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Creation of 3D Optical Metamaterials by Using Biomimetic Block Copolymers

Research Project

Project/Area Number 16K14071
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionTohoku University

Principal Investigator

Yabu Hiroshi  東北大学, 材料科学高等研究所, 准教授 (40396255)

Co-Investigator(Kenkyū-buntansha) 松尾 保孝  北海道大学, 電子科学研究所, 准教授 (90374652)
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords自己組織化 / ブロック共重合体 / メタマテリアル / ナノ粒子 / 磁気光学効果 / バイオミメティック / プラズモン / バイオミメティクス / 銀ナノ粒子 / カテコール
Outline of Final Research Achievements

Diblock and triblock copolymers containing polyvinyl catechol (PVCa) moieties were successfully synthesized by using reversible-addition fragmentation transfer (RAFT) polymerization process. Iron oxide nanoparticles and silver nanoparticles were co-assembled in the PVCa phases by using adhesion and reduction properties of catechol moieties, and the composite films show unique magneto-optical effect in the wavelength of the plasmonic absorption band of silver nanoparticles. From these results, we have succeeded in the development of a new fabrication process of metamaterials by using biomimetic block copolymers.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (9 results)

All 2018 2017 2016 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 3 results) Presentation (1 results)

  • [Int'l Joint Research] Royal Collage of Art, London(United Kingdom)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] KIT(Germany)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Core-Shell Cylinder (CSC) Nanotemplates Comprised of Mussel-Inspired Catechol-Containing Triblock Copolymers for Silver Nanoparticle Arrays and Ion Conductive Channels2018

    • Author(s)
      H. Yabu, S. Nagano, Y. Nagao
    • Journal Title

      RSC Advances

      Volume: 8 Issue: 19 Pages: 10627-10632

    • DOI

      10.1039/c8ra00630j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reversible Shape Transformation of Ultrathin Polydopamine-Stabilized Droplet2017

    • Author(s)
      Abe Hiroya、Matsue Tomokazu、Yabu Hiroshi
    • Journal Title

      Langmuir

      Volume: 33 Issue: 25 Pages: 6404-6409

    • DOI

      10.1021/acs.langmuir.7b01355

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of unusual microphase-separated ultrathin films of poly(vinyl catechol-block-styrene) (PVCa-b-PSt) at the air-water interface by solution casting onto water2017

    • Author(s)
      Hiroshi Yabu, Shusaku Nagano
    • Journal Title

      RSC Advances

      Volume: 7 Issue: 53 Pages: 33086-33090

    • DOI

      10.1039/c7ra06574d

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Biomimetic Bubble Repellent Tubes; Micro Dimple Arrays Enhance Repellency of Bubbles Inside of Tubes2017

    • Author(s)
      J. Kamei, H. Abe, H. Yabu
    • Journal Title

      Langmuir

      Volume: 33 Issue: 2 Pages: 585-590

    • DOI

      10.1021/acs.langmuir.6b04155

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Preparation of Poly(Vinyl Catechol-block-Styrene) (PVCa-b-PSt) Stabilized Iron Oxide Nanoparticles by Ligand Exchange and Janus Particle Formation2017

    • Author(s)
      H. Yabu, R. Koike, Y. Hirai
    • Journal Title

      Journal of Nanoscience and Nanotechnology

      Volume: 印刷中 Issue: 12 Pages: 9251-9256

    • DOI

      10.1166/jnn.2017.14363

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Proton Conductivities of Lamellae-forming Bio-inspired Block Copolymer Thin Films Containing Silver Nanoparticles2016

    • Author(s)
      H. Yabu, J. Matsui, M. Hara, S. Nagano, Y. Matsuo, Y. Nagao
    • Journal Title

      Langmuir

      Volume: 32 Issue: 37 Pages: 9484-9491

    • DOI

      10.1021/acs.langmuir.6b02521

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ナノミセル中におけるフタロシアニン類縁体ナノ結晶の UV 光合成2016

    • Author(s)
      平井裕太郎、澤野文司、高木斗志彦、藪浩
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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