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Hybrid improper ferroelectrics: design of ferroelectrics without second-order Jahn-Teller ions

Research Project

Project/Area Number 16K14386
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionKyoto University

Principal Investigator

Fujita Koji  京都大学, 工学研究科, 教授 (50314240)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2017: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2016: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords強誘電体 / 誘電体
Outline of Final Research Achievements

In contrast to polar cation displacements driving oxides into noncentrosymmetric and ferroelectric states, inversion-preserving oxide anion displacements, such as rotations or tilts of oxygen octahedra about cation coordination centers, are exceedingly common. More than one nonpolar rotational mode in layered perovskites can lift inversion symmetry and combine to induce an electric polarization through a hybrid improper ferroelectric (HIF) mechanism. In this study, we report the new Ruddlesden-Popper HIF Sr3Zr2O7, which is the first ternary lead-free zirconate ferroelectric, and demonstrate room-temperature polarization switching. Our experimental and first-principles study shows that the paraelectric polymorph competes with the polar phase and emerges from a trilinear coupling of rotation and tilt modes interacting with an antipolar mode. Our work establishes the importance of understanding anharmonic interactions among lattice degrees of freedom.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (29 results)

All 2018 2017 2016 Other

All Int'l Joint Research (7 results) Journal Article (9 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 9 results,  Open Access: 2 results,  Acknowledgement Compliant: 5 results) Presentation (11 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (2 results)

  • [Int'l Joint Research] Universite de Rennes(France)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Rutherford Appleton Laboratory(英国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Pennsylvania State University/Northwestern University(米国)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Universite de Rennes(France)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Pennsylvania State University(米国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] Rutherford Appleton Laboratory(英国)

    • Related Report
      2016 Research-status Report
  • [Int'l Joint Research] ANSTO(Australia)

    • Related Report
      2016 Research-status Report
  • [Journal Article] Collective plasmonic modes excited in Al nanocylinder arrays in the UV spectral region2018

    • Author(s)
      Kawachiya Yuki、Murai Shunsuke、Saito Motoharu、Sakamoto Hiroyuki、Fujita Koji、Tanaka Katsuhisa
    • Journal Title

      Optics Express

      Volume: 26 Issue: 5 Pages: 5970-5970

    • DOI

      10.1364/oe.26.005970

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ferroelectric Sr3Zr2O7: Competition between Hybrid Improper Ferroelectric and Antiferroelectric Mechanisms2018

    • Author(s)
      Yoshida Suguru、Fujita Koji、Akamatsu Hirofumi、Hernandez Olivier、Sen Gupta Arnab、Brown Forrest G.、Padmanabhan Haricharan、Gibbs Alexandra S.、Kuge Toshihiro、Tsuji Ryosuke、Murai Shunsuke、Rondinelli James M.、Gopalan Venkatraman、Tanaka Katsuhisa
    • Journal Title

      Advanced Functional Materials

      Volume: 28 Issue: 30 Pages: 1801856-1801856

    • DOI

      10.1002/adfm.201801856

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Perovskite-Type InCoO3 with Low-Spin Co3+: Effect of InーO Covalency on Structural Stabilization in Comparison with Rare-Earth Series2017

    • Author(s)
      Fujita Koji、Kawamoto Takahiro、Yamada Ikuya、Hernandez Olivier、Akamatsu Hirofumi、Kumagai Yu、Oba Fumiyasu、Manuel Pascal、Fujikawa Ryo、Yoshida Suguru、Fukuda Masayuki、Tanaka Katsuhisa
    • Journal Title

      Inorganic Chemistry

      Volume: 56 Issue: 18 Pages: 11113-11122

    • DOI

      10.1021/acs.inorgchem.7b01426

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Plasmonic-Photonic Hybrid Modes Excited on a Titanium Nitride Nanoparticle Array in the Visible Region2017

    • Author(s)
      Kamakura Ryosuke、Murai Shunsuke、Ishii Satoshi、Nagao Tadaaki、Fujita Koji、Tanaka Katsuhisa
    • Journal Title

      ACS Photonics

      Volume: 4 Issue: 4 Pages: 815-822

    • DOI

      10.1021/acsphotonics.6b00763

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Competing Structural Instabilities in the Ruddlesden-Popper Derivatives HRTiO4 (R = Rare Earths): Oxygen Octahedral Rotations Inducing Noncentrosymmetricity and Layer Sliding Retaining Centrosymmetricity2017

    • Author(s)
      A. S. Gupta, H. Akamatsu, F. G. Brown, M. T. Nguyen, M. E. Strayer, S. Lapidus, S. Yoshida, K. Fujita, K. Tanaka, I. Tanaka, T. E. Mallouk, and V. Gopalan
    • Journal Title

      Chemistry of Materials

      Volume: 29 Issue: 2 Pages: 656-665

    • DOI

      10.1021/acs.chemmater.6b04103

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Giant Faraday rotation through Fe0n states in superparamagnetic FeO-SiO2 vitreous films2017

    • Author(s)
      Yuko Nakatsuka, Kilian Pollok, Torsten Wieduwilt, Falko Langenhorst, Markus A. Schmidt, Koji Fujita, Shunsuke Murai, Katsuhisa Tanaka, and Lothar Wondraczek
    • Journal Title

      Advanced Science

      Volume: - Issue: 4

    • DOI

      10.1002/advs.201600299

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] LiNbO3-type InFeO3: Room-temperature polar magnet without second-order Jahn Teller active ions2016

    • Author(s)
      Koji Fujita, Takahiro Kawamoto, Ikuya Yamada, Olivier Hernandez, Naoaki Hayashi, Hirofumi Akamatsu, William Lafargue-Dit-Hauret, Xavier Rocquefelte, Masafumi Fukuzumi, Pascal Manuel, Andrew J. Studer, Christopher Knee, and Katsuhisa Tanaka
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 18 Pages: 6644-6655

    • DOI

      10.1021/acs.chemmater.6b02783

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] ZnTaO2N: Stabilized High-Temperature LiNbO3-type Structure2016

    • Author(s)
      Kuno, Y.; Tassel, C.; Fujita, K.; Batuk, D.; Abakumov, A. M.; Shitara, K.; Kuwabara, A.; Moriwake, H.; Watabe, D.; Ritter, C.; Brown, C. M.; Yamamoto, T.; Takeiri, F.; Abe, R.; Kobayashi, Y.; Tanaka, K.; Kageyama, H.
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 49 Pages: 15950-15955

    • DOI

      10.1021/jacs.6b08635

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Structural phase transitions in EuNbO3 perovskite2016

    • Author(s)
      Yoshiro Kususe, Suguru Yoshida, Koji Fujita, Hirofumi Akamatsu, Masafumi Fukuzumi, Shunsuke Murai, and Katsuhisa Tanaka
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 239 Pages: 192-199

    • DOI

      10.1016/j.jssc.2016.04.032

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] 層状ペロブスカイト強誘電体に見られる準安定な反極性構造2018

    • Author(s)
      吉田傑、藤田晃司、赤松寛文、Olivier Hernandez、Arnab Sen Gupta、Alexandra Gibbs、久家俊洋、辻涼介、村井俊介、Venkatraman Gopalan、田中勝久
    • Organizer
      第65回応用物理学会 春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 酸素欠損ペロブスカイト化合物における極性構造と弱強磁性の共存2018

    • Author(s)
      辻涼介、藤田晃司、吉田傑、三宅仁介、村井俊介、田中勝久
    • Organizer
      日本セラミックス協会 2018年年会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 新規機能性酸化物の創製と機能発現機構の解明2018

    • Author(s)
      藤田晃司
    • Organizer
      日本セラミックス協会 2018年年会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 新規ペロブスカイト型ニッケル酸化物の高圧合成、結晶構造および磁気的性質2017

    • Author(s)
      菅智樹、藤田晃司、河本崇博、田中勝久、山田幾也
    • Organizer
      日本セラミックス協会 2017年年会
    • Place of Presentation
      日本大学駿河台キャンパス
    • Year and Date
      2017-03-17
    • Related Report
      2016 Research-status Report
  • [Presentation] 層状ペロブスカイト型酸化物における間接型強誘電性と構造相転移2017

    • Author(s)
      吉田傑、藤田晃司、赤松寛文、Olivier Hernandez、Arnab Sen Gupta、Alexandra Gibbs、久家俊洋、辻涼介、村井俊介、Venkatraman Gopalan、田中勝久
    • Organizer
      日本セラミックス協会 第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] ルドルスデンーポッパー相における強誘電性と構造相転移2017

    • Author(s)
      吉田傑、藤田晃司、赤松寛文、Olivier Hernandez、Arnab Sen Gupta、Alexandra Gibbs、久家俊洋、辻涼介、村井俊介、Venkatraman Gopalan、田中勝久
    • Organizer
      第78回応用物理学会 秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Coexistence of ferroelectricity and weak ferromagnetism in iron-based layered compound2017

    • Author(s)
      Tsuji Ryosuke、Fujita Koji、Yoshida Suguru、Miyake Jinsuke、Murai Shunsuke、Tanaka Katsuhisa
    • Organizer
      IUMRS-ICAM2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 層状ペロブスカイトARTiO4 (A=アルカリ金属、R=希土類) における 酸素配位八面体回転に対するカチオンサイズ効果2016

    • Author(s)
      赤松 寛文、藤田晃司、田中勝久、田中功、Venkatraman Gopalan
    • Organizer
      日本金属学会秋期講演大会
    • Place of Presentation
      大阪大学豊中キャンパス
    • Year and Date
      2016-09-21
    • Related Report
      2016 Research-status Report
  • [Presentation] Large Faraday Effect of Amorphous Iron Silicate Thin Films by Metallic Iron2016

    • Author(s)
      Yuko Nakatsuka, Kilian Pollok, Falko Langenhorst, Lothar Wondraczek, Shunsuke Murai, Koji Fujita, and Katsuhisa Tanaka
    • Organizer
      JSAP Autumn Meeting
    • Place of Presentation
      Toki Messe, Niigata
    • Year and Date
      2016-09-13
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research
  • [Presentation] 新規ペロブスカイト型鉄酸フッ化物の合成と物性2016

    • Author(s)
      竹入史隆、山本隆文、藤田晃司、細川三郎、小林洋治、陰山洋、林直顕、池田一貴、本田孝志、大友季哉
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Presentation] Novel Oxynitride Perovskite with a High-Temperature-type LiNbO3 Structure2016

    • Author(s)
      Cedric Tassel, Yoshinori Kuno, Koji Fujita, Daichi Watabe, Dmitry Batuk, Artem M. Abakumov, Kazuki Shitara, Akihide Kuwabara, Hiroki Moriwake, Clemens Ritter, Craig M. Brown, Takafumi Yamamoto, Ryu Abe, Yoji Kobayashi, Katsuhisa Tanaka, Hiroshi Kageyama
    • Organizer
      日本セラミックス協会 第29回秋季シンポジウム
    • Place of Presentation
      広島大学 東広島キャンパス
    • Year and Date
      2016-09-07
    • Related Report
      2016 Research-status Report
  • [Remarks]

    • URL

      http://www1.kuic.kyoto-u.ac.jp/

    • Related Report
      2017 Annual Research Report
  • [Remarks] 京都大学 大学院工学研究科 材料化学専攻 無機材料化学講座 応用固体化学分野 田中研究室

    • URL

      http://dipole7.kuic.kyoto-u.ac.jp

    • Related Report
      2016 Research-status Report

URL: 

Published: 2016-04-21   Modified: 2022-06-16  

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