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Photochemical Preparation of n-type Carbon nanotubes with Aromatic Amines and Derivatives

Research Project

Project/Area Number 16K13981
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Research InstitutionNara Institute of Science and Technology

Principal Investigator

KAWAI Tsuyoshi  奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (40221197)

Co-Investigator(Kenkyū-buntansha) 宇田 亮子  奈良工業高等専門学校, 物質化学工学科, 准教授 (90321463)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsカーボンナノチューブ / 芳香族アミン / 化学吸着 / n型 / n型 / ドーピング / マラカイトグリーン / トリアリールアミン / 熱電変換 / 光還元
Outline of Final Research Achievements

In recent years, thermoelectric conversion of heat in the environment is considered promising for generating electric power. In this purpose, carbon nanotube CNT is extensively studied because of their lightweight and highly flexibility. In this research, we tried to generate n-type CNT which is necessary for high-efficiency power generation by photo-chemical methods. Stable n - type thermoelectric power generation characteristics were observed in the CNT composite membrane prepared by immersing CNT film in aqueous solution of aromatic amines. We also used a hydride-type amine as a reducing agent, it was possible to obtain an effective n - type CNT.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (2 results)

All 2017

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results)

  • [Journal Article] Solvent Basicity Promotes the Hydride-mediated Electron Transfer Doping of Carbon Nanotubes2017

    • Author(s)
      Y. Nonoguchi, S. Sudo, A. Tani, T. Murayama, Y. Nishiyama, R. M. Uda, T. Kawai
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 74 Pages: 10259-10262

    • DOI

      10.1039/c7cc04295g

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water-Processable, Air-Stable Organic Nanoparticle-Carbon Nanotube Nonocomposites Exhibiting n-Type Thermoelectric Properties2017

    • Author(s)
      Y. Nonoguchi, A. Tani, T. Ikeda, C. Goto, N. Tanifuji, R.M. Uda, T. Kawai
    • Journal Title

      SMALL

      Volume: 13 Issue: 11 Pages: 1850-1857

    • DOI

      10.1002/smll.201603420

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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