Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2018: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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Outline of Final Research Achievements |
I have developed a method for photo-induced alkyl radical generation based on triazinylammonium salt. Direct radical generation by UV irradiation to triazinylammonium salt has proved to be difficult. On the other hand, the reaction of triazinylammonium salt in the presence of a metal photoredox catalyst and a reducing agent under visible light irradiation allowed to generate the alkyl radical, which subsequently reacted with the coexisting Michael acceptor to give the desired adduct in a 73% yield
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