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Atomic position analysis in whole particle of ferroelectrics

Research Project

Project/Area Number 16K14389
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionKyushu University

Principal Investigator

Sato Yukio  九州大学, 工学研究院, 准教授 (80581991)

Project Period (FY) 2016-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords強誘電体 / ナノ粒子 / 電子顕微鏡 / メモリ / チタン酸バリウム / 圧電体 / 誘電体 / 走査透過型電子顕微鏡
Outline of Final Research Achievements

In this research project, we have conducted electron microscopic analysis of ferroelectric nanoparticle, which is a promising material for future electronic devices wherein downsizing and improving is strongly demanded. Using scanning transmission electron microscopy (STEM) by which atomic position can be determined at high precision, atomic resolution images were acquired. We have measured STEM image from multiple fields of view and connect them to unravel the lattice constant and ionic position in the unit cell and their spatial distribution in the particle. We have characterized commercially available barium titanate (BaTiO3) nanoparticle and found that Ba ion largely displaced by larger than 20 pm. This implies that dielectric and ferroelectric properties of the particle is affected by the surface.

Report

(3 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • Research Products

    (17 results)

All 2018 2017 2016 Other

All Int'l Joint Research (1 results) Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results) Remarks (1 results)

  • [Int'l Joint Research] Indian Institute of Science, Bangalore(India)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Measurement of Barium Ion Displacement Near Surface in a Barium Titanate Nanoparticle by Scanning Transmission Electron Microscopy2018

    • Author(s)
      Mai Aoki, Yukio Sato, Ryo Teranishi, Kenji Kaneko
    • Journal Title

      Applied Microscopy

      Volume: 48 Issue: 1 Pages: 27-32

    • DOI

      10.9729/am.2018.48.1.27

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron microscopy with high accuracy and precision at atomic resolution: In-situ observation of a dielectric crystal under electric field2017

    • Author(s)
      Yukio Sato, Takashi Gondo, Hiroya Miyazaki, Ryo Teranishi, and Kenji Kaneko
    • Journal Title

      Applied Physics Letters

      Volume: 111 Issue: 6 Pages: 062904-062904

    • DOI

      10.1063/1.4986361

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Transformation and Interface Segregation Behavior in Si3N4 Ceramics Sintered with La2O3-Lu2O3 Mixed Additive2017

    • Author(s)
      R. Urakami, Y. Sato, M. Ogushi, T. Nishiyama, A. Goto, K. Yamada, R. Teranishi, K. Kaneko, and M. Kitayama
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 100 Issue: 3 Pages: 1231-1240

    • DOI

      10.1111/jace.14663

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electron microscopic analysis of surface damaged layer in Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystal2017

    • Author(s)
      Y. Kasuya, Y. Sato, R. Urakami, K. Yamada, R. Teranishi, and K. Kaneko
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 1 Pages: 010312-010312

    • DOI

      10.7567/jjap.56.010312

    • NAID

      210000147324

    • Related Report
      2016 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanostructural characterization of artificial pinning centers in PLD-processed REBa2Cu3O7-d films2017

    • Author(s)
      T. Maeda, K. Kaneko, K. Yamada, A. Roy, Y. Sato, R. Teranishi, T. Kato, T. Izumi, and Y. Shiohara
    • Journal Title

      Ultramicroscopy

      Volume: 176 Pages: 151-160

    • DOI

      10.1016/j.ultramic.2016.11.015

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Presentation] Atomic scale and in-situ electron microscopic analysis of ferroelectrics2017

    • Author(s)
      Yukio Sato
    • Organizer
      12th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM 12)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] チタン酸バリウムナノ粒子の表面近傍における原子スケール構造解析2017

    • Author(s)
      青木舞、佐藤幸生、寺西亮、金子賢治
    • Organizer
      日本セラミックス協会第30回秋季シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] Nano- and atomic-scale characterization of electroceramics2017

    • Author(s)
      Yukio Sato,Ryo Teranishi,and Kenji Kaneko
    • Organizer
      International Symposium on Microscopy and Microanalysis of Materials 2017
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Electron microscopic analysis of piezoelectric material for medical imaging device2017

    • Author(s)
      Yukio Sato
    • Organizer
      BIT’s 3rd Annual World Congress of Smart Materials - 2017
    • Place of Presentation
      Bangkok, Thailand
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 高分解能およびその場電子顕微鏡法による強誘電体の研究2017

    • Author(s)
      佐藤幸生
    • Organizer
      強的秩序とその操作に関わる研究グループ 第4回 研究会
    • Place of Presentation
      東京
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] BaTiO3ナノ粒子の表面近傍における高分解能構造解析2017

    • Author(s)
      青木舞,佐藤幸生,寺西亮,金子賢治
    • Organizer
      日本金属学会2017年春期(第160回)講演大会
    • Place of Presentation
      東京
    • Related Report
      2016 Research-status Report
  • [Presentation] Nanoscopic study on domain structure in morphotropic phase boundary Pb(Mg1/3Nb2/3)O3-PbTiO32016

    • Author(s)
      Yukio Sato
    • Organizer
      International Conference on Technologically Advanced Materials & Asian Meeting of Ferroelectricity (ICTAM-AMF10)
    • Place of Presentation
      Dehli, India
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Atomic Scale Characterization of Grain Boundary in Zinc Oxide Ceramics Using Electron Microscopy and First-Principles Calculation2016

    • Author(s)
      Yukio Sato
    • Organizer
      International Symposium on Microscopy and Microanalysis of Materials 2016 (ISMMM 2016)
    • Place of Presentation
      Nanjing, China
    • Related Report
      2016 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] チタン酸バリウム粒子の表面近傍における高分解能構造解析2016

    • Author(s)
      佐藤幸生,稲田幹,Ahin Roy,青木舞,林克郎,金子賢治
    • Organizer
      日本セラミックス協会第29回秋季シンポジウム
    • Place of Presentation
      広島大学、広島
    • Related Report
      2016 Research-status Report
  • [Presentation] BaTiO3粒子の表面およびその近傍における構造解析2016

    • Author(s)
      佐藤幸生,稲田幹,Ahin Roy,青木舞,林克郎,金子賢治
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学、石川
    • Related Report
      2016 Research-status Report
  • [Remarks] ナノ材料組織解析学・金子研究室 佐藤幸生准教授

    • URL

      http://zaiko13.zaiko.kyushu-u.ac.jp/sato.html

    • Related Report
      2017 Annual Research Report

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Published: 2016-04-21   Modified: 2019-03-29  

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