Development of Molecular Transformation Through the Synergy of Aluminum and Conjugated Systems
| Project/Area Number |
16K13953
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | Ibaraki University |
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Principal Investigator |
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | アルミニウム / アルモール / 共役電子系 / 触媒反応 / 分子活性化 / ホスファアルメン / 遷移金属錯体 / ポルフィリン / 金属錯体 / 共役系 / ルイス酸 / 触媒 |
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| Outline of Final Research Achievements |
We have investigated the synthesis and reactivity of alumole (aluminacyclopentadiene)-transition metal complexes as potential catalysts for small molecule activation reactions. Reactivity of stable alumoles with various small molecules were also investigated, while inorganic small molecules, such as dihydrogen and carbon monoxide, did not react with the almoles under ambient conditions. We have investigated the synthesis of phosphaalumenes, Al=P conjugated systems.
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Report
(3 results)
Research Products
(33 results)
