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Development of water splitting device with thermal-photo-hybridized activity via solar demonstration

Research Project

Project/Area Number 16K14056
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Research InstitutionNiigata University

Principal Investigator

Kodama Tatsuya  新潟大学, 自然科学系, 教授 (60272811)

Research Collaborator Kang Yong-Heack  韓国エネルギー技術研究院(KIRE), 太陽熱研究センター, センター長
Kim Jong-Kyu  韓国エネルギー技術研究院(KIRE), 太陽熱研究センター, 主任研究員
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords水素製造 / 水分解 / 太陽熱 / エネルギー転換 / 熱化学サイクル / セラミック / 光触媒 / 反応器 / 反応性セラミック / 再生可能エネルギー / 水素 / 太陽集光 / 集光太陽熱 / 触媒・化学プロセス / 新エネルギー
Outline of Final Research Achievements

This project aims at the development of water splitting device with a “thermal-photo-hybridized” activity via solar demonstration, in order to reduce the reaction temperature of solar two-step water splitting cycle with a redox metal oxide. It is well known that cerium oxide (ceria) has a high thermal activity as a working reactive ceramic (redox metal oxide) for solar “thermochemical” two-step water splitting cycle. In this project, iron oxide, which has “photochemical activity”, was doped into ceria, and then, small ceramic foams were coated with the iron-doped ceria powder. The prepared reactive foam devices were tested on activity for the two-step water splitting cycle under irradiation of artificial solar fluxes from a sun-simulator. Under the experiments, the new devices were found to split water at temperatures below 1300C while the conventional device without doping of iron-oxide needs temperatures above 1500C.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (4 results)

All 2017 2016

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Development and experimental study for hydrogen production from the thermochemical two-step water splitting cycles with a CeO2 coated new foam device design using solar furnace system2017

    • Author(s)
      Cho Hyun seok、Kodama Tatsuya、Gokon Nobuyuki、Kim Jong kyu、Lee Sang nam、Kang Yong heack
    • Journal Title

      AIP Conference Proceedings

      Volume: 1850 Pages: 100003-100003

    • DOI

      10.1063/1.4984460

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Hydrogen Productivity and Repeatability for Thermochemical Two-step Water-splitting Cycle Using Mn-doped Cerium Oxides2017

    • Author(s)
      K. Naito, N. Gokon, H. S. Cho, S. Bellan, T. Hatamachi, T. Kodama
    • Organizer
      1st Asian Conference on Thermal Science 2017
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2017-03-26
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 高温太陽炉によるCeO2/MPSZ反応デバイスの二段階水熱分解サイクル2017

    • Author(s)
      鶴間一成、山田愛美、Hyun-Seok Cho、郷右近展之、児玉竜也
    • Organizer
      平成29年度日本太陽エネルギー学会研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 金属ドープセリアの二段階水熱分解サイクルの高活性化に関する研究2016

    • Author(s)
      内藤喜子,旗町剛,郷右近展之,児玉竜也
    • Organizer
      第25回日本エネルギー学会大会
    • Place of Presentation
      東京
    • Year and Date
      2016-08-09
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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