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Experimental investigation and modeling of adsorption of surfactants on a moving interface

Research Project

Project/Area Number 16K06083
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Fluid engineering
Research InstitutionKobe University

Principal Investigator

Hosokawa Shigeo  神戸大学, 工学研究科, 准教授 (10252793)

Co-Investigator(Kenkyū-buntansha) 冨山 明男  神戸大学, 工学研究科, 教授 (30211402)
Research Collaborator HAYASHI Kosuke  
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords流体工学 / 混相流 / 界面 / 界面活性剤 / 吸着・脱離 / 流体計測
Outline of Final Research Achievements

Numerical simulations of contaminated bubbles or drops adopt a model of adsorption-desorption kinetics developed for quiescent systems. However, the model has rarely been validated due to the lack of experimental data of surfactant concentration at a moving interface. Hence, we experimentally investigated surfactant concentration at the moving interface of a spherical drop falling in a stagnant liquid containing surfactant based on the velocity distribution measured by spatiotemporal filter velocimetry (SFV). The applicability of the Frumkin-Levich model to a drop falling in a contaminated system was examined based on the measured data. The result showed that the evaluation of surfactant concentration using SFV is of great use in understanding adsorption-desorption kinetics at an interface in a contaminated system and in validation of adsorption and desorption models. The Frumkin-Levich model is not applicable to a moving interface, whereas it is applicable to an immobile interface.

Academic Significance and Societal Importance of the Research Achievements

本研究の成果は、流動を伴う界面における界面活性剤濃度計測を可能とする新しい手法を提供するとともに、実験データがほとんどなかった流動界面への界面活性剤の吸着・脱着特性に関する定量的データを提供するものであり、汚染系気泡・液滴の数値計算・モデルの検証および流動界面への吸着・脱離現象の解明に有益である。また、従来多用されてきた静的な吸着・脱離モデルが流動界面に利用できない場合があるとの結論は、汚染系気泡・液滴の数値予測において重要な知見である。さらに、本研究で開発した界面/境界近傍速度分布の精密測定法は、物体周囲流動の分析にも適用可能であり、流体関連分野の計測手法高度化にも貢献するものである。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (4 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results) Presentation (16 results) (of which Int'l Joint Research: 11 results,  Invited: 4 results)

  • [Int'l Joint Research] Hamburg University of Technology(Germany)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Evaluation of Adsorption of Surfactant at a Moving Interface of a Single Spherical Drop2018

    • Author(s)
      Shigeo Hosokawa, Kosuke Hayashi, Akio Tomiyama
    • Journal Title

      Experimental Thermal and Fluid Science

      Volume: 96 Pages: 397-405

    • DOI

      10.1016/j.expthermflusci.2018.03.026

    • NAID

      120006484298

    • Related Report
      2018 Annual Research Report 2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Experimental Evaluation of Marangoni stress and surfactant concentration at interface of contaminated single drops using spatiotemporal filter velocimetry2017

    • Author(s)
      Shigeo Hosokawa, Yuya Masukura, Kosuke Hayashi, Akio Tomiyama
    • Journal Title

      International Journal of Multiphase Flow

      Volume: 97 Pages: 157-167

    • DOI

      10.1016/j.ijmultiphaseflow.2017.08.007

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] 時空間フィルタ流速計による界面近傍の流れの計測2017

    • Author(s)
      細川茂雄, 冨山明男
    • Journal Title

      ながれ

      Volume: 36 Pages: 303-308

    • Related Report
      2017 Research-status Report
    • Open Access
  • [Journal Article] Gaslift Pump making use of Phase Change of Working Fluid2016

    • Author(s)
      Shigeo Hosokawa, Shudai Fujimoto, Akio Tomiyama
    • Journal Title

      Applied Thermal Engineering,

      Volume: 103 Pages: 1119-1125

    • DOI

      10.1016/j.applthermaleng.2016.05.010

    • NAID

      120005842588

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Diagnostics of flow about a contaminated single drop using spatiotemporal filter velocimetry2018

    • Author(s)
      Shigeo Hosokawa, Gaku Shigekane, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      19th Symposium on Applications of Laser and Imaging Techniques to Fluid Mechanics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optical Measurements for Validation of Numerical Simulation of Two-Phase Flow2018

    • Author(s)
      Shigeo Hosokawa
    • Organizer
      3rd Workshop on Advances in CFD and LB Modeling of Interface Dynamics in Capillary Two-Phase Flows
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Experimental Evaluation of Adsorption of Surfactant at Moving Interface2018

    • Author(s)
      Shigeo Hosokawa
    • Organizer
      2nd International COFTEC Symposia
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単一液滴に作用する力の実験的分析2018

    • Author(s)
      重兼楽,細川茂雄, 林公祐,冨山明男
    • Organizer
      第95期日本機械学会流体工学部門講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 界面含む流れの計測2018

    • Author(s)
      細川茂雄
    • Organizer
      化学工学会第83年会 粒子流体プロセス部会セミナー
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] Liquid Velocity Distribution of Turbulent Bubbly Flow in a 2X2 Rod Bundle2017

    • Author(s)
      Shigeo Hosokawa, Akio Tomiyama
    • Organizer
      J-US Seminar on Two-Phase Flow Dynamics
    • Place of Presentation
      札幌
    • Year and Date
      2017-06-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Adsorption of Surfactant at a Moving Interface of a Single Spherical Drop2017

    • Author(s)
      Shigeo Hosokawa, Ryota Okamoto, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      9th World Conference on Experimental Heat Transfer, Fluid Mechanics and Thermodynamics
    • Place of Presentation
      イグアス(ブラジル)
    • Year and Date
      2017-06-11
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Adsorption of Surfactant at a Moving Interface of a Single Spherical Drop2017

    • Author(s)
      Shigeo Hosokawa, Ryota Okamoto, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      9th World Conference on Experimental Heat Transfer, Fluid Mechanics and Thermodynamics (ExHFT-9)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Evaluation of Adsorption of Surfactant at a Drop Interface using Spatiotemporal Filter Velocimetry2017

    • Author(s)
      Shigeo Hosokawa, Ryota Okamoto, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      10th International Symposium on Measurement Techniques for Multiphase Flow (ISMTMF2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Turbulent property of air-water bubbly flow in a 2X2 rod bundle2017

    • Author(s)
      Shigeo Hosokawa, Akio Tomiyama
    • Organizer
      10th International Symposium on Measurement Techniques for Multiphase Flow (ISMTMF2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 流れの光学計測よもやま話2016

    • Author(s)
      細川茂雄
    • Organizer
      日本混相流学会若手研究者夏季セミナー
    • Place of Presentation
      高槻
    • Year and Date
      2016-08-10
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Effect of Bubbles on Turblence Kinetic Energy Budget in Vertical Duct flow2016

    • Author(s)
      Shigeo Hosokawa, Hiroki Karasawa, Ryosuke Iwai, Akio Tomiyama
    • Organizer
      18th Symposium on Applications of Laser Techniques to Fluid Mechanics, Lisbon 2016
    • Place of Presentation
      リスボン(ポルトガル)
    • Year and Date
      2016-07-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Experimental Evaluation of Surfactant Concentration at an Interface of Single Spherical Drop2016

    • Author(s)
      Shigeo Hosokawa, Yuya Masukura, Kosuke Hayashi, Akio Tomiyama
    • Organizer
      The 9th International Conference on Multiphase Flow, ICMF2016
    • Place of Presentation
      フィレンテェ(イタリア)
    • Year and Date
      2016-05-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Numerical Simulation of Surfactant Concentration at an Interface of Single Spherical Drop2016

    • Author(s)
      Kosuke Hayashi, Yuya Masukura, Shigeo Hosokawa, Akio Tomiyama
    • Organizer
      The 9th International Conference on Multiphase Flow, ICMF2016
    • Place of Presentation
      フィレンテェ(イタリア)
    • Year and Date
      2016-05-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 時空間フィルタ流速計による界面活性剤の吸着を伴う液滴の測定2016

    • Author(s)
      細川茂雄,益倉侑冶,林公祐, 冨山明男
    • Organizer
      第94期日本機械学会流体工学部門講演会
    • Place of Presentation
      宇部
    • Related Report
      2016 Research-status Report
  • [Presentation] 二相流数値計算検証のための実験計測2016

    • Author(s)
      細川茂雄,林公祐,冨山明男
    • Organizer
      日本機械学会RC270第3回分科会
    • Place of Presentation
      東京
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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