| Project/Area Number |
16K13950
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
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| Keywords | 光有機分子触媒 / 光触媒 / ケトン / イミン / 有機合成化学 / 有機分子触媒 / 光化学 / ラジカル |
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| Outline of Final Research Achievements |
Study on the development of a new catalytic function of photoexcited ketones was pursued. The high catalytic activity of the ketones was confirmed in a model reaction which was designed for evaluating the expected new catalytic function. However, the mechanistic analysis by the physicochemical approach is not completed yet and I could not come to clarify the details the catalysis within a study period. On the other hand, I conducted some experimental analyses on photoexcited imines which have been regarded as a ketone analog in synthetic chemistry. Markedly, new photophysical properties were found in this study and these finding will open the door to a new field of the photochemistry.
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