Synthesis, Structures, and Properties of Icosasiladodecahedrane and Related Compounds
| Project/Area Number |
16K13944
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 曲面σ共役 / ボウル形オリゴシラン / デカシラヘキサヒドロトリキナセン / デカシライソツイスタン / オリゴシランデンドリマー / 電荷移動錯体 / 合成化学 / イコサシラドデカヘドラン / 有機ケイ素クラスター |
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| Outline of Final Research Achievements |
Decasilahexahydrotriquinacene (1) and decasilaisotwistane (2) were synthesized, and their structures and electronic properties were studied. Compounds 1 and 2 were synthesized by the reduction of tris(1,3-dibromo-2-trisilanyl)methylsilane with 6.3 equiv of potassium graphite. The structure of 1 was determined by NMR spectra and theoretical calculations. The structure of 2 was determined by X-ray crystallography. The UV spectra of 1 and 2 show that the lowest energy absorption band of 1 is bathochromically shifted compared with that of 2. This result was analyzed by theoretical calculations of 1 and 2.
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Report
(3 results)
Research Products
(11 results)
