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Holmium composite polymer brush: Development of colorless magnetic material

Research Project

Project/Area Number 16K14072
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionChiba University

Principal Investigator

Kohri Michinari  千葉大学, 大学院工学研究院, 准教授 (80512376)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsホルミウム / 磁性材料 / 磁性粒子 / ランタノイド / 高分子ブラシ / 磁性 / 無着色 / ポリマーネットワーク / リビング重合 / 表面改質
Outline of Final Research Achievements

Here, we demonstrated the preparation of polymeric magnetic materials based on a three-dimensional (3D) polymer network via holmium atoms, one of the lanthanide elements. By creating the 3D polymer network composed with polyacrylic acid (PAA) and holmium atoms showing trivalent nature, we succeeded in the creation of a new category of the magnetic polymer in which the polymer itself responds to a magnet. In addition, polymeric scaffolds such as polymer-grafted particles made it possible to produce non-colored magnetic composite materials that respond quickly to the magnet. This simple and novel process of using a 3D polymer network via holmium atoms can be used in basic research on magnetic materials and hold a great potential for technological applications, ranging from optical to colored devices.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (21 results)

All 2018 2017 2016 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 4 results) Presentation (8 results) Book (1 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] In-situ assembly of diblock copolymers onto submicron-sized particles for preparation of core-shell and ellipsoidal particles2017

    • Author(s)
      K. Hamada, M. Kohri, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Colloids Surf. A: Physicochem. Eng. Aspects

      Volume: 512 Pages: 80-86

    • DOI

      10.1016/j.colsurfa.2016.10.035

    • Related Report
      2017 Annual Research Report 2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Bright structural color films independent of background prepared by the dip-coating of biomimetic melanin-like particles having polydopamine shell layers2017

    • Author(s)
      M. Kohri, S. Yamazaki, A. Kawamura, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Colloids Surf. A: Physicochem. Eng. Aspects

      Volume: - Pages: 564-569

    • DOI

      10.1016/j.colsurfa.2017.03.035

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Structural color tuning: Mixing melanin-like particles with different diameters to create neutral colors2017

    • Author(s)
      A. Kawamura, M. Kohri, S. Yoshioka, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Langmuir

      Volume: 33 Issue: 15 Pages: 3824-3830

    • DOI

      10.1021/acs.langmuir.7b00707

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A metal-lustrous porphyrin foil2017

    • Author(s)
      Morisue Mitsuhiko、Hoshino Yuki、Shimizu Masaki、Tomita Shogo、Sasaki Sono、Sakurai Shinichi、Hikima Takaaki、Kawamura Ayaka、Kohri Michinari、Matsui Jun、Yamao Takeshi
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 77 Pages: 10703-10706

    • DOI

      10.1039/c7cc06159e

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Color Materials from Polydopamine-Inorganic Hybrid Thin Films Inspired by Rock Pigeon Feathers2017

    • Author(s)
      河村彩香,桑折道済,奥博行,濵田紘佑,中川恵介,谷口竜王,岸川圭希
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 74 Issue: 1 Pages: 54-58

    • DOI

      10.1295/koron.2016-0044

    • NAID

      130005296434

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Why chiral tartaric imide derivatives give large helical twisting powers in nematic liquid crystal phases: substituent-effect approach to investigate intermolecular interactions between dopant and liquid crystalline molecules2017

    • Author(s)
      K. Kishikawa, Y. Furukawa, T. Watanabe, M. Kohri, T. Taniguchi, and S. Kohmoto
    • Journal Title

      Liq. Cryst.

      Volume: - Issue: 6 Pages: 956-968

    • DOI

      10.1080/02678292.2016.1255361

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen bond network-stabilization of blue phases by addition of a chiral N-(10-hydroxydecyl)succinimide derivative and alkane diols2017

    • Author(s)
      K. Kishikawa, Y. Furukawa, T. Watanabe, M. Kohri, T. Taniguchi, and S. Kohmoto
    • Journal Title

      Liq. Cryst.

      Volume: - Issue: 8 Pages: 1332-1339

    • DOI

      10.1080/02678292.2017.1295477

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shape-assisted self-organization in highly disordered liquid crystal phases2017

    • Author(s)
      K. Kishikawa, Y. Yamamoto, G. Watanabe, A. Kawamura, M. Kohri, T. Taniguchi
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 56 Issue: 16 Pages: 4598-4602

    • DOI

      10.1002/anie.201700809

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface Modification of Polydopamine Particles <i>via</i> Magnetically-Responsive Surfactants2016

    • Author(s)
      A. Kawamura, M. Kohri, T. Taniguchi, and K. Kishikawa
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 41 Issue: 3 Pages: 301-304

    • DOI

      10.14723/tmrsj.41.301

    • NAID

      130005263764

    • ISSN
      1382-3469, 2188-1650
    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 磁性ポリマーブラシ被覆による材料表面改質2017

    • Author(s)
      桑折道済・柳本賢士・小白琴菜・谷口竜王・岸川圭希
    • Organizer
      第27回日本MRS年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁場応答性ポリマーブラシによる基板表面の改質2017

    • Author(s)
      柳本賢士・桑折道済・谷口竜王・岸川圭希・塩本昌平・小林元康
    • Organizer
      平成29年度 繊維学会秋季研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁場応答性ポリマーブラシを付与した微粒子の作製と評価2017

    • Author(s)
      小白琴菜・柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      平成29年度 繊維学会秋季研究発表会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁場応答性ポリマーを用いた材料表面改質2017

    • Author(s)
      柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] RAFT重合を用いたβ-ジケトン骨格を有するポリマーの作製と機能化2017

    • Author(s)
      小白琴菜・柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第7回CSJ化学フェスタ2017
    • Related Report
      2017 Annual Research Report
  • [Presentation] 磁場応答性ポリマーブラシによる材料表面改質2017

    • Author(s)
      柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 新規磁場応答性ポリマーブラシによる材料表面改質2017

    • Author(s)
      柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第34回高分子学会千葉地域活動若手セミナー
    • Place of Presentation
      東京理科大学葛飾キャンパス
    • Related Report
      2016 Research-status Report
  • [Presentation] 磁性ポリマーブラシによる材料表面改質2016

    • Author(s)
      柳本賢士・桑折道済・谷口竜王・岸川圭希
    • Organizer
      第26回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館
    • Year and Date
      2016-12-19
    • Related Report
      2016 Research-status Report
  • [Book] 高分子微粒子ハンドブック2017

    • Author(s)
      藤本啓二
    • Total Pages
      316
    • Publisher
      シーエムシー出版
    • ISBN
      9784781312538
    • Related Report
      2017 Annual Research Report
  • [Remarks] 千葉大学ソフト材料化学研究室HP

    • URL

      http://chem.tf.chiba-u.jp/gacb03/saito/toppu.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 生体模倣高分子研究室HP

    • URL

      http://chem.tf.chiba-u.jp/gacb03/saito/toppu.html

    • Related Report
      2016 Research-status Report
  • [Patent(Industrial Property Rights)] 磁性材料及び磁性材料の製造方法2018

    • Inventor(s)
      桑折道済・小白琴菜
    • Industrial Property Rights Holder
      桑折道済・小白琴菜
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2018-045410
    • Filing Date
      2018
    • Related Report
      2017 Annual Research Report

URL: 

Published: 2016-04-21   Modified: 2019-03-29  

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