Development of analytical method for quantitative determination of multi-elements in geological samples by LIBS-ICPMS tandem system
Project/Area Number |
16K13905
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Research Category |
Grant-in-Aid for Challenging Exploratory Research
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Allocation Type | Multi-year Fund |
Research Field |
Petrology/Mineralogy/Economic geology
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Research Institution | The University of Tokyo |
Principal Investigator |
Ishikawa Akira 東京大学, 大学院総合文化研究科, 助教 (20524507)
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Research Collaborator |
KIMURA Junichi 国立研究開発法人海洋研究開発機構, 地球内部物質循環研究分野, 分野長代理 (30241730)
HIRATA Takafumi 東京大学, 大学院理学系研究科, 教授 (10251612)
SANO Takashi 独立行政法人国立科学博物館, 地学研究部, 研究グループ長 (40329579)
SHIMIZU Kenji 国立研究開発法人海洋研究開発機構, 高知コア研究所, 技術研究員
KONSTANTIN Litasov ロシア科学アカデミー, シベリア支部ソボレフ地質学鉱物学研究所, 教授
SHARYGIN Igor S. ロシア科学アカデミー, シベリア支部ソボレフ地質学鉱物学研究所, 研究員
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Project Period (FY) |
2016-04-01 – 2018-03-31
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Project Status |
Completed (Fiscal Year 2017)
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Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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Keywords | LIBS / ICPMS / 主要元素 / 微量元素 / 揮発性元素 / レーザー誘起ブレークダウン分光分析 / レーザーアブレーション ICP 質量分析 / LA-ICPMS |
Outline of Final Research Achievements |
Simultaneous laser-induced breakdown spectroscopy (LIBS) and laser-ablation ICP mass spectrometry (LA-ICPMS) measurements were attempted to develop a simple analytical method for quantitative determination of whole-rock major, trace and volatile element concentration in geological materials. The method is potentially useful for rapid but quantitative evaluation of whole-rock compositions by multi-spot analyses on pressed powder pellets or cross-sections of rocks comprised of variable mixture of hydrous silicate, carbonate and phosphate minerals. However, present study revealed that simultaneous measurements of H2O, CO2 and other elements in heterogeneous samples were difficult to perform on pressed powder pellets or cross-sections with the use of 213nm Nd:YAG laser and single channel detector. Whereas, the LIBS-ICPMS tandem system can be applied for rapid determinations of major, minor and trace element concentrations in the fused-glass beads (rock powder + lithium tetraborate).
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Report
(3 results)
Research Products
(31 results)
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[Journal Article] Collision-induced post-plateau volcanism: evidence from a seamount on Ontong Java Plateau2017
Author(s)
Hanyu, T., M. L. G. Tejada, K. Shimizu, O. Ishizuka, T. Fujii, J. -I. Kimura, Q. Chang, R. Senda, T. Miyazaki, Y. Hirahara, B. S., Vagalov, K. T., Goto, A. Ishikawa
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Journal Title
Lithos
Volume: 294-295
Pages: 87-96
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Widespread tungsten isotope anomalies and W mobility in crustal and mantle rocks of the Eoarchean Saglek Block, northern Labrador, Canada: implications for early Earth processes and W recycling2016
Author(s)
Liu, J.G., Touboul, M., Ishikawa, A., Walker, R.J., Pearson, D.G.
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Journal Title
Earth and Planetary Science Letters
Volume: 448
Pages: 13-23
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] In situ oxygen-isotope, major-, and trace-element constraints on the metasomatic modification and crustal origin of a diamondiferous eclogite from Roberts Victor, Kaapvaal Craton2016
Author(s)
Riches, A.J.V., Ickert, R.B., Pearson, D.G., Stern, R.A., Jackson, S.E., Ishikawa, A., Kjarsgaard, B.A., Gurney, J.J.
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Journal Title
Geochimica et Cosmochimica Acta
Volume: 174
Pages: 345-359
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Occurrence and geochronology of the Eoarchean, ~3.9 Ga, Iqaluk Gneiss in the Saglek Block, northern Labrador, Canada: Evidence for the oldest supracrustal rocks in the world2016
Author(s)
Shimojo, M., Yamamoto, S., Sakata, S., Maki, K., Sawaki, Y., Ishikawa, A., Aoki, K., Okada, Y., Aoki, S., Koshida, K., Hirata, T., Collerson, K. D., Komiya, T.
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Journal Title
Precambrian Research
Volume: 278
Pages: 218-243
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Presentation] Osmium isotope and PGE signatures of the deep-sea deposits from Japan: implications for the Late Triassic impact event2017
Author(s)
Sato, H., Nozaki, T., Ishikawa, A., Onoue, T., Kimura, J.-I., Chang, Q. Suzuki, K.
Organizer
Goldschmidt Conference
Related Report
Int'l Joint Research
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