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Plasma chemical conversion of carbon dioxide to performic acid by water-sealed dielectric barrier discharge

Research Project

Project/Area Number 16K13712
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Plasma electronics
Research InstitutionOsaka Electro-Communication University

Principal Investigator

Nakamura Toshihiro  大阪電気通信大学, 工学部, 准教授 (90293886)

Co-Investigator(Kenkyū-buntansha) 橘 邦英  大阪電気通信大学, 工学部, 客員研究員 (40027925)
Co-Investigator(Renkei-kenkyūsha) TAKAHASHI Kazuya  大阪歯科大学, 歯学部, 准教授 (10236268)
KOMASA Satoshi  大阪歯科大学, 歯学部, 助教 (70632066)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords気液界面プラズマ / 誘電体バリア放電 / 有機過酸化物 / 過ギ酸 / 二酸化炭素固定化 / CO2固定化 / 選択的物質合成 / 殺菌・滅菌・消毒
Outline of Final Research Achievements

Water-sealed dielectric barrier discharge in carbon dioxide under atmospheric pressure affords a carbon fixation pathway to peroxide products such as a performic acid. The chemical mechanisms of the catalyst-free carbon fixation were analyzed by several spectroscopic methods with the aim of improving the efficiency of the selective generation of performic acid. We measured water molecule density in dielectric barrier discharges with a gas-water interface by tunable diode laser absorption spectroscopy. The water molecule density at the gas-water interface has a significant influence on the generation of peroxide products.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (4 results)

All 2018 2017 2016

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results) Presentation (1 results)

  • [Journal Article] Measurements of water molecule density by tunable diode laser absorption spectroscopy in dielectric barrier discharges with gas-water interface2018

    • Author(s)
      K. Tachibana, T. Nakamura, M. Kawasaki, T. Morita, T. Umekawa and M. Kawasaki
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 57 Issue: 1 Pages: 0102BB-0102BB

    • DOI

      10.7567/jjap.57.0102bb

    • NAID

      210000148495

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Catalyst-free One-pot Plasma Chemical Conversion of Carbon Dioxide to Performic Acid by Water-sealed Dielectric Barrier Discharge2016

    • Author(s)
      M. Kawasaki, T. Nakamura, T. Morita, K. Tachibana
    • Journal Title

      Plasma Processes and Polymers

      Volume: 13 Issue: 12 Pages: 1230-1241

    • DOI

      10.1002/ppap.201600025

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Monolithic structure of integrated coaxial micro-hollow dielectric barrier discharges: characterization for environmental and biomedical applications2016

    • Author(s)
      K. Tachibana, T. Nakamura, H. Motomura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 55 Issue: 7S2 Pages: 07LB01-07LB01

    • DOI

      10.7567/jjap.55.07lb01

    • NAID

      210000146860

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 過ギ酸生成用気液界面誘電体バリア放電プラズマ中の水蒸気密度測定2017

    • Author(s)
      橘 邦英, 中村敏浩, 川崎三津夫, 森田達夫
    • Organizer
      第64回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report 2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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