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Search for new superconductors and frustrated magnets by means of the ionic liquid synthesis method

Research Project

Project/Area Number 16K13831
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionThe University of Tokyo

Principal Investigator

HIROI ZENJI  東京大学, 物性研究所, 教授 (30192719)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords物質開発 / 超伝導 / 磁気フラストレーション / イオン液体合成 / 水熱合成 / イオン液体合成法 / 水熱合成法 / フラストレート磁性体 / 物質探索 / 強相関電子系 / 超伝導体 / フラストレーション / イオン液体
Outline of Final Research Achievements

We have carried out the syntheses of new superconductors and frustrated magnets by using the ionic liquid and hydrothermal synthesis methods in order to give a breakthrough to the materials search in the strongly correlated electron system. We prepared crystals of Te4[BixCl4] by the ionic liquid synthesis method. Although the previous study reported the superconductivity of the compound, we could not obtain the evidence for this. The hydrothermal synthesis yielded a single crystal of the new kagome antiferromagnet CdCu3(OH)6(NO3)2・H2O (CdK). We found an unconventional magnetic order with a negative vector chirality in CdK. Moreover, a series of magnetization plateaus are observed under ultrahigh magnetic fields up to 160 T, which indicates the formation of magnon crystals on the kagome net.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (10 results)

All 2018 2017

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Weak ferromagnetic order breaking the threefold rotational symmetry of the underlying kagome lattice in CdCu3 (OH)6 (NO3)2 H2O2017

    • Author(s)
      Ryutaro Okuma, Takeshi Yajima, Daisuke Nishio-Hamane, Tsuyoshi Okubo, and Zenji Hiroi
    • Journal Title

      Physical Review B

      Volume: 95 Issue: 9 Pages: 094427-094427

    • DOI

      10.1103/physrevb.95.094427

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 正四面体クラスター磁性体毒鉄鉱の中性子散乱2018

    • Author(s)
      大熊隆太郎, 古府麻衣子, 河村聖子, 中島健次, 広井善二
    • Organizer
      2018春、日本物理学会第73回年次大会(東京理科大)
    • Related Report
      2017 Annual Research Report
  • [Presentation] ファラデー回転法によるS=1/2カゴメ格子反強磁性体CdCu3(NO3)2(OH)6・H2O(CdK)の全磁化過程の観測2017

    • Author(s)
      大熊隆太郎, 中村大輔, 嶽山正二郎, 広井善二
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市待兼山町)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 正四面体クラスター磁性体毒鉄鉱KFe4(AsO4)3(OH)4nH2O(A = alkali metal, H3O)の磁性2017

    • Author(s)
      鳥巣崇生, 大熊隆太郎, 高野幹夫A, 廣井善二
    • Organizer
      日本物理学会第72回年次大会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市待兼山町)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] テルルクラスターが一次元に積層した超伝導体Te4Bi0.74Cl4 の合成と物性2017

    • Author(s)
      大熊隆太郎, 広井善二
    • Organizer
      2017秋、日本物理学会秋期大会(岩手大学)
    • Related Report
      2017 Annual Research Report
  • [Presentation] S = 1/2カゴメ格子反強磁性体CdCu3(OH)6(NO3)2・H2Oにおけるプラトー相の解析2017

    • Author(s)
      大熊隆太郎, 中村大輔, 嶽山正二郎, 広井善二
    • Organizer
      2017秋、日本物理学会秋期大会(岩手大学)
    • Related Report
      2017 Annual Research Report
  • [Presentation] ファラデー回転法によるS=1/2カゴメ格子反強磁性体CdCu3(NO3)2(OH)6・H2O(CdK)の全磁化過程の観測2017

    • Author(s)
      大熊隆太郎, 中村大輔, 嶽山正二郎, 広井善二
    • Organizer
      2017春、日本物理学会第72回年次大会(大阪大学)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 正四面体クラスター磁性体毒鉄鉱KFe4(AsO4)3(OH)4nH2O(A = alkali metal, H3O)の磁性2017

    • Author(s)
      鳥巣崇生, 大熊隆太郎, 高野幹夫A, 廣井善二
    • Organizer
      2017春、日本物理学会第72回年次大会(大阪大学)
    • Related Report
      2017 Annual Research Report
  • [Presentation] Suprises in the kagome cuprates2017

    • Author(s)
      Z. Hiroi
    • Organizer
      APCTP Workshop on Quantum Magnetism
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Search for Novel Quantum States in Highly-Frustrated Magnets2017

    • Author(s)
      Z. Hiroi
    • Organizer
      Junjiro Kanamori Memorial International Symposium
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2019-03-29  

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