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Structure of ion tracks and microstructure development in fluorite-type ceramics

Research Project

Project/Area Number 16K06961
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Nuclear engineering
Research InstitutionKyushu University

Principal Investigator

Kazuhiro Yasuda  九州大学, 工学研究院, 准教授 (80253491)

Research Collaborator MATSUMURA SYO  九州大学, 工学研究院, 教授 (60150520)
YOSHIOKA SATORU  九州大学, 工学研究院, 助教 (50452818)
ISHIKAWA NORITO  日本原子力見空開発機構, 原子力科学研究部門原子力基礎工学研究センター, 研究主幹 (90354828)
COSTANTINI JEAN-MARC  フランス原子力庁, サクレー研究所原子力エネルギー部門, 研究部門長
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords照射損傷 / 核燃料・核変換処理材料 / 蛍石構造酸化物 / 走査透過電子顕微鏡法 / 動的観察・計測 / カソードルミネッセンス / 電子励起損傷 / イオントラック / セリア / 安定化ジルコニア / 酸化物セラミックス / 核燃料 / 核変換処理材料 / 電子顕微鏡法 / 電子励起 / X線散乱・分光法 / 電子顕微鏡 / 小角X線散乱法 / 格子欠陥
Outline of Final Research Achievements

We have investigated the structure and accumulation of ion tracks in ceramic compounds, which is induced by high density electronic excitation. A variety of techniques, such as transmission and transmission scanning electron microscopy, X-ray scattering/spectroscopy and Raman spectroscopy. It was found that the structure as well as the accumulation process of ion track depend on the electronic stopping power. The accumulation process of ion tracks were successfully modeled to reveal that the size, formation efficiency and recovery region of ion tracks are significantly different between ceria and stabilized zirconia. Furthermore, we tried to develop experimental techniques to understand fundamental behavior of point defects in ceramics, including analytical method of cation disordering in oxides by XAFS and “in-situ” cathodeluminescence technique under high energy electron irradiation.

Academic Significance and Societal Importance of the Research Achievements

本研究は電子励起損傷に対して優れた耐性を持つとされる蛍石型酸化物中のイオントラックの構造とその蓄積過程を種々の実験方法によりに詳細に調べ,微細組織発達過程に関する基礎的知見を与えた研究である.電子顕微鏡法では直接観察されない回復領域のサイズが電子的阻止能値や材料に依存することなどを定量的に示すと共に,セラミックス中の点欠陥挙動に関する新たな実験手法を提案した.本研究により得られた成果は,原子力材料の微細組織安定性や格子欠陥による新奇材料開発など資する基礎的知見を与える意義ある研究である.

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (48 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (4 results) Journal Article (10 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 8 results,  Open Access: 2 results) Presentation (30 results) (of which Int'l Joint Research: 13 results,  Invited: 7 results) Remarks (4 results)

  • [Int'l Joint Research] CEA-Saclay/Solbonne Universite(フランス)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] Atomic Energy Center Chittagong(バングラデシュ)

    • Related Report
      2018 Annual Research Report
  • [Int'l Joint Research] CEA-Salay/UPMC Univ Paris 06(France)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Universita degli Studi Milano-Bicocca(Italy)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Cathodoluminescence induced in oxides by high-energy electrons: Effects of beam flux, electron energy, and temperature2019

    • Author(s)
      J-M. Costantini, T. Ogawa, AKM S. I. Bhuian, K.Yasuda
    • Journal Title

      Journal of Luminescence

      Volume: 208 Pages: 108-118

    • DOI

      10.1016/j.jlumin.2018.12.045

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 酸化物中のイオントラック構造と微細組織発達2018

    • Author(s)
      安田和弘
    • Journal Title

      京都大学工学研究科附属量子理工学教育研究センター(QSEC)第19回公開シンポジウムプロシーディングス

      Volume: なし Pages: 15-21

    • Related Report
      2018 Annual Research Report
  • [Journal Article] Color-center formation and thermal recovery in X-ray and electron-irradiated magnesium aluminate spinel2018

    • Author(s)
      Jean-Marc Costantini, Gerald Lelong, Maxime Guillaumet, Seiya Takaki, Kazuhiro Yasuda
    • Journal Title

      Journal of Applied Physics

      Volume: 124 Issue: 24

    • DOI

      10.1063/1.5055230

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] X-ray absorption near edge structure and first-principles spectral investigations of cationic disorder in MgAl2O4 induced by swift heavy ions2018

    • Author(s)
      S. Yoshioka, K. Tsuruta, T. Yamamoto, K. Yasuda, S. Matsumura, N. Ishikawa, and E. Kobayashi
    • Journal Title

      Physical Chemistry and Chemical Physics

      Volume: 20 Issue: 7 Pages: 4962-4969

    • DOI

      10.1039/c7cp07591j

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Raman spectroscopy study of damage induced in cerium dioxide by swift heavy ion irradiations2018

    • Author(s)
      J.M. Costantini, S. Miro, G. Gutierrez, K. Yasuda, S. Takaki, N. Ishikawa, M. Toulemonde
    • Journal Title

      Journao of Applied Physics

      Volume: 122 Issue: 20 Pages: 205901-205901

    • DOI

      10.1063/1.5011165

    • Related Report
      2017 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure of Ion Tracks in Yttria Stabilized Cubic Zirconia2017

    • Author(s)
      S. Takaki, K. Yasuda, S.Yoshioka, S. Matsumura, N. Ishikawa
    • Journal Title

      JAEA-Review

      Volume: 印刷中

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Temperature dependent evolution of dislocation loops in YSZ under high energy electron irradiation2016

    • Author(s)
      AKM S.I. Bhuian, K. Kuwahara, T. Yamamoto, K. Yasuda, S. Matsumura, H. Yasuda
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 41 Issue: 3 Pages: 319-323

    • DOI

      10.14723/tmrsj.41.319

    • NAID

      130005263686

    • ISSN
      1382-3469, 2188-1650
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Color-center production and recovery in electron-irradiated magnesium aluminate spinel and ceria2016

    • Author(s)
      J.M. Costantini, G. Lelong, M. Guillaumet, W.J. Weber, S. Takaki, K.Yasuda
    • Journal Title

      J. Phys. Condensed Matter

      Volume: 28 Issue: 32 Pages: 325901-325901

    • DOI

      10.1088/0953-8984/28/32/325901

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structure of Ion Tracks in Ceria Irradiated with High Energy Xenon Ions2016

    • Author(s)
      S. Takaki, K. Yasuda, T. Yamamoto, S. Matsumura, N. Ishikawa
    • Journal Title

      Progress in Nuclear Energy

      Volume: 92 Pages: 306-312

    • DOI

      10.1016/j.pnucene.2016.07.013

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structure of defects and microstructure evolution in oxide ceramics -role of electronic excitation and selective displacement damage-2016

    • Author(s)
      K. Yasuda
    • Journal Title

      MINOS 2nd Int. Workshop, Irradiation of Nuclear Materials: Flux and Dose Effects, EPJ Web of Conferences

      Volume: 115 Pages: 29-30

    • Related Report
      2016 Research-status Report
    • Open Access
  • [Presentation] セリアおよび安定化ジルコニア中のイオントラックの構造と蓄積過程の比較2019

    • Author(s)
      山口芳明 、安田和弘、吉岡聰、松村晶、高木聖也、石川法人
    • Organizer
      2019年日本金属学会春季講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高速重イオン照射によるMgAl2O4の欠陥構造と不規則化過程2019

    • Author(s)
      吉岡聰、山本知一、安田和弘、松村晶、大場洋次郎、石川法人、小林英一、奥平幸司
    • Organizer
      2019年日本金属学会春季講演大会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 酸化物中のイオントラック構造と微細組織発達2019

    • Author(s)
      安田和弘
    • Organizer
      京都大学工学研究科附属量子理工学教育研究センター(QSEC)第19回公開シンポジウム
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Atomistic Structure Investigation on Ion Beam Induced Defects by X-ray Absorption Spectroscopy / First-principles Spectrum Calculation2018

    • Author(s)
      Satoru Yoshioka
    • Organizer
      Materials Research Society Japan Sympojium: “Innovative Material Technologies Utilizing Ion Beams”
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Structure and Accumulation of Ion Tracks in YSZ Induced by High Density Electronic Excitation2018

    • Author(s)
      Y. Yamaguchi, T. Yamamot, S. Yoshioka, K. Yasuda, S. Matsumura , S. Takaki, N. Ishikawa
    • Organizer
      Materials Research Society Japan Sympojium: “Innovative Material Technologies Utilizing Ion Beams”
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-situ Cathodoluminescence in Cerium Dioxide Induced by High-Energy Electron Irradiation2018

    • Author(s)
      Pooreun SEO, AKM Saiful I. BHUIAN, Syo MATSUMURA, Kazuhiro YASUDA, Jean-Marc COSTANTINI
    • Organizer
      Materials Research Society Japan Sympojium: “Innovative Material Technologies Utilizing Ion Beams”
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] In-situ Observation of Radiation-Induced Defects in ZrN under Electron Irradiation in HVEM2018

    • Author(s)
      M. M. Rahman, T. Yamamoto, Y. Yamaguchi, K. Yasuda, S. Matsumura, S. Takaki, and M. Takano
    • Organizer
      Materials Research Society Japan Sympojium: “Innovative Material Technologies Utilizing Ion Beams”
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of cation disordering in magnesium aluminate spinel induced by SHI usig X-ray absorption near edge structure and first principles calculations2018

    • Author(s)
      S. Yoshioka, K. Tsuruta, T. Yamamoto, K. Yasuda, S. Matsumura, N. Ishikawa, E. Kobayashi
    • Organizer
      The 28th International Conference on Atomic Collisions in Solids &10th International symposium on Swift Heavy Ions in Matter (ICACS-SHIM 2019)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高速重イオン照射に誘起された複酸化物中の不規則配列のXAFS解析2018

    • Author(s)
      吉岡聰、山口芳明,山本知一、安田和弘、松村晶、石川法人、小林英一
    • Organizer
      材料照射研究会・ゼロエミッションエネルギー拠点研究会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 高速重イオン照射した安定化ジルコニアのイオントラック構造2018

    • Author(s)
      山口芳明 、安田和弘、吉岡聰、松村晶、高木聖也、石川法人
    • Organizer
      第13回 先進原子力科学技術に関する連携重点研究討論会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 電子励起損傷に伴う安定化ジルコニアの微細構造発達2018

    • Author(s)
      山口芳明,山本知一,吉岡聰,安田和弘,松村晶,髙木聖也,石川法人,薮内聖皓、 木村晃彦
    • Organizer
      材料照射研究会・ゼロエミッションエネルギー拠点研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] 高速重イオン照射に誘起されたMgAl2O4中不規則配列のX線構造解析 ~X線吸収分光法およびX線小角散乱法~2018

    • Author(s)
      吉岡聰、鶴田幸之介、山本知一、安田和弘、松村晶、石川法人、小林英一、薮内聖皓、 木村晃彦
    • Organizer
      材料照射研究会・ゼロエミッションエネルギー拠点研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] 蛍石構造酸化物の電子照射効果 ~選択的はじき出し損傷効果と照射欠陥形成過程~2018

    • Author(s)
      安田和弘,AKM S.I. Bhuian,山本知一,松村晶,保田 英洋
    • Organizer
      材料照射研究会・ゼロエミッションエネルギー拠点研究会
    • Related Report
      2017 Research-status Report
  • [Presentation] 電子励起損傷に伴う安定化ジルコニアの微細構造発達2018

    • Author(s)
      山口 芳明、山本 知一、吉岡 聰、安田 和弘、松村 晶、髙木 聖也、石川 法人
    • Organizer
      日本原子力学会2018春の年会
    • Related Report
      2017 Research-status Report
  • [Presentation] Structure and Accumulation of Ion Tracks in Ceria2017

    • Author(s)
      永石 大誠、高木 聖也、安田 和弘、吉岡 聰、松村 晶、石 川法人
    • Organizer
      東海・重イオン科学シンポジウム ―タンデム加速器成果報告会―
    • Place of Presentation
      東海村、日本原子力研究開発機構
    • Year and Date
      2017-01-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Structure Investigations for Ion Tracks in MgAl2O4 by SAXS2017

    • Author(s)
      鶴田 幸之助、高木 聖也、吉岡 聰、安田 和弘、松村 晶、石 川法人子力機構)
    • Organizer
      東海・重イオン科学シンポジウム ―タンデム加速器成果報告会―
    • Place of Presentation
      東海村、日本原子力研究開発機構
    • Year and Date
      2017-01-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Dislocation Loops in Yttria Satabilized Zirconia: Role of e- and/or Ion Energy and Irradiation Temperatures2017

    • Author(s)
      AKM S.I. Bhuian, K. Kuwahara , T. Yamamoto , K.Yasuda, S. Matsumura, H. Yasuda
    • Organizer
      東海・重イオン科学シンポジウム ―タンデム加速器成果報告会―
    • Place of Presentation
      東海村、日本原子力研究開発機構
    • Year and Date
      2017-01-05
    • Related Report
      2016 Research-status Report
  • [Presentation] Small Angle X-ray Scattering and X-ray Absorption Spectroscopy Investigations of Ion Tracks in MgAl2O42017

    • Author(s)
      S. Yoshioka, K. Tsuruta, T. Yamamoto, S. Matsumura, K. Yasuda, N. Ishikawa, and E. Kobayashi
    • Organizer
      International Conference on Radiation Effect in Insulators (REI 2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Atomic Structure of Ion Tracks in Non-Amorphizable Oxides2017

    • Author(s)
      Kazuhiro Yasuda
    • Organizer
      2017 EMRS Fall Meeting, Symposium E “Basic research on ionic-covalent materials for nuclear applications“
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Dislocation loops in yttria stabilized zirconia induced by electron irradiataion : role of electron energy and irradiation temperature2017

    • Author(s)
      AKM Saiful Islam Bhuian, K. Kuwahara, T. Yamamoto, K. Yasuda, S. Matsumura, H. Yasuda and N. Ishikawa
    • Organizer
      Joint ICTP‐IAEA Workshop on Fundamentals of Vitrification and Vitreous Materials for Nuclear Waste and Immobilization
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] 蛍石型酸化物中のイオントラック原子構造と微細構造発達過程2017

    • Author(s)
      安田 和弘,永石 大誠,松村 晶,高木 聖也,石川 法人
    • Organizer
      第63回放射線科学研究会
    • Related Report
      2017 Research-status Report
    • Invited
  • [Presentation] High Voltage Electron Microscope Study of Lattice Defect Formation in Fluorite-type Oxide Crystals2017

    • Author(s)
      S. Matsumura, K. Yasuda, AKM S. I. Bhuian, S. Takaki,
    • Organizer
      International Conference on Materials and Systems for Sustainability (ICMaSS 2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高速重イオン照射に誘起されたMgAl2O4中不規則配列のXAFS構造解析c2017

    • Author(s)
      吉岡聰、鶴田幸之介、山本知一、安田和弘、松村晶、石川法人、小林英一
    • Organizer
      日本金属学会2017秋期講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] Defects in yttria stabilized zirconia under electron and/or ion irradiation2017

    • Author(s)
      AKM S. I. Bhuian 、山本知一、安田和弘、松村晶 保田英 洋、 石川法人
    • Organizer
      日本原子力学会九州支部第 36 回研究発表講演会
    • Related Report
      2017 Research-status Report
  • [Presentation] セラミックスにおける粒子線照射効果2016

    • Author(s)
      安田和弘
    • Organizer
      大阪大学ナノテクノロジープラットフォーム  平成28年度第2回地域セミナー“超高圧電子顕微鏡による微細構造解析と材料科学研究”
    • Place of Presentation
      大阪
    • Year and Date
      2016-12-23
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 二酸化セリウム中のイオントラック構造と蓄積過程の電子的阻止能依存性2016

    • Author(s)
      永石大誠、安田 和弘、吉岡聰、松村晶、高木聖也、石川法人
    • Organizer
      日本原子力学会九州支部第35回研究発表講演会
    • Place of Presentation
      春日、九州大学
    • Year and Date
      2016-12-03
    • Related Report
      2016 Research-status Report
  • [Presentation] 酸化物セラミックスの超高圧電子顕微鏡内カソードルミネッセンス「その場」測定2016

    • Author(s)
      渡部恭志、安田和弘、松村晶、前野宏志、J.M. Costantini
    • Organizer
      日本原子力学会九州支部第35回研究発表講演会
    • Place of Presentation
      春日、九州大学
    • Year and Date
      2016-12-03
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Local Structure Investigations of Ceramics by Small Angle X-ray Scattering and X-ray Absorption Spectroscopy2016

    • Author(s)
      S. Yoshioka
    • Organizer
      Invited Seminer at CEA-Saclay
    • Place of Presentation
      Saclay, France
    • Year and Date
      2016-11-14
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Small Angle X-ray Scattering Investigations of Defect Structure in Ceria Irradiated with Swift Heavy Ions2016

    • Author(s)
      S. Yoshioka, K. Tsuruta , K. Yasuda, S. Matsumra, T.Horide, and N. Ishikawa
    • Organizer
      NuMat2016: The Nuclear Materials Conference
    • Place of Presentation
      Cadarache, France
    • Year and Date
      2016-11-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effects of Electronic Stopping on the Structure and Accumulation of Ion Tracks in Ceria2016

    • Author(s)
      K. Yasuda, T. Nagaishi, S. Takaki1, S. Yoshioka, S. Matsumura and N. Ishikawa
    • Organizer
      NuMat2016: The Nuclear Materials Conference
    • Place of Presentation
      Cadarache, France
    • Year and Date
      2016-11-07
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Remarks] 九州大学大学院工学研究院エネルギー量子工学部門 エネルギー物質科学講座 量子線物性工学研究室

    • URL

      http://neutrino.nucl.kyushu-u.ac.jp/lab3/

    • Related Report
      2018 Annual Research Report
  • [Remarks] 九州大学工学研究院 エネルギー量子工学部門 エネルギー物質科学講座 量子線物性工学研究室

    • URL

      http://www.qpn.kyushu-u.ac.jp/lab3/

    • Related Report
      2017 Research-status Report
  • [Remarks] 九州大学大学院工学研究院 エネルギー量子工学部門

    • URL

      http://www.qpn.kyushu-u.ac.jp/index.html

    • Related Report
      2016 Research-status Report
  • [Remarks] 九州大学大学院工学研究院 エネルギー量子工学部門 エネルギー物質科学講座

    • URL

      http://www.qpn.kyushu-u.ac.jp/lab3/

    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2020-03-30  

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