• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Creation of pi-Conjugated System Possessing a Long Exciton Diffusion Length toward Efficient Organic Solar Cells

Research Project

Project/Area Number 16K13945
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Organic chemistry
Research InstitutionSaitama University

Principal Investigator

FURUKAWA Shunsuke  埼玉大学, 理工学研究科, 助教 (70625590)

Co-Investigator(Renkei-kenkyūsha) SAEKI Akinori  大阪大学, 大学院 工学研究科, 准教授 (10362625)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords有機薄膜太陽電池 / 高周期14族化合物 / テトリレノイド / 面外異方性分子 / 長寿命励起子 / イオン結晶 / ヘテラスマネン / 半導体材料 / 太陽電池
Outline of Final Research Achievements

During this research, we found two unexpected results. First, we have succeeded in synthesizing new organolead compounds known as plumbylenoid. We revealed the structures and properties of the obtained the species. Second, we have created a new pi-conjugated molecules having front/back two-faced character. We elucidated its electronic character, and demonstrated the surface treatment of metal surfaces by using the obtained compound.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (14 results)

All 2018 2017 2016

All Journal Article (5 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Disodium Benzodipyrrole Sulfonate as Neutral Hole-Transporting Materials for Perovskite Solar Cells2018

    • Author(s)
      Rui Shang*, Zhongmin Zhou, Hiroki Nishioka, Henry Halim, Shunsuke Furukawa, Izuru Takei, Naoya Ninomiya, and Eiichi Nakamura
    • Journal Title

      Journal of the American Chemical Society

      Volume: 140 Issue: 15 Pages: 5018-5022

    • DOI

      10.1021/jacs.8b01783

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis and Properties of Spiro-type Heterasumanenes containing Group 14 Elements as Bridging Atoms2018

    • Author(s)
      Furukawa, S.; Hayashi, K.; Yamagishi, K.; Saito, M.
    • Journal Title

      Mater. Chem. Front.

      Volume: 印刷中 Issue: 5 Pages: 929-934

    • DOI

      10.1039/c7qm00590c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Reactivity of a Ruthenocene-type Complex bearing an Aromatic π-Ligand with the Heaviest Group 14 Element2017

    • Author(s)
      Marisa Nakada, Takuya Kuwabara, Shunsuke Furukawa, Masahiko Hada, Mao Minoura, Masaichi Saito
    • Journal Title

      Chemical Science

      Volume: 8 Issue: 4 Pages: 3092-3097

    • DOI

      10.1039/c6sc04843a

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Triphosphasumanene Trisulfide: High Out-of-Plane Anisotropy and Janus-Type π-Surfaces2017

    • Author(s)
      Shunsuke Furukawa, Yuki Suda, Junji Kobayashi, Takayuki Kawashima, Tomofumi Tada, Shintaro Fujii, Manabu Kiguchi, Masaichi Saito
    • Journal Title

      Journal of the Americal Chemical Society

      Volume: 139 Issue: 16 Pages: 5787-5792

    • DOI

      10.1021/jacs.6b12119

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anisotropic Crystals Based on Main-group Coordination Polymer with Alignment of Rigid π-Skeletons2017

    • Author(s)
      M. Saito, T. Akiba, S. Furukawa, M. Minoura, M. Hada and H. Y. Yoshikawa
    • Journal Title

      Organometallics

      Volume: 36 Issue: 14 Pages: 2487-2490

    • DOI

      10.1021/acs.organomet.7b00217

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Presentation] Triphosphasumanenes: Janus-Type π-Conjugated Molecules and Their Out-of-Plane Anisotropy2018

    • Author(s)
      Shunsuke Furukawa, Yuki Suda, Masaichi Saito
    • Organizer
      International Congress on Pure&Applied Chemistry 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Out-of-Plane Anisotropy of Triphosphasumanene Derivatives and Their Application to Organic/Metal Interfaces2018

    • Author(s)
      古川俊輔,須田祐貴,小林潤司,川島隆幸,多田朋史,藤井慎太郎,木口学,斎藤雅一
    • Organizer
      日本化学会第98回春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボウル型トリカルコゲナスマネンを基本π骨格とする共有結合性有機構造体(COF)の合成と性質2017

    • Author(s)
      林敬祐,古川俊輔,斎藤雅一
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス,神奈川県横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] スピロ架橋型ヘテラスマネンの合成とその段階的酸化還元挙動2017

    • Author(s)
      山岸健,林敬祐,古川俊輔,斎藤雅一
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス,神奈川県横浜市
    • Year and Date
      2017-03-16
    • Related Report
      2016 Research-status Report
  • [Presentation] スピロ架橋型ヘテラスマネン類の系統的合成とその性質2017

    • Author(s)
      山岸健,林敬祐,古川俊輔,斎藤雅一
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] ボウル型ヘテラスマネンを鍵骨格としたヘキサゴナルネットワークの創製2017

    • Author(s)
      林敬祐,古川俊輔,酒巻大輔,関修平,斎藤雅一
    • Organizer
      第28回基礎有機化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大きな面外異方性を有するトリホスファスマネンの金属界面での物性2016

    • Author(s)
      須田祐貴,古川俊輔,小林潤司,川島隆幸,多田朋史,藤井慎太郎,木口学,斎藤雅一
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      タワーホール船堀,東京都江戸川区
    • Year and Date
      2016-11-14
    • Related Report
      2016 Research-status Report
  • [Presentation] ボウル型トリへテラスマネンを基本π骨格とする共有結合性有機構造体(COF)の合成2016

    • Author(s)
      林敬祐,古川俊輔,斎藤雅一
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場,広島県広島市
    • Year and Date
      2016-09-01
    • Related Report
      2016 Research-status Report
  • [Presentation] Triphosphasumanenes2016

    • Author(s)
      Shunsuke Furukawa, Junji Kobayashi, Takayuki Kawashima, Masaichi Saito
    • Organizer
      International Conference on Phosphorus Chemistry
    • Place of Presentation
      Kazan, Russia
    • Year and Date
      2016-06-05
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi