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Development of a high-speed method for x-ray reciprocal space mapping for the four-dimensional structure analysis of nanomaterials

Research Project

Project/Area Number 16K13816
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Condensed matter physics I
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Shirasawa Tetsuro  国立研究開発法人産業技術総合研究所, 物質計測標準研究部門, 主任研究員 (80451889)

Co-Investigator(Renkei-kenkyūsha) TAKAHASHI Toshio  東京学芸大学, 教育学部, 研究員 (20107395)
MATSUSHITA Tadashi  大学共同利用機関法人高エネルギー加速器研究機構, 物質構造科学研究所, 名誉教授 (40092332)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2017: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
KeywordsX線散乱 / 逆空間マッピング / 薄膜 / ナノ構造 / X線散乱 / ナノ材料 / X線 / 表面・界面物性
Outline of Final Research Achievements

A high-speed method for three-dimensional x-ray reciprocal space mapping was developed. An iterative reconstruction method was developed, which is capable of constructing a three-dimensional reciprocal space map from a series of two-dimensional diffuse scattering pattern recorded by using the wavelength-dispersive diffractometry. To obtain a high-resolution reciprocal space map, we reduced the focus size of the wavelength-dipersive x-rays by optimizing the curvature of the curved crystal polychromator. We succeeded in constructing a three-dimensional reciprocal space map at least two times as fast as the state-of-the-art high-speed method which used a monochromatic x-rays and position-sensitive two-dimensional detector. It is indicated that an improvement of the iterative reconstruction algorism can make the developed method further faster.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (11 results)

All 2018 2017

All Journal Article (3 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 4 results)

  • [Journal Article] A quick convergent-beam laboratory X-ray reflectometer using a simultaneous multiple-angle dispersive geometry2017

    • Author(s)
      Wolfgang Voegeli, Chika Kamezawa, Etsuo Arakawa, Yohko F. Yano, Tetsuroh Shirasawa, Toshio Takahashi and Tadashi Matsushita
    • Journal Title

      Journal of Applied Crystallography

      Volume: 50 Issue: 2 Pages: 570-575

    • DOI

      10.1107/s1600576717002461

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fast Structure Determination of Electrode Surfaces for Investigating Electrochemical Dynamics Using Wavelength-Dispersive X-ray Crystal Truncation Rod Measurements2017

    • Author(s)
      Shirasawa Tetsuroh、Masuda Takuya、Voegeli Wolfgang、Arakawa Etsuo、Kamezawa Chika、Takahashi Toshio、Uosaki Kohei、Matsushita Tadashi
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 121 Issue: 44 Pages: 24726-24732

    • DOI

      10.1021/acs.jpcc.7b09784

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural Change of TiO<sub>2</sub>(110) Surface Involved in the Photoinduced Wettability Transition2017

    • Author(s)
      白澤徹郎, Voegeli Wolfgang, 荒川悦雄, 亀沢知夏, 高橋敏男, 松下正
    • Journal Title

      Hyomen Kagaku

      Volume: 38 Issue: 12 Pages: 620-625

    • DOI

      10.1380/jsssj.38.620

    • NAID

      130006262571

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] X線CTR散乱の高速測定による相界面現象のその場追跡2018

    • Author(s)
      白澤徹郎
    • Organizer
      第16回SPRUCナノ材料科学研究会・ 第13回日本表面科学会放射光表面科学研究部会・第2回日本表面科学会プローブ顕微鏡研究会合同シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] High-Speed Characterization of Surface, Interface, and Thinfilm Structures by Using Multi-Wavelength Dispersive X-ray Diffraction2017

    • Author(s)
      Tetsuroh Shirasawa
    • Organizer
      The 5th Annual Conference of AnalytiX-2017
    • Place of Presentation
      Hilton福岡シーホーク(福岡市)
    • Year and Date
      2017-03-22
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Tracking of Solid-Liquid Interfaces by a High-Speed Surface X-ray Diffraction2017

    • Author(s)
      Tetsuroh Shirasawa
    • Organizer
      The 5th Ito International Conference, RIKEN Centennial Anniversary, ISSP International Workshop & Surface and Interface Spectroscopy 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 波長分散型表面X線回折による固液界面反応のその場追跡2017

    • Author(s)
      白澤徹郎
    • Organizer
      量子ビームで視る原子層と表面
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] In-situ Structure Determination of the Pt(111) Electrode Surface during Electro-Oxidation of Methanol2017

    • Author(s)
      T. Shirasawa, T. Masuda, W. Voegeli, E. Arakawa, T. Takahashi, K. Uosaki, T. Matsushita
    • Organizer
      The 8th Internationa l Symposium on Surface Science
    • Related Report
      2017 Annual Research Report
  • [Presentation] Structural Change of the Pt(111) Electrode Surface During Electrochemical Reaction Observed Using High -Speed X-ray CTR Measurement2017

    • Author(s)
      T. Shirasawa, W. Voegeli, E. Arakawa, T. Masuda, T. Takahashi, K. Uosaki, T. Matsushita
    • Organizer
      12th International Conference on the Structure of Surface
    • Related Report
      2017 Annual Research Report
  • [Presentation] Dynamics of Methanol Oxidation on Pt(111) Observed by High-Speed Surface X-ray Diffraction2017

    • Author(s)
      T. Shirasawa, W. Voegeli, T. Masuda, E. Arakawa, T. Takahashi, K. Uosaki, T. Matsushita
    • Organizer
      2017 International Workshop on Electrified Interfaces for Energy Conversion
    • Related Report
      2017 Annual Research Report
  • [Presentation] 時分割X線CTR散乱法を用いた電気化学反応中のPt(111)電極表面構造変化の解析2017

    • Author(s)
      白澤徹郎, 増田卓也, Wolfgang Voegeli, 荒川悦雄, 高橋敏男, 魚崎浩平, 松下正
    • Organizer
      第78回 応用物理学会 秋季学術講演会
    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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