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State analysis of organic nanomaterials by high-resolution EELS

Research Project

Project/Area Number 16K13625
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Research InstitutionKyoto University

Principal Investigator

Kurata Hiroki  京都大学, 化学研究所, 教授 (50186491)

Research Collaborator Yamaguchi Atsushi  , 大学院生
Shirasawa Yuri  , 大学院生
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords電子エネルギー損失分光法 / 有機材料 / 有機結晶 / 電子顕微鏡 / EELS
Outline of Final Research Achievements

By combining high energy resolution electron energy loss spectroscopy (EELS) and scanning transmission electron microscope (STEM), we succeeded in measuring spectra with reduced electron beam irradiation damage on organic materials. Especially, with the aloof beam method which can measure the spectrum without directly irradiating the sample with electons, the absorption spectrum in the infrared to ultraviolet region can be measured with almost no damage.
Spectral simulation was performed on the fine structures of the carbon K-shell absorption edge measured from organic crystals by first principle band calculation, and both agreed very well. As a result, new knowledge important for the state analysis of organic molecules could be obtained.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (9 results)

All 2018 2017 2016

All Journal Article (1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results)

  • [Journal Article] Electronic state analysis by monochromated STEM-EELS2018

    • Author(s)
      Hiroki Kurata
    • Journal Title

      JEOL News

      Volume: 53 Pages: 49-53

    • Related Report
      2017 Annual Research Report
  • [Presentation] 銅フタロシアニン結晶の炭素K殻ELNESの第一原理バンド計算による解析2018

    • Author(s)
      山口睦, 根本隆, 倉田博基
    • Organizer
      日本顕微鏡学会第74回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] aloofビームによるAg-TCNQナノロッドの高分解能EELS2018

    • Author(s)
      白澤由理, 治田充貴, 根本隆, 倉田博基
    • Organizer
      日本顕微鏡学会第74回学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 精密構造観察と状態分析2017

    • Author(s)
      倉田博基
    • Organizer
      日本顕微鏡学会第60回記念シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高エネルギー分解能STEM-EELSによる電子状態分析2017

    • Author(s)
      倉田博基
    • Organizer
      日本顕微鏡学会北海道支部講演会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高エネルギー分解能EELSと有機結晶への応用2016

    • Author(s)
      倉田博基
    • Organizer
      第32回 分析電子顕微鏡討論会
    • Place of Presentation
      幕張
    • Year and Date
      2016-09-06
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] High energy resolution EELS of copper phthalocyanine crystals2016

    • Author(s)
      Hiroki Kurata, Yoshifumi Fujiyoshi, Yuriko Tomisaki, Takashi Nemoto, Mitsutaka Haruta
    • Organizer
      The 16th European Microscopy Congress
    • Place of Presentation
      Lyon, France
    • Year and Date
      2016-08-28
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 有機結晶の高エネルギー分解能EELS2016

    • Author(s)
      倉田博基、藤吉好史、富崎友理子、根本隆、治田充貴
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Place of Presentation
      仙台
    • Year and Date
      2016-06-14
    • Related Report
      2016 Research-status Report
  • [Presentation] High-resolution EELS study of organic crystals2016

    • Author(s)
      Hiroki Kurata
    • Organizer
      The 11th Asia-Pacific Microscopy Conference
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2016-05-23
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2019-03-29  

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