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Development of new high-performance thermoelectric conversion materials using dislocations in topological insulators

Research Project

Project/Area Number 16K14371
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Physical properties of metals/Metal-base materials
Research InstitutionThe University of Tokyo

Principal Investigator

Edagawa Keiichi  東京大学, 生産技術研究所, 教授 (20223654)

Co-Investigator(Renkei-kenkyūsha) Tokumoto Yuki  東京大学, 生産技術研究所, 講師 (20546866)
Kamimura Yasushi  東京大学, 生産技術研究所, 助教 (40291314)
Research Collaborator Hamasaki Hiromu  東京大学, 大学院工学系研究科, 大学院生
Hattori Yuya  東京大学, 大学院工学系研究科, 大学院生
Kamiyama Ryosuke  東京大学, 大学院工学系研究科, 大学院生
Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsトポロジカル絶縁体 / 転位 / 熱電変換材料 / 狭ギャップ半導体
Outline of Final Research Achievements

We experimentally investigated the theoretically predicted dislocation conduction in Bi-Sb topological insulator (TI). We grew single crystals of Bi-Sb by unidirectional solidification under a controlled temperature gradient. Then, we plastically deformed the crystals to introduce dislocations. High-density dislocations with the Burgers vector satisfying the conductivity condition were introduced, which were dominantly of the edge type. We performed conductivity measurements for undeformed and deformed samples. The results for the deformed samples in different orientations, parallel and perpendicular to the edge components of dislocations, showed excess conductivity due to dislocation conduction, which can be attributed to the formation of 1D propagating states along dislocations in the 3D TI.
We also fabricated Pb-(Bi,Sb)-Te TI crystals with various Sb molar ratios, and performed a systematic study of their transport properties. We succeeded in improving bulk insulation.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (13 results)

All 2018 2017 2016 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 3 results,  Acknowledgement Compliant: 1 results) Presentation (9 results) Remarks (1 results)

  • [Journal Article] Peierls stresses estimated via the Peierls-Nabarro model using ab-initio γ -surface and their comparison with experiments2018

    • Author(s)
      Kamimura Y.、Edagawa K.、Iskandarov A.M.、Osawa M.、Umeno Y.、Takeuchi S.
    • Journal Title

      Acta Materialia

      Volume: 148 Pages: 355-362

    • DOI

      10.1016/j.actamat.2018.02.009

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Optimizing composition of Pb(Bi1-xSbx)(2)Te-4 topological insulator to achieve a bulk-sulating state2017

    • Author(s)
      Yuya Hattori, Yuki Tokumoto, and Keiichi Edagawa
    • Journal Title

      Physical Review Materials

      Volume: 1 Issue: 7 Pages: 074201-074201

    • DOI

      10.1103/physrevmaterials.1.074201

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Dislocation conduction in Bi-Sb topological insulators2017

    • Author(s)
      Hiromu Hamasaki, Yuki Tokumoto, and Keiichi Edagawa
    • Journal Title

      APPLIED PHYSICS LETTERS

      Volume: 110 Issue: 9 Pages: 092105-092105

    • DOI

      10.1063/1.4977839

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Pb(Bi,Sb)2Te4トポロジカル絶縁体のバルク絶縁性制御2018

    • Author(s)
      服部裕也, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 第73回年次大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pb(Bi1-xSbx)2Te4 (0< x <1)トポロジカル絶縁体の熱電特性2018

    • Author(s)
      上山僚介, 服部裕也, 徳本有紀, 枝川圭一, 北原功一, 木村薫
    • Organizer
      日本金属学会2018年春期(第162回)講演大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pb(Bi,Sb)2Te4トポロジカル絶縁体の熱電特性2017

    • Author(s)
      上山僚介, 服部裕也, 徳本有紀, 枝川圭一
    • Organizer
      日本金属学会2017年春期(第160回)講演大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2017-09-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Pb(Bi,Sb)2Te4トポロジカル絶縁体の作製と電気伝導2017

    • Author(s)
      服部裕也, 上山僚介, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学 豊中キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Bi-Sbトポロジカル絶縁体中転位の評価と電気伝導22017

    • Author(s)
      濱崎拡, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学 豊中キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] Bi-Sbトポロジカル絶縁体中転位の電気的性質2017

    • Author(s)
      濱崎拡, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Pb-(Bi,Sb)-(Te,Se)トポロジカル絶縁体の結晶作製と輸送特性評価2017

    • Author(s)
      服部裕也, 上山僚介, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 2017年秋季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Bi-Sbトポロジカル絶縁体中転位の評価と電気伝導異方性2016

    • Author(s)
      濱崎拡, 大江杏奈, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学 角間キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Research-status Report
  • [Presentation] Pb-(Bi,Sb)-Teトポロジカル絶縁体の結晶作製と評価2016

    • Author(s)
      服部裕也, 市川和樹, 徳本有紀, 枝川圭一
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学 角間キャンパス
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
  • [Remarks] 東京大学生産技術研究所 枝川研究室

    • URL

      http://www.edalabo.iis.u-tokyo.ac.jp

    • Related Report
      2017 Annual Research Report 2016 Research-status Report

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Published: 2016-04-21   Modified: 2019-03-29  

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