Preparation and Application of 3D-3D Porous Composite Materials

• Project/Area Number: 16K14081
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Polymer/Textile materials
• Research Institution: Osaka University
• Principal Investigator: UYAMA Hiroshi 大阪大学, 大学院工学研究科, 教授 (70203594)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000); Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: クチクラ / クチン / バイオミミクリー / ダイマー酸 / バクテリアセルロース / バイオベースポリマー / モノリス / エチレン-ビニルアルコール共重合体 / 酢酸セルロース / 複合材料 / ポリアクリロニトリル / 電気二重層キャパシタ / セルロースナノファイバー / 炭素材料

Outline of Final Research Achievements

Plant cuticle is an ideal bio-based packaging material with well-balanced performance. This study deals with new biomimic design of artificial cutin and cuticle. A network polymer consisting of soft segment derived from plant oils such as dimer acid and ricinoleic acid was synthesized as artificial cutin. Cellulose sheet from reactive bacterial cellulose and amorphous cellulose was used for lamination with artificial cutin to produce artificial cuticle.

Research Products

• [Int'l Joint Research] 西北大学(中国)
• [Journal Article] Unique Transitions in Morphology and Characteristics of Porous Poly(Lactic Acid) Enantiomers (2018)
  • Author(s): Kanno Tomonari、Uyama Hiroshi
  • Journal Title: Macromol. Chem. Phys. Volume: 0 Issue: 7 Pages: 1700547-1700547
  • DOI: 10.1002/macp.201700547
  • Peer Reviewed / Open Access
• [Journal Article] Unique Ivy-Like Morphology Composed of Poly(lactic acid) and Bacterial Cellulose Cryogel (2018)
  • Author(s): Kanno Tomonari、Uyama Hiroshi
  • Journal Title: ACS Omega Volume: 3 Issue: 1 Pages: 631-635
  • DOI: 10.1021/acsomega.7b01968
  • Peer Reviewed / Open Access
• [Journal Article] Hierarchical Porous Carbons from Poly(methyl methacrylate)/Bacterial Cellulose Composite Monolith for High-Performance Supercapacitor Electrodes (2017)
  • Author(s): Bai Qiuhong、Xiong Qiancheng、Li Cong、Shen Yehua、Uyama Hiroshi
  • Journal Title: ACS Sus. Chem. Eng. Volume: 5 Issue: 10 Pages: 9390-9401
  • DOI: 10.1021/acssuschemeng.7b02488
  • Peer Reviewed
• [Journal Article] Hierarchical porous cellulose/activated carbon composite monolith for efficient adsorption of dyes (2017)
  • Author(s): Bai Qiuhong、Xiong Qiancheng、Li Cong、Shen Yehua、Uyama Hiroshi
  • Journal Title: Cellulose Volume: 24 Issue: 10 Pages: 4275-4289
  • DOI: 10.1007/s10570-017-1410-y
  • Peer Reviewed
• [Journal Article] Nitrogen-doped biomass/polymer composite porous carbons for high performance supercapacitor (2017)
  • Author(s): Shu Yu、Maruyama Jun、Iwasaki Satoshi、Maruyama Shohei、Shen Yehua、Uyama Hiroshi
  • Journal Title: J. Power Sources Volume: 364 Pages: 374-382
  • DOI: 10.1016/j.jpowsour.2017.08.059
  • Peer Reviewed
• [Journal Article] Activated Carbon Monolith Derived from <i>Amygdalus Pedunculata</i> Shell and Polyacrylonitrile for Supercapacitors (2017)
  • Author(s): Shu Yu、Maruyama Jun、Iwasaki Satoshi、Shen Yehua、Uyama Hiroshi
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 90 Issue: 12 Pages: 1333-1336
  • DOI: 10.1246/bcsj.20170211
  • NAID: 130006250389
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed
• [Journal Article] Fabrication of N-doped and shape-controlled porous monolithic carbons from polyacrylonitrile for supercapacitors (2017)
  • Author(s): Shu Yu、Maruyama Jun、Iwasaki Satoshi、Maruyama Shohei、Shen Yehua、Uyama Hiroshi
  • Journal Title: RSC Adv. Volume: 7 Issue: 68 Pages: 43172-43180
  • DOI: 10.1039/c7ra07003a
  • Peer Reviewed / Open Access
• [Presentation] Functional Nanocomposites Based on Bacterial Cellulose (2018)
  • Author(s): H. Uyama
  • Organizer: The 2nd International Symposium on Green Technology for Value Chains
• [Presentation] セルロースモノリスの開発と前処理カラムへの応用 (2018)
  • Author(s): 宇山 浩
  • Organizer: 質量分析オープンイノベーション協働ユニットキックオフシンポジウム
  • Invited
• [Presentation] Functional Nanocomposites Based on Bacterial Cellulose (2017)
  • Author(s): H. Uyama
  • Organizer: 6th International Conference on Bio-based Polymers
  • Int'l Joint Research
• [Presentation] Functional Nanocomposites Based on Bacterial Cellulose (2017)
  • Author(s): H. Uyama
  • Organizer: 25th Polychar 2017
  • Invited
• [Presentation] Functional Nanocomposites Based on Bacterial Cellulose (2017)
  • Author(s): H. Uyama
  • Organizer: IUPAC 13th International Conference on Novel Materials and Their Synthesis
• [Presentation] Fabrication of Functional Porous Materials by Phase Separation (2017)
  • Author(s): H. Uyama
  • Organizer: Pure and Applied Chemistry International Conference 2017 (PACCON 2017)
  • Place of Presentation: Centra Government Complex Hotel & Convention Centre（バンコク、タイ）
  • Int'l Joint Research / Invited
• [Presentation] Fabrication of Mesoporous Polymer Monoliths by Phase Separation (2016)
  • Author(s): H. Uyama
  • Organizer: EMN Meeting on Mesoporous Materials
  • Place of Presentation: Grandior Prague Hotel（プラハ、チェコ）
  • Int'l Joint Research / Invited
• [Presentation] Functional Nanocomposites Based on Bacterial Cellulose (2016)
  • Author(s): H. Uyama
  • Organizer: Advances in Sustainable Polymers Kyoto Institute of Technology
  • Place of Presentation: 京都工芸繊維大学（京都市）
  • Int'l Joint Research / Invited
• [Presentation] バクテリアセルロースを基盤とする機能材料の開発 (2016)
  • Author(s): 宇山 浩
  • Organizer: 16-2 エコマテリアル研究会
  • Place of Presentation: 京都工芸繊維大学（京都市）
  • Invited
• [Presentation] Fabrication of Functional Porous Polymeric Nanomaterials by Phase Separation (2016)
  • Author(s): H. Uyama
  • Organizer: Science & Technology-2016
  • Place of Presentation: Holiday Inn Singapore Atrium（シンガポール)
  • Int'l Joint Research / Invited