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Development of advanced resource utilization process of carbon dioxide by NH3 decomposition + non-equilibrium structured catalyst system

Research Project

Project/Area Number 16K14045
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Green/Environmental chemistry
Research InstitutionShizuoka University

Principal Investigator

Fukuhara Choji  静岡大学, 工学部, 教授 (30199260)

Co-Investigator(Kenkyū-buntansha) 渡部 綾  静岡大学, 工学部, 准教授 (80548884)
Project Period (FY) 2016-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2018: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords構造体触媒 / 膜分離 / アンモニア分解 / メタン化反応 / 水素 / 反応システム / 触媒・化学プロセス / 温室効果ガス削減 / 再生可能エネルギー
Outline of Final Research Achievements

The purpose of this research is to construct a new chemical reaction field, using a structured catalyst system, combining CO2 methanation with NH3 decomposition, and connecting CH4 dry reforming. This research is intended to make effective utilization of CO2 emitted from industrial processes. In CO2 methanation with a large heat generation, the developed Ni/CeO2 structure catalyst showed high functionality of thermal energy controlling, and methane converting characteristics was high. The K-Ru/CeO2 catalyst showed high performance in the ammonia decomposition that requires a large supply of thermal energy. The Ni/Al2O3 catalyst prepared on a stainless steel fin by the electroless plating was found to exhibit high tolerance to carbon deposition in CH4 dry reforming.

Academic Significance and Societal Importance of the Research Achievements

再生可能エネルギー由来のグリーンアンモニアの分解反応で製造されるH2を用い、産業プロセスから排出されるCO2の処理とその活用を図ることが本研究の目的である。本研究の推進で得られた知見から、熱エネルギーの制御管理が重要となるCO2のメタン化反応とアンモニアの分解反応に対して、それぞれすぐれた触媒特性を示す構造体触媒が創製できた。CO2処理の新しい展開性を開く成果であり、産業プロセスの発展に貢献することが考えられる。また、ドライ改質反応における析出炭素の抑制方法に関した有意義な指針も得られた。

Report

(4 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Research-status Report
  • 2016 Research-status Report
  • Research Products

    (29 results)

All 2019 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (11 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 11 results,  Acknowledgement Compliant: 2 results) Presentation (16 results) (of which Int'l Joint Research: 10 results,  Invited: 3 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Chulalongkorn University/Mahidol University(Thailand)

    • Related Report
      2017 Research-status Report
  • [Journal Article] Auto-methanation of Carbon Dioxide: A Novel Route for Transforming CO2 over Ni-based Catalyst2019

    • Author(s)
      Fukuhara Choji、Ratchahat Sakhon、Suzuki Yuji、Sudoh Masao、Watanabe Ryo
    • Journal Title

      Chemistry Letters

      Volume: 48 Issue: 3 Pages: 196-199

    • DOI

      10.1246/cl.180894

    • NAID

      130007607581

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 物質・熱移動の促進による触媒反応場のプロセス強化(PI)2019

    • Author(s)
      福原長寿
    • Journal Title

      触媒

      Volume: 61 Pages: 9-15

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of a powerful CO2 methanation process using a structured Ni/CeO2 catalyst2018

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, W.Kawasaki, R.Watanabe, C.Fukuhara
    • Journal Title

      Journal of CO2 Utilization

      Volume: 24 Pages: 210-219

    • DOI

      10.1016/j.jcou.2018.01.004

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] An easy and effective method for the intercalation of hydrophobic natural dye into organo-montmorillonite for improved photostabilitycarbon capture2018

    • Author(s)
      Y.Kohno, T.Taguchi, M.Shibata, Y.Tomita, C.Fukuhara, Y.Maeda
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 116C Pages: 168-173

    • DOI

      10.1016/j.jpcs.2018.01.027

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Active Species of Sulfated Metal Oxide Catalyst for Propane Dehydrogenation2017

    • Author(s)
      R.Watanabe, N.Hirata, C.Fukuhara
    • Journal Title

      Journal of the Japan Petroleum Institute

      Volume: 60 Issue: 5 Pages: 223-231

    • DOI

      10.1627/jpi.60.223

    • NAID

      130006039454

    • ISSN
      1346-8804, 1349-273X
    • Year and Date
      2017-09-01
    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of a novel synthesis-gas production system combining with carbon capture2017

    • Author(s)
      W.Kawasaki, K.Hidenori, S. Ratchahat, R.Watanabe, C.Fukuhara
    • Journal Title

      Journal of CO2 Utilization

      Volume: 22 Pages: 91-96

    • DOI

      10.1016/j.jcou.2017.08.021

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] 水素の製造と利用のための構造体触媒反応システム2017

    • Author(s)
      福原長寿
    • Journal Title

      水素エネルギーシステム

      Volume: 42(2) Pages: 76-82

    • Related Report
      2017 Research-status Report
    • Peer Reviewed
  • [Journal Article] A novel nickel-based structured catalyst for CO2 methanation: a honeycomb-type Ni/CeO2 catalyst to transform greenhouse gas into useful resources2017

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Kotaro Hayakawa, Yuji Suzuki, Wataru Kawasaki
    • Journal Title

      Applied Catalysis A: General

      Volume: 532 Pages: 12-18

    • DOI

      10.1016/j.apcata.2016.11.036

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of a noble-structured catalyst for methane decomposition to produce pure hydrogen2017

    • Author(s)
      Wataru Kawasaki, Hidenori Kato, Ryo Watanabe, Choji Fukuhara
    • Journal Title

      Chemistry Letters

      Volume: 46 Pages: 211-214

    • NAID

      130005317094

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of promoter addition on water gas shift property over structured-type iron oxide catalyst2016

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Nozomu Hirata, Choji Fukuhara
    • Journal Title

      Catalysis Letters

      Volume: 146(12) Issue: 12 Pages: 2478-2484

    • DOI

      10.1007/s10562-016-1872-9

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Performance of non-stoichiometric perovskite catalyst AxCrO3-δ, A: La, Pr, N ) for dehydrogenation of propane under steam condition2016

    • Author(s)
      Ryo Watanabe, Masahiro Tsujioka, Choji Fukuhara
    • Journal Title

      Catalysis Letters

      Volume: 146(12) Issue: 12 Pages: 2458-2467

    • DOI

      10.1007/s10562-016-1876-5

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Estimation of heat and mass transfer of structured catalyst system for CO2 methanation2018

    • Author(s)
      Choji Fukuhara, Yuji Suzuki, Ryo Watanabe, Masao Sudoh, Sakhon Ratchahat
    • Organizer
      The 25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
  • [Presentation] Advantage of structured catalyst system for CO2 methanation under extremely high flow rate2018

    • Author(s)
      Sakhon Ratchahat, Masao Sudoh, Yuji Suzuki, Ryo Watanabe, Choji Fukuhara
    • Organizer
      The 25th International Symposium on Chemical Reaction Engineering
    • Related Report
      2018 Annual Research Report
  • [Presentation] A structured nickel-based catalyst with high performance and tolerance to coke deposition in naphthalene steam reforming for biomass-gasification process2018

    • Author(s)
      Choji Fukuhara, Ryo Watanabe, Kota Matsuzawa, Mio Yokoe, Kenji Asaoka, Hidekiyo Suyama, Shuichiro Suzuki
    • Organizer
      The 8th Tokyo Conference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
  • [Presentation] Alkali promotion of iron oxide based catalyst for water gas shift reaction2018

    • Author(s)
      Ryo Watanabe, Kengo Tajima, Yuya Fushimi, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 8th Tokyo COnference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
  • [Presentation] Development of honeycomb-type Ru-based catalyst for NH3 decomposition, with mass processing ability of raw materials2018

    • Author(s)
      Masaki Kawase, Kimihito Suzuki, Ryo Watanabe, Choji Fukuhara
    • Organizer
      The 8th Tokyo COnference on Advanced Catalytic Science and Technology
    • Related Report
      2018 Annual Research Report
  • [Presentation] Advanced catalytic reforming system contributing to hydrogen production2018

    • Author(s)
      Choji Fukuhara
    • Organizer
      SCEJ 83nd Annual Meeting, International Symposium(K-4)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] (Requested talk) Novel catalytic property of structured catalyst prepared by wet-type chemical deposition2017

    • Author(s)
      Choji Fukuhara
    • Organizer
      The SCEJ 82nd Annual Meeting
    • Place of Presentation
      Shibaura Institute of Technology, Toyosu, Tokyo, Japan
    • Year and Date
      2017-03-06
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Investigation of CO2 methanation performance over a structured catalyst system under fluctuating reaction condition2017

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, R.Watanabe, C.Fukuhara
    • Organizer
      The 47th Petrolium-Petrochemistry Symposium of JPI
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Innovative chemical reaction system contributing to issue of energy and environment2017

    • Author(s)
      Choji Fukuhara
    • Organizer
      The 8th Asian-Pacific Chemical Reaction Engineering Symposium (APCRE2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of honeycomb-type CO2 methanation reactor with advantage of hest and mass transfers2017

    • Author(s)
      S.Ratchahat, M.Sudoh, Y.Suzuki, R.Watanabe, C.Fukuhara
    • Organizer
      The 8th Asian-Pacific Chemical Reaction Engineering Symposium (APCRE2017)
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Auto-thermal reforming property of Ni-based structured catalyst for dry reforming of methane2017

    • Author(s)
      K.Hirao, W.Kawasaki, Y.Kohno, R.Watanabe, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Sulfation treatment to transition metal oxide on propane dehydrogenation property2017

    • Author(s)
      N.Hirata, R.Watanabe, A.Maezawa, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Effect of alkali metal addition to iron oxide structured catalyst for water gas shift property2017

    • Author(s)
      R.Watanabe, K.Tajima, N.Hirata, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] IR observation in methylcyclohexane dehydrogenation over Pt/TiO2 and Pt/Al2O3 catalysts2017

    • Author(s)
      K.Watanabe, Y.Bandai, R.Watanabe, Y.Kohno, C.Fukuhara
    • Organizer
      16th Korea-Japan Symposium on Catalysis & 3rd International Symposium of Institute for Catalysis
    • Related Report
      2017 Research-status Report
    • Int'l Joint Research
  • [Presentation] Promotion effect of heat and mass transfer characteristics on CO2 methanation over the structured Ni/CeO2 catalyst2016

    • Author(s)
      Sakhon Ratchahat, Yuji Suzuki, Kotaro Hayakawa, Ryo Watanabe, Yoshiumi Khono, Choji Fukuhara
    • Organizer
      The 46th Petrol.-Petrochem. Symp. of JPI
    • Place of Presentation
      Kyoto Research Park, Kyoto, Kyoto, Japan
    • Year and Date
      2016-11-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Effect of promoter addition on water gas shift property of iron-oxide type structured catalyst2016

    • Author(s)
      Ryo Watanabe, Shuhei Watanabe, Nozomu Hirata, Choji Fukuhara
    • Organizer
      The 9th International Conference on Environmental Catalysis
    • Place of Presentation
      Newcastle City, Australia
    • Year and Date
      2016-07-10
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Patent(Industrial Property Rights)] メタンを製造する方法、及び製造システム2018

    • Inventor(s)
      福原長寿
    • Industrial Property Rights Holder
      福原長寿
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-159398
    • Filing Date
      2018
    • Related Report
      2018 Annual Research Report

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Published: 2016-04-21   Modified: 2020-03-30  

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