| Project/Area Number |
16K13607
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanostructural chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
Ohno Kohji 京都大学, 化学研究所, 准教授 (00335217)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 高分子合成 / 高分子構造・物性 / ナノ材料 / 表面・界面物性 / 自己組織化 |
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| Outline of Final Research Achievements |
In order to precisely synthesize disk-like particles with narrow particle size distribution of the structure, the monodispersed polystyrene spherical particles were dispersed in water containing a small amount of THF as a good solvent, and the dispersion liquid was stirred in a rotary compression apparatus. Using the obtained particles, atom transfer radical polymerization of methyl methacrylate and styrene was carried out to synthesize disc shaped particles modified with a graft polymer having a narrow molecular weight distribution. In addition, we have newly developed a route to synthesize cobalt hydroxide disk like particles grafted polymer brushes. The process of ordered formation of the hybrid particles was observed in real space using a confocal laser scanning fluorescence microscope. As a result, it was revealed that the formed ordered structure largely depends on the molecular weight of the graft polymer of the hybrid particles, that is, their aspect ratio.
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