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Development of the technique to measure thermal conductivity of small samples at high temperatures and its application to organic thermoelectric materials

Research Project

Project/Area Number 16K13840
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Condensed matter physics II
Research InstitutionOsaka City University

Principal Investigator

Yoshino Harukazu  大阪市立大学, 大学院理学研究科, 准教授 (60295681)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords熱伝導率 / 熱電材料 / 有機伝導体 / 熱伝導度 / 定常比較法 / 熱輻射 / 有機熱電材料 / 輸送現象測定
Outline of Final Research Achievements

Thermoelectric materials, which can directly generate electricity from temperature difference, are promising to utilize waste heat. The efficiency of a material becomes higher for lower thermal conductivity. At higher temperature above 200 K, however, the experimental error in the thermal conductivity due to heat radiation makes the accurate estimate of the efficiency very difficult. In this study, we improved our own technique to measure thermal conductivity with a steady-state comparative method. By optimizing the arrangement of reference samples to a target sample, we have successfully calibrated the influence of the heat radiation as well as unexpected heat leak through thermocouples to measure the temperature difference along the target and reference samples. We applied the improved technique to samples of a p-type organic conductor (TTT)2I3 and compared the results with that obtained by the conventional method.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (11 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (1 results)

  • [Int'l Joint Research] National Hellenic Research Foundation(Greece)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] 数値計算によるディラック電子系の巨大ローレンツ数の解明2017

    • Author(s)
      吉野治一
    • Journal Title

      熱測定

      Volume: 44 Pages: 93-100

    • NAID

      40021281288

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] 擬一次元有機伝導体(TTT)3I3+δ (δ < 0.1)の熱電性能指数の試料依存性2018

    • Author(s)
      吉野治一,長谷川祥史,黒田菜月,田中里佳,小嵜正敏
    • Organizer
      2018年 第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 擬一次元有機伝導体(TTT)3I3+δの無次元熱電性能指数ZTの試料依存性2018

    • Author(s)
      吉野治一,長谷川祥史,黒田菜月,田中里佳,小嵜正敏
    • Organizer
      日本物理学会第73回年次大会(2018年)
    • Related Report
      2017 Annual Research Report
  • [Presentation] τ-(EDO-S,S-DMEDT-TTF)2(AuBr2)1+y (y ≦ 0.875)のキャリア密度と無次元熱電性能指数ZTの試料依存性2018

    • Author(s)
      菅原寛人,吉野治一,G. C. Anyfantis,G. C. Papavassiliou
    • Organizer
      日本物理学会第73回年次大会(2018年)
    • Related Report
      2017 Annual Research Report
  • [Presentation] 擬一次元有機伝導体(TTT)2I3の無次元熱電性能指数ZT2017

    • Author(s)
      長谷川祥史,黒田菜月,小嵜正敏,吉野治一
    • Organizer
      日本物理学会第72回年次大会(2017年)
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Thermoelectric Figure of Merit ZT of Quasi-One-Dimensional Organic Conductor (TTT)2I3 (TTT = tetrathiatetracene)2017

    • Author(s)
      H. Yoshino, A. Hasegawa, N. Kuroda, R. Tanaka and M. Kozaki,
    • Organizer
      12th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2017)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 擬一次元有機伝導体(TTT)2I3のESR測定2017

    • Author(s)
      中村敏和,浅田瑞枝,長谷川祥史,小嵜正敏,吉野治一
    • Organizer
      日本物理学会2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 気相成長させたトポロジカル絶縁体Bi2-xSbxTe3-ySey薄膜の電子状態:輸送現象の膜厚依存性II2016

    • Author(s)
      松下ステファン悠,T.-N. Han,田邉洋一,K.-K. Huynh,渡部智貴,L.-H. Phuoc,吉野治一,谷垣勝己
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学(石川県金沢市)
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Thermal Conductivity of the Organic Conductors: Phase Transitions and Thermoelectric Figure of Merit2016

    • Author(s)
      Harukazu Yoshino
    • Organizer
      Joint Meeting of the Japan Society of Calorimetry and Thermal Analysis and the Calorimetry Conference (CalCon2016)
    • Place of Presentation
      Hawaii (USA)
    • Year and Date
      2016-07-31
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] 物性研究者 吉野治一のぺーじ 【業績リスト】

    • URL

      http://e.sci.osaka-cu.ac.jp/yoshino/study/publication.shtml

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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