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Creation of Highly Selective Separation Membranes Based on Precise Design of Nanopore Structure

Research Project

Project/Area Number 16K05926
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionMie University

Principal Investigator

Fujii Yoshihisa  三重大学, 工学研究科, 准教授 (70578062)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2017: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsカーボン / 分離膜 / ナノ薄膜 / 構造・物性 / 傾斜構造膜 / プラズマCVD / ナノ細孔 / プラズマCVD / 高分子機能材料
Outline of Final Research Achievements

Nanoporous carbon membranes were successfully obtained from graphite targets by using the magnetron sputtering method at room temperature. The characteristics of the newly prepared nanoporous carbon membranes were investigated using X-ray reflectivity (XR), ellipsometry, and X-ray photoelectron spectroscopy (XPS) methods. The results indicated that the nanoporous carbon membranes possess relatively low density and refractive index, nevertheless they consist of sp3 and sp2 bonds as same as diamond-like carbon. Interestingly, our carbon membrane showed outstanding filtration properties. These filtration properties and porous structure may relate to its low density and refractive index. A more conclusive study including these effects will be reported in the near future.

Academic Significance and Societal Importance of the Research Achievements

ナノ細孔構造の精密設計に基づく高選択分離膜の創出は、「材料の構造・物性解析」と「新材料開発」および「ナノサイズにける高分子の物質透過」という新しい領域の組み合わせにより初めて実現可能である。また、動的ナノ細孔の精密設計の応用展開を分離材料に設定しているが、その基礎学理は、ほとんどの材料に応用可能であり、得られる成果は材料科学分野へ学術的に寄与する。さらに、社会的には、省エネルギー性に優れる次世代高速液相分離プロセスの普及が予想される。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (11 results)

All 2018 2017 2016

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results)

  • [Journal Article] 中性子反射率法によるソフト界面・薄膜のその場ナノ構造解析2016

    • Author(s)
      藤井義久、鳥飼直也
    • Journal Title

      オレオサイエンス

      Volume: 16 Pages: 535-540

    • NAID

      130007599735

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ポリスルホン相分離膜の形態観察と無機物添加の効果2018

    • Author(s)
      板倉圭吾,藤井義久,鳥飼直也
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] ポリスチレン薄膜の表面構造に及ぼす溶媒の揮発性と水の溶解度の効果2018

    • Author(s)
      宮田淳史,山田優太,藤井義久,鳥飼直也
    • Organizer
      第67回高分子学会年次大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Relationship Between Solvent Properties and Pore Size in Nonsolvent Induced Phase Separation Method2018

    • Author(s)
      Keigo Itakura・Yoshihisa Fujii・Naoya Torikai
    • Organizer
      The 8th International Symposium for Sustainability
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Pore Size Controlling of Polystyrene Thin Films by Good Solvents2018

    • Author(s)
      Atsushi Miyata, Yoshihisa Fujii, Naoya Torikai
    • Organizer
      The 8th International Symposium for Sustainability
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キャスト溶媒の揮発性と吸湿性を利用したポリスチレン薄膜の表面形態制御2018

    • Author(s)
      宮田淳史,藤井義久,鳥飼直也
    • Organizer
      第49回 中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 界面構造解析に基づく分離材料開発2018

    • Author(s)
      藤井義久
    • Organizer
      先導物質化学研究所 特別講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ポリスチレン薄膜の脱濡れ形態に及ぼす溶媒の吸湿効果2017

    • Author(s)
      山田優太、藤井義久、鳥飼直也
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Research-status Report
  • [Presentation] キャスト溶媒の吸湿性とポリスチレン薄膜の表面構造の関係2017

    • Author(s)
      宮田淳史、山田優太、藤井義久、鳥飼直也
    • Organizer
      第16回 産官学接着若手フォーラム
    • Related Report
      2017 Research-status Report
  • [Presentation] 多孔性架橋高分子膜の分離特性2017

    • Author(s)
      藤井義久
    • Organizer
      第161回東海高分子研究会講演会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] 塗膜および接着剤の界面構造解析と機能性制御2017

    • Author(s)
      藤井義久
    • Organizer
      第5回関西支部 福岡講演会
    • Related Report
      2017 Research-status Report
    • Invited

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Published: 2016-04-21   Modified: 2020-03-30  

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