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Development of Luminescence Changeable Organic Crystals aiming for Bio-sensing Materials

Research Project

Project/Area Number 16K13979
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionOsaka University

Principal Investigator

Tohnai Norimitsu  大阪大学, 工学研究科, 准教授 (30346184)

Co-Investigator(Renkei-kenkyūsha) HISAKI Ichiro  大阪大学, 大学院工学研究科, 助教 (90419466)
Research Collaborator MIYANO Tetsuya  
TSUCHIYA Keiho  
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords有機塩 / 多孔質材料 / 分子認識 / 非線形光学効果 / 蛍光発光 / 結晶工学 / 多孔質構造 / 電荷補助型水素結合 / 超分子複合体 / 超分子 / 発光変換 / 自己組織化
Outline of Final Research Achievements

The purpose of this study is to develop an optics changeable organic crystal responsive to external stimuli, which would be applied for sensing tools and imaging materials. In order to realize this theme, we employed organic salts composed of aromatic sulfonate and various amines. Chiral amines and 4-aminoazobenzene-4-sulfonic acid gives organic salts which have polar crystals by incorporating guest molecules to yield hyperpolarizability. Guest molecules precisely controlled the polarity and then the crystals became to generate a large non-linear optical (NLO) effect. Triphenylmetylamine (TPMA) and 2-sulfophenyl anthracene (2-SPA) constructed five types of different porous organic salts (POS) depending on template molecules. These POS crystals give various luminescent properties responsive to the difference in molecular and electronic structure of the templates. These effects responsive to chemical species are significant for sensing and imaging materials.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (20 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (9 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results)

  • [Int'l Joint Research] University of Milano Bicocca(イタリア)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Aggregation-Induced Singlet Oxygen Generation: Functional Fluorophore and Anthrylphenylene Dyad Self-Assemblies2018

    • Author(s)
      S. Kim, Y. Zhou, N. Tohnai, H. Nakatsuji, M. Matsusaki, M. Fujitsuka, M. Miyata, T. Majima
    • Journal Title

      Chem. Eur. J.

      Volume: 24 Issue: 3 Pages: 636-645

    • DOI

      10.1002/chem.201703686

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic Polymorph Formation During Evaporative Crystallization from Solution: The Key Role of Liquid-like Clusters as "Crucible" at Ambient Temperature2018

    • Author(s)
      Oka, N.; Ito, F.; Haketa, Y.; Maeda, H.; Miyano, T.; Tohnai, N.; Ito, S.; Miyasaka, H.; Ozeki, S.
    • Journal Title

      Chem. Eur. J.

      Volume: 24 Issue: 17 Pages: 4343-4349

    • DOI

      10.1002/chem.201705356

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical and Structural Properties of ESIPT Inspired HBT-Fluorene Molecular Aggregates and Liquid Crystals2017

    • Author(s)
      V. S. Padalkar, Y. Tsutsui, T. Sakurai, D. Sakamaki, N. Tohnai, K. Kato, M. Takata, T. Akutagawa, K.-i. Sakai, S. Seki
    • Journal Title

      J. Phys. Chem. B

      Volume: 121 Issue: 45 Pages: 10407-10416

    • DOI

      10.1021/acs.jpcb.7b08073

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] AIE Active Carbazole-Benzothiazole Based ESIPT Motifs: Positional Isomers Directing the Optical and Electronic Properties2017

    • Author(s)
      V. Padalkar, K. Kuwada, D. Sakamaki, N. Tohnai, T. Akutagawa, K. Sakai, T. Sakurai, and S. Seki
    • Journal Title

      Chem. Select

      Volume: 2 Issue: 5 Pages: 1959-1966

    • DOI

      10.1002/slct.201602044

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Thermoresponsive Emission Switching via Lower Critical Solution Temperature Behavior of Organic-Inorganic Perovskite Nanoparticles2017

    • Author(s)
      Nishikubo Ryosuke、Tohnai Norimitsu、Hisaki Ichiro、Saeki Akinori
    • Journal Title

      Adv. Mater.

      Volume: 29 Issue: 23 Pages: 1700047-1700047

    • DOI

      10.1002/adma.201700047

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Strategy to Construct Functional Porous Crystals by Mixed Crystallization through Charge Transfer Interaction2017

    • Author(s)
      Tetsuya Miyano, Ichiro Hisaki, Norimitsu Tohnai
    • Journal Title

      Chem. Lett.

      Volume: 46 Issue: 2 Pages: 225-227

    • DOI

      10.1246/cl.160947

    • NAID

      130005317099

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Photoinduced electron transfer in porous organic salt crystals impregnated with fullerenes2016

    • Author(s)
      Tetsuya Hasegawa, Kei Ohkubo, Ichiro Hisaki, Mikiji Miyata, Norimitsu Tohnai, Shunichi Fukuzumi
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 51 Pages: 7928-7931

    • DOI

      10.1039/c6cc02377k

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Hierarchical Construction of SHG-active Polar Crystals by Using Multi-component Crystals2016

    • Author(s)
      Tetsuya Miyano, Tatsuya Sakai, Ichiro Hisaki, Hideki Ichida, Yasuo Kanematsu, Norimitsu Tohnai
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 94 Pages: 13710-13713

    • DOI

      10.1039/c6cc07544d

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Structurally Variable Porous Organic Salt based on Multi-directional Supramolecular Cluster2016

    • Author(s)
      Tetsuya Miyano, Naoki Okada, Ryunosuke Nishida, Atsushi Yamamoto, Ichiro Hisaki, Norimitsu Tohnai
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 43 Pages: 15430-15436

    • DOI

      10.1002/chem.201602233

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] スルホン酸とアミンによる多孔質有機塩の分子設計による構造安定性制御2018

    • Author(s)
      冨本篤功・土屋慧歩・藤内謙光・久木一朗
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] テトラスルホン酸と嵩高いアミンによる四面体型多孔質有機塩(d-POS)の構築とその触媒反応場への応用2018

    • Author(s)
      土屋慧歩・久木一朗・藤内謙光
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Hierarchical Construction of Versatile Diamondoid Porous Organic Salts (d-POS)2017

    • Author(s)
      藤内謙光
    • Organizer
      The 34th International Conference of Photopolymer Science and Technology
    • Related Report
      2017 Annual Research Report
  • [Presentation] 超分子的アプローチによる 多孔質有機塩の 階層的構築と機能制御2017

    • Author(s)
      藤内謙光
    • Organizer
      平成29年度日本結晶学会年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Construction of Triangle-Shaped Porous Structure with Organic Salts composed of Aromatic Divinylsulfonic Acids and Triphenylmethylamine2017

    • Author(s)
      藤内 謙光
    • Organizer
      Taiwan-Japan Bilateral Workshop 2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 刺激に応じて輝きを変える有機宝石! 発光性多孔質有機塩2016

    • Author(s)
      藤内 謙光
    • Organizer
      CSJ化学フェスタ
    • Place of Presentation
      東京
    • Year and Date
      2016-11-14
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] Construction of Diamondoid Porous Organic Salts (d-POS) with Various Connectivities and their Properties2016

    • Author(s)
      Norimitsu Tohnai
    • Organizer
      7th Japan-Taiwan Bilateral Workshop on Nano-Science
    • Place of Presentation
      Kagoshima, Japan
    • Year and Date
      2016-10-31
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] ターフェニルジスルホン酸誘導体を用いた柔軟な超分子ネットワークの構築と動的変換2016

    • Author(s)
      宮野 哲也・岡田 直樹・久木 一朗・藤内 謙光
    • Organizer
      第25回有機結晶シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2016-09-18
    • Related Report
      2016 Research-status Report
  • [Presentation] ジビニルスルホン酸誘導体を用いた3次元籠目型多孔質有機塩の構築とその動的挙動2016

    • Author(s)
      岡田直樹・宮野哲也・久木一朗・藤内謙光
    • Organizer
      第25回有機結晶シンポジウム
    • Place of Presentation
      京都
    • Year and Date
      2016-09-18
    • Related Report
      2016 Research-status Report
  • [Presentation] Design of Porous Organic Salts (POS) with Versatile Function2016

    • Author(s)
      Norimitsu Tohnai
    • Organizer
      12th International Workshop of the Crystal Growth of Organic Material
    • Place of Presentation
      LEEDS, UK
    • Year and Date
      2016-06-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited

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Published: 2016-04-21   Modified: 2022-02-22  

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