organizer
      8th Pacific Basin Conference on Adsorption Science and Technology
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Quantum Sieving Effect of Fluorinated Activated Carbon Fibers on Hydrogen isotope adsorption2018

    • Author(s)
      Hironori Sugiyama and Yoshiyuki Hattori
    • Organizer
      The 22nd International Symposium on Fluorine Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノグラファイトのフッ素化と構造2018

    • Author(s)
      小笠原 悠二、杉山 広忠、匂坂 憲人、服部 義之
    • Organizer
      第41回フッ素化学討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] セルロースナノファイバー由来カーボンに担持したニッケルナノ粒子の光触媒特性2018

    • Author(s)
      大山 智文,服部 義之
    • Organizer
      第45回炭素材料学会年会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Influence of fluorination on nitrogen adsorption of activated carbon fibers2018

    • Author(s)
      Hironori Sugiyama and Yoshiyuki Hattori
    • Organizer
      ISPlasma2018 / IC-PLANTS2018
    • Related Report
      2017 Research-status Report
  • [Presentation] Pore structure of Hollow Activated Carbon Fibers composed of nano-sheets structure2018

    • Author(s)
      Kento Sagisaka and Yoshiyuki Hattori
    • Organizer
      ISPlasma2018 / IC-PLANTS2018
    • Related Report
      2017 Research-status Report
  • [Presentation] Gas adsorption properties of fluorinated single-walled carbon nanotubes2017

    • Author(s)
      Yuta Sekiya and Yoshiyuki Hattori
    • Organizer
      The 6th Symposium on Future Challenges for Carbon-based Nanoporous Materials (6CBNM)
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 異なる細孔構造を有するフッ素化活性炭素繊維への窒素および二酸化炭素吸着2017

    • Author(s)
      杉山広忠、 服部義之、金子克美
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] 完全フッ素化活性炭素繊維の窒素吸着特性2017

    • Author(s)
      杉山広忠、 服部義之、金子克美
    • Organizer
      第40回フッ素化学討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] フッ素化単層カーボンナノチューブの気体吸着特性2016

    • Author(s)
      関谷勇太、杉山広忠、匂坂憲人、服部義之
    • Organizer
      第39回フッ素化学討論会
    • Place of Presentation
      アバンセ、佐賀県佐賀市
    • Year and Date
      2016-09-29
    • Related Report
      2016 Research-status Report
  • [Presentation] Preparation of porous hollow carbon fibers and their electric double layer capacitor performance2016

    • Author(s)
      K. Sagisaka, H. Touhara, H. Fujimoto, T. Iiyama, M. Kimura, Y. Hattori
    • Organizer
      2016 International Conference on Advanced Capacitors
    • Place of Presentation
      大津プリンスホテル、滋賀県大津市
    • Year and Date
      2016-05-23
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] フッ化黒鉛のRamanスペクトル2016

    • Author(s)
      川澄 直人、小笠原 悠二、杉山 広忠、匂坂 憲人、服部 義之
    • Organizer
      第39回フッ素化学討論会
    • Place of Presentation
      アバンセ、佐賀県佐賀市
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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