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Effect of Polymer-wrapping on Carbon Nanotubes for Li-O2 Rechargeable Battery

Research Project

Project/Area Number 16K14084
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionKyushu University

Principal Investigator

Fujigaya Tsuyohiko  九州大学, 工学研究院, 准教授 (30444863)

Co-Investigator(Renkei-kenkyūsha) ISHIHARA Tatsumi  九州大学, 大学院工学系研究院, 教授 (80184555)
Research Collaborator KANAMORI Ryota  
MATSUMOTO Masamichi  
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords金属空気電池 / カーボンナノチューブ / ポリベンズイミダゾール / ポリイミド / レドックス / リチウム電池 / 低消費電力・高エネルギー密度 / ナノチューブ / 高分子合成 / ナノチューブ・フラーレン
Outline of Final Research Achievements

In the development of lithium (Li)-oxygen (O2) rechargeable battery, improvement of the rechargeability is one of the key issues to be solved. Here, a novel strategy to solve these issues is explored, in which polymer-wrapped single-walled carbon nanotubes (SWNTs) are used for a cathode material. Poly[2,2’-(2,6-pyridine)-5,5’-bibenzimidazole] (PyPBI) employed as the wrapping polymer of SWNTs serves to coordinate Li ion to facilitate the favorable deposition of the discharge products on SWNTs during discharge reaction in the cell cathode. As a result, rechargeability of the cell (SWNT/PyPBI-cell) is improved compared to the cell having non-wrapped SWNTs as the cathode (SWNT-cell).

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (8 results)

All 2018 2017 2016

All Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Presentation] カーボンナノチューブ電極の空隙サイズ制御によるリチウム空気電池の充放電容量の向上2018

    • Author(s)
      松本 昌修, 江口 雅人, 石原 達己, 藤ヶ谷 剛彦
    • Organizer
      日本化学会第98春季年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カーボンナノチューブ電極の低密度化によるリチウム空気電池の充放電容量の向上2017

    • Author(s)
      松本昌修、藤ヶ谷剛彦、中嶋直敏
    • Organizer
      第54回化学関連支部合同大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] カーボンナノチューブ電極の3D化によるリチウム空気電池の充放電容量の向上2017

    • Author(s)
      松本昌修、藤ヶ谷剛彦、中嶋直敏
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Non-covalent Functionalization of Carbon Nanotubes by Functional Polymers for Energy and Biotechnology Applications2017

    • Author(s)
      藤ヶ谷 剛彦
    • Organizer
      FNTG
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多孔質カーボンナノチューブ電極によるリチウム空気電池の充放電容量の向上2017

    • Author(s)
      松本昌修、江口雅人、石原達己、藤ヶ谷剛彦
    • Organizer
      九州地区高分子若手研究会・冬の講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Development of Lithium Air Battery Cathode using Carbon Nanotube wrapped by Polyimide2016

    • Author(s)
      Ryota Kanamori, Tsuyohiko Fujigaya, Il-Chang Jang, Tatsumi Ishihara, Naotoshi Nakashima
    • Organizer
      The 11th SPSJ International Polymer Conference
    • Place of Presentation
      福岡国際センター
    • Year and Date
      2016-12-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] ポリイミド被覆カーボンナノチューブをカソード極とするリチウム空気電池の作製と評価2016

    • Author(s)
      金森亮太、藤ヶ谷剛彦、Il-Chang Jang、石原達己、中嶋直敏
    • Organizer
      第65回 高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-14
    • Related Report
      2016 Research-status Report
  • [Presentation] リチウム空気電池のカソード極としてのポリイミド被覆カーボンナノチューブの利用2016

    • Author(s)
      金森亮太、藤ヶ谷剛彦、張 一讃、石原達己、中嶋直敏
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2016-07-02
    • Related Report
      2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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