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Wet Process Fabrication of Metal-Oxide Granular Films with Magnetic Anisotropy Direction Change with Thickness

Research Project

Project/Area Number 16K06282
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionNara National College of Technology

Principal Investigator

Fujita Naoyuki  奈良工業高等専門学校, 電気工学科, 教授 (90249813)

Co-Investigator(Kenkyū-buntansha) 平井 誠  長岡工業高等専門学校, 電気電子システム工学科, 准教授 (00534455)
Project Period (FY) 2016-04-01 – 2021-03-31
Project Status Completed (Fiscal Year 2020)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2019: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords磁場中電析 / 異方性方向制御 / 電磁波吸収材料 / ウェットプロセス形成 / グラニュラ薄膜 / Fe-B合金 / 磁気異方性 / 金属―絶縁物同時電析法 / 金属-絶縁物同時電析 / 磁場中成膜 / グラニュラ膜 / 金属-絶縁物グラニュラ膜 / 金属-絶縁物同時無電解析出 / 電気化学成膜 / 磁気特性
Outline of Final Research Achievements

Amorphous Fe-B bilayers with orthogonal easy axes of magnetization were prepared by electrodeposition by changing the direction of the externally applied magnetic field during the process. In order to suppressed the dispersion in the magnetic properties of the first and second layers of film, the temperature of the reaction solution was kept constant by using a pump to supply the solution. As a result, it was found that two-layer thin films with orthogonal easy magnetization axes can be easily prepared by electrodeposition.
In addition, a new method of fabricating insulating films containing metal ultrafine particles was investigated. Fe-Ni particles with polyelectrolyte adsorbed on the surface were immersed in water-soluble epoxy solution. By electrodeposition using this solution for 5 minutes, a thin film with a thickness of 80 μm and a magnetic particle content of 22% was obtained.

Academic Significance and Societal Importance of the Research Achievements

通信が高速になるに伴って,高い周波数で動作する電磁波吸収材料が必要となっている.本研究は,めっき法という安価な方法で,優れた電磁波吸収材料を作ることを目指している.外部から電磁石で磁界を加えながら,めっきすると,磁界を加えた方向が磁石になりやすい膜(磁化容易軸という)ができる.磁界を加える方向をめっきの途中で90°ずらすことで,膜の厚さ方向で,磁化容易軸が90°ずれた膜が作製できた.こうすることで,あらゆる方向からくる電磁波が吸収できるようになる.

Report

(6 results)
  • 2020 Annual Research Report   Final Research Report ( PDF )
  • 2019 Research-status Report
  • 2018 Research-status Report
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (14 results)

All 2020 2019 2018 2017

All Presentation (14 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Presentation] Fabrication of Fe-Ni Ultrafine Particles Epoxy Composite Film Using the LbL Assisted Composite Plating Method2020

    • Author(s)
      Naoyuki Fujita, Makoto Takeuchi, Kouta Fujiwara, Hiroyuki Muto
    • Organizer
      ECS Meeting Abstracts 237th ECS Meeting with the 18th International Meeting on Chemical Sensors MA2020-01
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ウェットプロセスによる機能性磁性薄膜の作製2019

    • Author(s)
      藤田直幸
    • Organizer
      2019年度 関西表面技術シンポジウム
    • Related Report
      2019 Research-status Report
    • Invited
  • [Presentation] Fabrication of Magnetic Ultrafine Particles-Insulator Composite Film Using the LbL Assisted Composite Plating Method2018

    • Author(s)
      N. Fujita,M. Takeuchi,Y. Watanabe,N. Matsumoto,H. Muto
    • Organizer
      IEEE International Magnetics Conference
    • Related Report
      2018 Research-status Report
    • Int'l Joint Research
  • [Presentation] LbL法アシスト複合めっきによる金属-絶縁物複合膜の作製2018

    • Author(s)
      竹内誠,武藤浩行,藤田直幸
    • Organizer
      平成30年度第315回電気材料技術懇談会
    • Related Report
      2018 Research-status Report
  • [Presentation] 金属絶縁物コンポジット薄膜のLbL法アシスト複合めっきによる作製2018

    • Author(s)
      竹内誠,武藤浩行,藤田直幸
    • Organizer
      電気学会マグネティックス研究会
    • Related Report
      2018 Research-status Report
  • [Presentation] 電磁波吸収用金属-絶縁物複合膜のウェットプロセス形成2018

    • Author(s)
      竹内誠,武藤浩行,藤田直幸
    • Organizer
      エレクトロニクス実装学会 第28回マイクロエレクトロニクスシンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] Fe-Ni-epoxy 複合膜のLbL法アシスト複合めっきによる作製2018

    • Author(s)
      竹内誠,武藤浩行,渡邉佳孝,藤田直幸
    • Organizer
      日本磁気学会 第42回学術講演会
    • Related Report
      2018 Research-status Report
  • [Presentation] ウェットプロセスによる機能性磁性薄膜の作製2018

    • Author(s)
      藤田直幸
    • Organizer
      表面技術シンポジウム
    • Related Report
      2018 Research-status Report
  • [Presentation] LbL 法アシスト複合めっきによるFe-Ni/ Epoxy 複合膜の作製2018

    • Author(s)
      竹内誠, 武藤浩行, 横井敦史, 松本直也, 藤田直幸
    • Organizer
      国立高等専門学校機構 第3ブロック 専攻科研究発表会
    • Related Report
      2017 Research-status Report
  • [Presentation] LbL法アシスト複合めっきによる金属-絶縁物コンポジット薄膜の作製2017

    • Author(s)
      渡邉 佳孝,武藤浩行,松本直也,藤田直幸
    • Organizer
      表面技術協会
    • Place of Presentation
      東洋大学
    • Year and Date
      2017-03-09
    • Related Report
      2016 Research-status Report
  • [Presentation] LbL法アシスト複合めっきによる金属―絶縁物複合膜の作製とその磁気特性2017

    • Author(s)
      竹内誠, 芦原佑樹, 武藤浩行, 横井敦史, 松本直也, 藤田直幸
    • Organizer
      表面技術協会 学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] 金属―絶縁物同時無電解析出法による金属―絶縁物コンポジット膜の作製22017

    • Author(s)
      藤田直幸
    • Organizer
      電気鍍金研究会 関西表面技術シンポジウム
    • Related Report
      2017 Research-status Report
  • [Presentation] LbL 法アシスト複合めっきによるFe-Ni/ Epoxy 複合膜の作製2017

    • Author(s)
      竹内誠, 武藤浩行, 横井敦史, 松本直也, 藤田直幸
    • Organizer
      表面技術協会 関西支部 関西表面技術フォーラム
    • Related Report
      2017 Research-status Report
  • [Presentation] Fabrication of Magnetic Metal-Insulator Composite Film by Using The LbL Assisted Composite Plating Method2017

    • Author(s)
      Naoyuki Fujita, Yoshitaka Watanabe, Makoto Takeuchi, Naoya Matsumoto, Atsushi Yokoi, Hiroyuki Muto
    • Organizer
      The International Symposium on Advanced Magnetic Materials and Applications
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research

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Published: 2016-04-21   Modified: 2022-01-27  

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