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Nanocomposite thin layers of in situ-embedded bismuth nanoparticles in a polymer matrix: synthesis and size-dependent thermal properties

Research Project

Project/Area Number 16K13643
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanomaterials engineering
Research InstitutionKonan University

Principal Investigator

AKAMATSU Kensuke  甲南大学, フロンティアサイエンス学部, 教授 (60322202)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywordsナノコンポジット / 金属ナノ粒子 / 潜熱蓄熱 / 蓄熱材料 / ビスマスナノ粒子 / 相変化材料 / ナノ粒子 / 低融点金属
Outline of Final Research Achievements

Thin polymer layers consisting of a polyimide matrix with bismuth nanoparticles were synthesized in situ by hydrogen reduction using an ion-doped precursor. The mean nanoparticle size could be systematically controlled from 12 to 25 nm simply by variation of the heat treatment temperature. These relatively large nanoparticles have a narrow size distribution with a standard deviation of almost 10%. The melting temperature of the embedded bismuth nanoparticles decreased as the particle size decreased, which suggests that the nanocomposite could be utilized as a phase change composite material.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (6 results)

All 2017 2016 Other

All Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Remarks (2 results)

  • [Presentation] In situ synthesis of metal/polymer nanocomposites and control of particle size and thermal properties2017

    • Author(s)
      Kensuke Akamatsu
    • Organizer
      Energy Materials Nanotechnology Americas Meetings
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Controlled Synthesis of Bismuth Nanoparticles/Polymer Nanocomposites and their Thermal Properties2017

    • Author(s)
      K. Akamatsu, T. Kawakami, Y. Takashima, T. Tsuruoka
    • Organizer
      8th international Workshop on Polymer Metal Nanocomposites
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 合成高分子中における金属ナノ粒子の合成2016

    • Author(s)
      畠茉奈美、髙嶋洋平、鶴岡孝章、赤松謙祐
    • Organizer
      第18回関西表面技術フォーラム
    • Place of Presentation
      甲南大学、兵庫県神戸市
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Fundamental aspects for design of metal nanoparticle-based composite nanostructures2016

    • Author(s)
      K. Akamatsu
    • Organizer
      The future direction of Nanomaterials and Bionanoscience in Japan-EU Cooperation
    • Place of Presentation
      Thessaloniki, Greece
    • Year and Date
      2016-07-04
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] ナノ材料化学研究室

    • URL

      http://www.konan-u.ac.jp/hp/FIRST_nanomaterials/

    • Related Report
      2017 Annual Research Report
  • [Remarks] ナノ材料科学研究室

    • URL

      http://www.konan-u.ac.jp/hp/FIRST_nanomaterials/

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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