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Research on contribution of ANAMMOX reaction for nitrogen removal

Research Project

Project/Area Number 16K12584
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Environmental dynamic analysis
Research InstitutionShimane University

Principal Investigator

Seike Yasushi  島根大学, エスチュアリー研究センター, 特任教授 (30243421)

Co-Investigator(Kenkyū-buntansha) 管原 庄吾  島根大学, 総合理工学研究科, 講師 (30721302)
半田 真  島根大学, 総合理工学研究科, 教授 (70208700)
Co-Investigator(Renkei-kenkyūsha) SENGA Yukiko  東邦大学, 理学部, 准教授 (30434210)
Research Collaborator EGAWA Michiko  島根大学, 大学院総合理工学研究科, 助手 (20565882)
KATO Toshikuni  島根県保健環境科学研究所, 研究員 (20791734)
KAMIYA Hiroshi  島根県保健環境科学研究所, 環境部長 (50601928)
MIWA Keiya  島根大学, 大学院総合理工学研究科
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywordsアナモックス反応 / 中間体 / ヒドロキシルアミン / ヒドラジン / 窒素浄化プロセス / 汽水湖 / エスチュアリー / 定量法の開発 / 窒素浄化 / 環境分析
Outline of Final Research Achievements

We newly developed a simple in situ method for the determination of trace hydrazine and hydroxylamine, intermediate products in the ANAMMOX reaction, applicable to environmental water. The determination of the trace hydrazine is based on the concentration of aldazine compound fomed by the reaction of hydrazine with p-dimethylaminobenzaldehyde. We next developed a method for quantifying trace hydroxylamine in brackish-and sea-water samples. We used a method of ECD-GC measurement of the nitrous oxide produced by the reaction with sodium hypochlorite. Those new methods can quantify for natural water samples with a wide range of salinity, and then were applied successfully to the samples from Lake Nakaumi, a brackish lake located in the eastern part of Shimane Prefecture, Japan. The lower limit of detection for those new methods were 0.2μgN/L.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report

Research Products

(5 results)

All 2017 2016

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (3 results)

  • [Journal Article] Determination of Trace Hydrazine in Environmental Water Samples by <i>in situ</i> Solid Phase Extraction2017

    • Author(s)
      Kato T, Sugahara S, Kajitani T, Senga Y, Egawa M, Kamiya H, Seike Y
    • Journal Title

      Anal. Sci.

      Volume: 33 Issue: 4 Pages: 487-491

    • DOI

      10.2116/analsci.33.487

    • NAID

      130005587974

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Sensitive method for the oxidation-determination of trace hydroxylamine in environmental water using hypochlorite followed by gas chromatography2017

    • Author(s)
      2)Kato T., S. Sgahara, M. Murakami, Y. Senga, M. Egawa, H. Kamiya, K. Omata, and Y. Seike
    • Journal Title

      Analytical Sciences

      Volume: 印刷中

    • NAID

      130005696780

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 鉄(III)の新規比色定量法の開発2017

    • Author(s)
      三輪圭哉,管原庄吾,江川美智子,清家泰
    • Organizer
      日本分析化学会第66年会(東京)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 鉄(III)の新規吸光光度定量法の開発2017

    • Author(s)
      三輪圭哉,管原庄吾,江川美智子,清家泰
    • Organizer
      第7回CSJ化学フェスタ(東京)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 汽水湖中海の底層におけるアナモックス反応に関する研究2016

    • Author(s)
      加藤季晋,管原庄吾,神谷宏,江川美千子,清家泰
    • Organizer
      第81回日本陸水学会(沖縄)
    • Place of Presentation
      沖縄,琉球大学
    • Year and Date
      2016-11-03
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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