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Chiral network formation using an achiral ligand by rheology

Research Project

Project/Area Number 16K13960
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kawano Masaki  東京工業大学, 理学院, 教授 (30247217)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords配位高分子 / 結晶化学 / キラル / レオロジー
Outline of Final Research Achievements

Two kinds of microporous network complexes were synthesized by heating the ligand capable of multipoint interaction and the copper iodide complex in a solvent and then controlling the speed of crystallization. The porosity of the network complex with small pores was 18%, the space group was not the desired chiral space group at P-1. On the other hand, the void ratio of the network complex with the larger pore was 80%, the interaction site was exposed on the pore surface, and it was found that it has the chiral space group of P212121. Furthermore, we investigated selective synthesis of network using rheology effect by adding surfactant etc. As a result, it succeeded mainly in synthesis of chiral network by utilizing larger temperature gradient, but the rheology effect should be necessary to carefully verify.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (29 results)

All 2018 2017 2016 Other

All Int'l Joint Research (5 results) Journal Article (19 results) (of which Int'l Joint Research: 14 results,  Peer Reviewed: 19 results,  Open Access: 9 results) Presentation (4 results) (of which Int'l Joint Research: 3 results,  Invited: 4 results) Remarks (1 results)

  • [Int'l Joint Research] 浦項工科大学(韓国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] マンチェスター大学(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] シドニー大学(オーストラリア)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] マンチェスター大学(英国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] 浦項工科大学(韓国)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Spectroscopic, Electronic and Computational Properties of a Mixed Tetrachalcogenafulvalene and its Charge Transfer Complex2018

    • Author(s)
      Walwyn, R. J.; Chan, B.; Usov, P. M.; Solomon, M. B.; Duyker, S. G.; Koo, J. Y.; Kawano, M.; Turner, P.; Kepert, C. J.; D'Alessandro, D. M.
    • Journal Title

      J. Mater. Chem. C

      Volume: 6 Issue: 5 Pages: 1092-1104

    • DOI

      10.1039/c7tc03853d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks2018

    • Author(s)
      Ha Joo Yeon、Koo Jin Young、Ohtsu Hiroyoshi、Yakiyama Yumi、Kim Kimoon、Hashizume Daisuke、Kawano Masaki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 57 Issue: 17 Pages: 4717-4721

    • DOI

      10.1002/anie.201713035

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Tris(2-hydroxyphenyl)triazasumanene: bowl-shaped excited-state intramolecular proton transfer (ESIPT) fluorophore coupled with aggregation-induced enhanced emission (AIEE)2018

    • Author(s)
      Kaewmati Patcharin、Yakiyama Yumi、Ohtsu Hiroyoshi、Kawano Masaki、Haesuwannakij Setsiri、Higashibayashi Shuhei、Sakurai Hidehiro
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 2 Issue: 3 Pages: 514-519

    • DOI

      10.1039/c7qm00530j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Intermediate-Spin Iron(III) Complexes Having a Redox-Noninnocent Macrocyclic Tetraamido Ligand2018

    • Author(s)
      Kojima Takahiko、Ogishima Fumiya、Nishibu Takahisa、Kotani Hiroaki、Ishizuka Tomoya、Okajima Toshihiro、Nozawa Shunsuke、Shiota Yoshihito、Yoshizawa Kazunari、Ohtsu Hiroyoshi、Kawano Masaki、Shiga Takuya、Oshio Hiroki
    • Journal Title

      Inorganic Chemistry

      Volume: NA Issue: 16 Pages: 9683-9695

    • DOI

      10.1021/acs.inorgchem.8b00037

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Supramolecular Nanostructures of Chiral Perylene Diimides with Amplified Chirality for High-Performance Chiroptical Sensing2017

    • Author(s)
      X. Shang, I. Song, H. Ohtsu, Y. H. Lee, T. Zhao, T. Kojima, J. H. Jung, M. Kawano, J. H. Oh
    • Journal Title

      Adv. Mater.

      Volume: ー Issue: 21 Pages: 1605828-1605828

    • DOI

      10.1002/adma.201605828

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Field-Induced Slow Magnetic Relaxation of Gd(III) Complex with Pt-Gd Heterometallic Bond2017

    • Author(s)
      T. Yoshida, G. Cosquer, D. C. Izuogu, H. Ohtsu, M. Kawano, Y. -H. Lan, W. Wernsdorfer, H. Nojiri, B. K. Breedlove, M. Yamashita
    • Journal Title

      Chem. Eur. J.

      Volume: ー Issue: 19 Pages: 4551-4556

    • DOI

      10.1002/chem.201700886

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Kinetic assembly of coordination networks2017

    • Author(s)
      Ohtsu Hiroyoshi、Kawano Masaki
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 63 Pages: 8818-8829

    • DOI

      10.1039/c7cc04277a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Amorphous-amorphous transition in a porous coordination polymer2017

    • Author(s)
      Ohtsu Hiroyoshi、Bennett Thomas D.、Kojima Tatsuhiro、Keen David A.、Niwa Yasuhiro、Kawano Masaki
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 52 Pages: 7060-7063

    • DOI

      10.1039/c7cc03333h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural Investigation of Chemiresistive Sensing Mechanism in Redox-Active Porous Coordination Network2017

    • Author(s)
      Kim Jaejun、Koo Jin Young、Lee Yoon Ho、Kojima Tatsuhiro、Yakiyama Yumi、Ohtsu Hiroyoshi、Oh Joon Hak、Kawano Masaki
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 15 Pages: 8735-8738

    • DOI

      10.1021/acs.inorgchem.7b01165

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] “Polymerizable Ionic Liquid Crystals Comprising Polyoxometalate Clusters toward Inorganic-Organic Hybrid Solid Electrolytes”2017

    • Author(s)
      T. Ito S. Otobe T. Oda T. Kojima S. Ono M. Watanabe Y. Kiyota T. Misawa S. Koguchi M. Higuchi M. Kawano Y. Nagase
    • Journal Title

      Polymers

      Volume: 9 Issue: 7 Pages: 290-290

    • DOI

      10.3390/polym9070290

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of a C70 Fragment Buckybowl C28H14 from a C60 Fragment Sumanene2017

    • Author(s)
      S. Hishikawa, Y. Okabe, R. Tsuruoka, S. Higashibayashi, H. Ohtsu, M. Kawano, Y. Yakiyama, H. Sakurai
    • Journal Title

      Chemical Letters

      Volume: 46 Issue: 10 Pages: 1556-1559

    • DOI

      10.1246/cl.170612

    • NAID

      130006140000

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Selective Formation of Conductive Network by Radical-Induced Oxidation2016

    • Author(s)
      Koo, J.-Y.; Yakiyama, Y.; Lee, G.-R.; Lee, J.; Choi, H. C.; Morita, Y.; Kawano, M.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 6 Pages: 1776-1779

    • DOI

      10.1021/jacs.5b12355

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Crystallinity-dependence of ionic conductivity in ion pairs of multi-interactive anion2016

    • Author(s)
      G. R. Lee, H. Ohtsu, J. Y. Koo, Y. Yakiyama, M. J. Park, D. Inoue, D.Hashizume, M. Kawano
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 20 Pages: 3962-3965

    • DOI

      10.1039/c5cc10136k

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Br2 induced oxidative pore modification of a porous coordination network2016

    • Author(s)
      H.Ohtsu, M. Kawano
    • Journal Title

      Dalton. Trans.

      Volume: 45 Issue: 2 Pages: 489-493

    • DOI

      10.1039/c5dt04122h

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct Observation of Ordered High-Spin-Low-Spin Intermediate States of an Iron(III) Three-Step Spin-Crossover Complex2016

    • Author(s)
      Z.-Y. Li, H. Ohtsu, T. Kojima, J.-W. Dai, T. Yoshida, B. K. Breedlove, W.-X. Zhang, H. Iguchi, O. Sato, M. Kawano, M. Yamashita
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 17 Pages: 5184-5189

    • DOI

      10.1002/anie.201511281

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Optically visible phase separation between Mott-Hubbard and charge-density-wave domains in a Pd-Br chain complex2016

    • Author(s)
      T. Yoshida, S. Takaishi, H. Iguchi, H. Okamoto, H. Tanaka, S. Kuroda, Y. Hosomi, S. Yoshida, H. Shigekawa, T. Kojima, H. Ohtsu, M. Kawano, B. K. Breedlove, L. Gué rin, and M. Yamashita
    • Journal Title

      ChemistrySelect

      Volume: 2 Issue: 2 Pages: 259-263

    • DOI

      10.1002/slct.201600065

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Safe P4 reagent in a reusable porous coordination network2016

    • Author(s)
      W. Choi, H. Ohtsu, Y. Matsushita, M. Kawano
    • Journal Title

      Dalton. Trans.

      Volume: 45 Issue: 15 Pages: 6357-6360

    • DOI

      10.1039/c6dt00860g

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Isolation and Evolution of Labile Sulphur Allotropes via Kinetic Encapsulation in Interactive Porous Networks2016

    • Author(s)
      H. Kitagawa, H. Ohtsu, A. J. Cruz-Cabeza, M. Kawano
    • Journal Title

      IUCrJ

      Volume: 3 Issue: 4 Pages: 232-236

    • DOI

      10.1107/s2052252516008423

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Crystalline-Amorphous-Crystalline Transformation in a Highly Brilliant Luminescent System with Trigonal-Planar Gold(I) Centers2016

    • Author(s)
      K. Igawa, N. Yoshinari, M. Okumura, H. Ohtsu, M. Kawano, T. Konno
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 26002-26002

    • DOI

      10.1038/srep26002

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Kinetic assembly of porous coordination networks2017

    • Author(s)
      河野正規
    • Organizer
      ACCC6
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 非平衡系を利用した結晶空間の設計2017

    • Author(s)
      河野正規
    • Organizer
      日本結晶学会平成29年度年会・シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] REDOX-ACTIVE COORDINATION NETWORKS2016

    • Author(s)
      Masaki Kawano
    • Organizer
      International Workshop on Porous Coordination Compounds (IWPCC) 2016
    • Place of Presentation
      Altay, Russia
    • Year and Date
      2016-09-19
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] X-Ray Snapshot of Chemical Processes in Interactive Porous Networks2016

    • Author(s)
      Masaki Kawano
    • Organizer
      The 2016 Dynamic Structural Science Workshop
    • Place of Presentation
      Abingdon,UK
    • Year and Date
      2016-04-25
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Remarks] 河野正規研究室 ホームページ

    • URL

      http://www.chemistry.titech.ac.jp/~kawano/

    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2022-06-16  

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