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Improvement of organic light-emitting diodes using natural carotenoids extracted from plants

Research Project

Project/Area Number 16K06322
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Electron device/Electronic equipment
Research InstitutionDoshisha University

Principal Investigator

Ohtani Naoki  同志社大学, 理工学部, 教授 (80359067)

Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2018: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords植物色素 / 発光ダイオード / 色素増感太陽電池 / 抗酸化作用 / カロテノイド / アントシアニン / クロマトグラフィー / カラムクロマトグラフィ / ほうれん草 / アオダモ / 蛍光寿命 / 天然色素 / 電子デバイス・機器 / 電子・電気材料 / 光物性
Outline of Final Research Achievements

We made red LED using chlorophyll isolated and purified from spinach, and realized improvement of device operation lifetime by antioxidant effect of isolated and purified β-carotene, and clarified its mechanism. We also examined the blue shift of the emission wavelength and the increase in emission intensity due to the β-carotene doping. In addition, we found that the blue fluorescent dye can be extracted from the branches of Audamo. Moreover, the green fluorescent dye has been successfully extracted from mini tomatoes by column chromatography method. These results show that luminescence of the three primary colors of light can be realized with plant pigments.
Dye-sensitized solar cells using plant pigments were fabricated, and it was found that good photoelectric conversion efficiency can be realized when using anthocyanins contained in berry fruits.

Academic Significance and Societal Importance of the Research Achievements

植物から抽出した天然βカロテンおよびアントシアニン系色素などの抗酸化作用による蛍光高分子の発光特性の変調については他の研究機関ではまったく行われておらず、その学術的独自性と創造性は極めて高い。また本研究は、天然色素の抗酸化作用のメカニズムと工業製品の効率化を結びつける学際的な位置付けにあり、新たな学問分野を喚起する可能性あがる。さらに、産業応用への波及効果も大きく、豊富な天然資源を利用できれば安価で低環境負荷の工業製品を量産できるので、資源に乏しい我が国にとってそのメリットはとても大きい。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (14 results)

All 2019 2018 2017 2016

All Presentation (14 results) (of which Int'l Joint Research: 10 results)

  • [Presentation] Separation of blue fluorescent pigments contained in Fraxinus lanuginosa f. serrata using reverse-phase column chromatography and investigation of luminescent properties2019

    • Author(s)
      T. Ohtsu, Y. Kinou, and N. Ohtani
    • Organizer
      The 7th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study of isolation method of green fluorescent pigments contained in cherry tomatoes using column chromatography2019

    • Author(s)
      A. Noma and N. Ohtani
    • Organizer
      The 7th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photoluminescence properties of emissive polymer MEH-PPV affected by antioxidant effect of natural beta-carotene extracted from spinach2019

    • Author(s)
      Y. Magata, S. Imada, and N. Ohtani
    • Organizer
      The 7th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子蛍光材料の発光特性におけるβカロテン混合の影響2018

    • Author(s)
      今田 駿,大谷直毅
    • Organizer
      2018年秋季第79回応用物理学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] アオダモに含まれる青色蛍光色素の抽出方法と発光特性の検討2018

    • Author(s)
      貴納悠介,大谷直毅
    • Organizer
      2018年秋季第79回応用物理学会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] Natural dye-sensitized solar cells containing anthocyanin dyes extracted from frozen blueberry using column chromatography method2018

    • Author(s)
      A. Mizuno, G. Yamada, and N. Ohtani
    • Organizer
      the 7th World Conference on Photovoltaic Energy Conversion
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Modulation of photoluminescence properties of emissive polymers induced by mixing of β-carotene2018

    • Author(s)
      S. Imada, B. Diodoro, and N. Ohtani
    • Organizer
      International Conference on Organic Materials for Electronics and Photonics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on extraction method of blue emissive pigments contained in fraxinus lanuginose2018

    • Author(s)
      Y. Kinou and N. Ohtani
    • Organizer
      International Conference on Organic Materials for Electronics and Photonics
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Blue-color photoluminescence from natural pigments extracted from fraxinus lanuginosa2017

    • Author(s)
      Yusuke Kinou and Naoki Ohtani
    • Organizer
      6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Place of Presentation
      AOSSA、福井県、福井市
    • Year and Date
      2017-06-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Antioxidant effect of β-carotene and lutein isolated and purified from spinach on photoluminescence lifetime of organic emissive materials2017

    • Author(s)
      Shun Imada, Takato Ito, and Naoki Ohtani
    • Organizer
      6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Place of Presentation
      AOSSA、福井県、福井市
    • Year and Date
      2017-06-18
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Antioxidant effect of β-carotene and lutein isolated and purified from spinach on photoluminescence lifetime of organic emissive materials2017

    • Author(s)
      S. Imada, T. Ito, and N. Ohtani
    • Organizer
      The 6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Blue-color photoluminescence from natural pigments extracted from Fraxinus lanuginosa2017

    • Author(s)
      Y. Kinou and N. Ohtani
    • Organizer
      The 6th International Symposium on Organic and Inorganic Electronic Materials and Related Nanotechnologies (EM-NANO 2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] アオダモに含まれる青色蛍光色素の抽出方法と発光特性の検討2017

    • Author(s)
      貴納悠介,大谷直毅
    • Organizer
      2017年秋季第78回応用物理学会学術講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] MDMO-PPV の発光スペクトルに対するβカロテン混合の影響2016

    • Author(s)
      伊藤嵩人, 大谷直毅
    • Organizer
      2016年秋季第77回応用物理学会学術講演会
    • Place of Presentation
      朱鷺メッセ、新潟県、新潟市
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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